• Title/Summary/Keyword: CO conversion

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The radio frequency excited slab waveguide CO2 laser (고주파 여기식 슬랩형 도파관 CO2 레이저)

  • 김규식;이영우;우삼용;최종운
    • Korean Journal of Optics and Photonics
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    • v.14 no.4
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    • pp.406-412
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    • 2003
  • We have developed a radio frequency excited slab waveguide $CO_2$ laser. The dimension of active volume is 2${\times}$40${\times}$400 mm. One concave and one convex mirror are used to make the unstable resonator of the positive branch. The radio frequency is 123 MHz and RF input power is varied from 100 to 900 W. The laser gas is set to a pressure of 10∼60 torr and the mixing ratio is $CO_2$:$N_2$:He=1:1:3. The laser output power of 70.7 W was obtained which corresponds to laser power to RF power conversion efficiency of 9.2%.

Crystal Structure of Acyl-CoA Oxidase 3 from Yarrowia lipolytica with Specificity for Short-Chain Acyl-CoA

  • Kim, Sangwoo;Kim, Kyung-Jin
    • Journal of Microbiology and Biotechnology
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    • v.28 no.4
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    • pp.597-605
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    • 2018
  • Acyl-CoA oxidases (ACOXs) play important roles in lipid metabolism, including peroxisomal fatty acid ${\beta}$-oxidation by the conversion of acyl-CoAs to 2-trans-enoyl-CoAs. The yeast Yarrowia lipolytica can utilize fatty acids as a carbon source and thus has extensive biotechnological applications. The crystal structure of ACOX3 from Y. lipolytica (YlACOX3) was determined at a resolution of $2.5{\AA}$. It contained two molecules per asymmetric unit, and the monomeric structure was folded into four domains; $N{\alpha}$, $N{\beta}$, $C{\alpha}1$, and $C{\alpha}2$ domains. The cofactor flavin adenine dinucleotide was bound in the dimer interface. The substrate-binding pocket was located near the cofactor, and formed at the interface between the $N{\alpha}$, $N{\beta}$, and $C{\alpha}1$ domains. Comparisons with other ACOX structures provided structural insights into how YlACOX has a substrate preference for short-chain acyl-CoA. In addition, the structure of YlACOX3 was compared with those of medium- and long-chain ACOXs, and the structural basis for their differences in substrate specificity was discussed.

Experiment of CO Cleaning Process in DME Autothermal Reformate Gas for PEMFC Application (고분자 전해질 연료전지 적용을 위한 DME 자열개질가스 내 CO제거 공정 특성 연구)

  • Choi, Seung-Hyeon;Bae, Joong-Myeon
    • Journal of Hydrogen and New Energy
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    • v.22 no.4
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    • pp.474-480
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    • 2011
  • Hydrocarbon is required to be converted to pure hydrogen without carbon monooxide (CO) for polymer exchange membran fuel cell (PEMFC) applications. In this paper, CO cleaning processes as the downstream of Dimethyl ehter (DME) autothermal reforming process were performed in micro-reactors. Our study suggested two kinds of water gas shift (WGS) reaction process: High Temperature shift (HTS) - Low Temperature shift (LTS), Middle temperature shift (MTS). Firstly, using perovskite catalyst for MTS was decreased effieiciency since methanation. Using HTS-LTS the CO concentration was decreased about 2% ($N_2$ & $H_2O$ free) with the reaction temperature of $420^{\circ}C$ and $235^{\circ}C$ for HTS and LTS, respectively. As the final stage of CO cleaning process, preferential oxidation (PROX) was applied. The amount of additional oxygen need 2 times of stoichiometric at $65^{\circ}C$. The total conversion reforming efficiency of 75% was gained.

The Development of Main Power Conversion System for MAGLEV (도시형 자기부상열차용 주요전장품 개발)

  • Lee, Kwang-Joo;Jung, Man-Gyu;Bang, Lee-Seok;Kim, Du-Sik;Seo, Kwang-Duk;Kim, Kuk-Jin;Kang, Byeong-Koan
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.638-641
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    • 1997
  • This paper describes the electrical design, characteristic and test results of both VVVF Inverter system and a auxiliary power supply system for UTM-01. As the propulsion system for SLIMs, GTO type VVVF inverter is used. IGBT 3 level inverter is adopt in Auxiliary Power Supply system. The control of two systems is fully digitalized by DSP TMS320C31. So a performance of two systems is more improved.

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Effects of Hexaaluminate Manufacturing on the Synthetic Time of Hydrothermal Synthesis Using Urea (요소를 이용한 수열합성의 합성시간에 따른 Hexaaluminate 제조의 영향)

  • Kim, Seo Young;Park, Ji Yun;Rhee, Young Woo
    • Clean Technology
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    • v.25 no.4
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    • pp.331-335
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    • 2019
  • Interest in environmental pollution is increasing all over the world, and technology development to solve it is actively carried out. In areas where heat is used, especially, combustion is causing countless pollutants in the air environment. Combustion catalyst is a technology that reduces NOx and CO by lowering combustion temperature and enabling complete combustion. Traditional combustion catalysts are expensive and complex in the synthesis process using precious metal catalyst. In this study, hexaaluminate, a high-temperature combustion catalyst, was manufactured using urea, and the properties were investigated according to the synthesis time. The combustion performance and characteristics were evaluated using this catalyst. As the temperature increased, the changing methane conversion rate was shown in two patterns. The conversion rates for 1 hour, 9 hours, and 12 hours were similar, while the conversion rates for 3 hours and 6 hours showed similar patterns. Methane combustion performance increased rapidly as the synthesis time increased from 6 hours to 9 hours, whereas the temperature at T50 was approximately 745 ℃. The performance of the synthesized combustion catalyst for 9 hours was optimum as the NOx emission of this combustion catalyst was not present and the maximum emission of CO was 72 ppm.

A Study on the Carbon Neutrality Scenario Model for Technology Application in Units of Space (공간 단위 탄소중립 기술적용 시나리오 모형(CATAS) 연구)

  • Park, Shinyoung;Choi, Yuyoung;Lee, Mina
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.1
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    • pp.63-69
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    • 2023
  • 'Carbon-neutrality Assessment based on Technology Application Scenario (CATAS)' provides an analysis of greenhouse gas (GHG) reduction effectiveness when applying carbon-neutrality technology to areas such as energy conversion, transportation, and buildings at certain spatial levels. As for the development scope of the model, GHG emission sources were analyzed for direct GHG emissions, and the boundary between direct and indirect emissions are set according to the spatial scope. The technical scope included nine technologies and forest sinks in the transition sector that occupies the largest portion of GHG emissions in the 2050 carbon neutral scenario. The carbon neutrality rate evaluation methodology consists of four steps: ① analysis of GHG emissions, ② prediction of energy production according to technology introduction, ③ calculation of GHG reduction, and ④ calculation of carbon neutrality rate. After the web-based CATAS-BASIC was developed, an analysis was conducted by applying the new and renewable energy distribution goals presented in the 「2050 Greenhouse Gas Reduction Promotion Plan」 of the Seoul Metropolitan Government. As a result of applying solar power, hydrogen fuel cell, and hydrothermal, the introduction of technology reduced 0.43 million tCO2eq of 1.49 million tCO2eq, which is the amount of emissions from the conversion sector in Seoul, and the carbon neutrality rate in the conversion sector was analyzed to be 28.94 %.

A Conversion of AFm Phases by Addition of CaCO3, CaCl2 and CaSO4 · 2H2O (CaCO3, CaCl2 및 CaSO4 · 2H2O 첨가에 의한 AFm상의 변화)

  • 이종규;추용식
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.24-30
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    • 2003
  • A formation and conversion of AFm phases decisively play role in the hydration, hardening and corrosion processes of various cement. In this study, the conversion of Alumino-Ferrite Monohydrates(AFm) phases under the addition of $CaCO_3,;CaCl_2;and;CaSO_4{cdot}2H_2O$was investigated by the XRD quantitative analysis. The thypical AFm phases are $M_S(monosulfoaluminate),;M_C(monocarboaluminate);and;M_{Cl}(monochloroaluminate and also Called Friedel's salts)$in this cementitious system, The conversion reaction were not occurred in $M_C-CaCO_3,;M_{Cl}-CaCO_3$ and $M_{Cl}-CaCl_2$system. However, in $M_S-CaCO_3$ system, ettringite and $monocarboaluminate(M_C)$ were formed. In $M_S-CaCl_2;system;M_S$ was transformed to Friedel's $salts(M_{Cl})$ and ettringite was formed. In the case of $CaSO_4{cdot}2H_2O$ addition, all AFm $phases(M_S,;M_C;and;M_{Cl})$ were transformed to ettringite. The order of stabilization of AFm phases under $CaCO_3,;CaCl_2;and;CaSO_4{cdot}2H_2O$ was as follows : $M_S< M_C

Development of a Plasma-Dump Reformer for Syngas Production (합성가스 생산을 위한 플라즈마-덤프 개질기 개발)

  • Lim, Mun Sup;Kim, Eun Hyuk;Chun, Young Nam
    • Journal of Hydrogen and New Energy
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    • v.25 no.6
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    • pp.586-593
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    • 2014
  • Limited sources of fossil fuels and also global climate changes caused by $CO_2$ emissions are currently discussed around the world. As a renewable, carbon neutral and widely available energy source, biogas is regarded as a promising alternative to fossil fuels. In this study, a plasma dump reformer was proposed to produce $H_2$-rich synthesis gas by a model biogas. The three-phase gliding arc plasma and dump combustor were combined. Screening studies were carried out with the parameter of a dump injector flow rate, water feeding flow rate, air ratio, biogas component ratio and input power. As the results, methane conversion rate, carbon dioxide conversion rate, hydrogen selectivity, carbon monoxide yield at the optimum conditions were achieved to 98%, 69%, 42%, 24.7%, respectively.

Development of Environmental Control Systems for Windowless Pig-housing (II) - Growth Performance of Weaned Piglets and Growing Pigs - (무창돈사의 환경제어 시스템 개발 (II) - 자돈과 육성돈의 사양성적 -)

  • 장동일;장홍희;임영일;박창식;이봉덕;이형석
    • Journal of Biosystems Engineering
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    • v.24 no.5
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    • pp.425-430
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    • 1999
  • Complex environmental control systems were developed, which control properly the pig's environment in windowless pig-housing based on the thermoregulatory behaviors of pigs and concentrations of noxious gases (CO2 and NH3). The this study was conducted to assess the performance of complex environmental control systems by raising weaned piglets and growing pigs under different seasonal conditions. Average daily gain of pigs in the experimental pig-housing was slightly higher than that of pigs in the conventional pig-housing. Average daily gain was not significantly different in winter and spring(P>0.05), but was significantly different in summer(P<0.05). Feed conversion rate of pigs in the experimental pig-housing was smaller than that of pigs in the conventional pig-housing. Feed conversion rate was not significantly different in environment for weaned piglets and growing pigs resulted in the improved daily gain, feed conversion rate, and carcass quality of the finishing pigs. These results showed that the performance of the complex environmental control systems in windowless pig-housing was excellent for weaned piglets and growing pigs.

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Hydrogen production by catalytic decomposition of propane-containing methane over N330 carbon black in a fluidized bed (유동층 반응기에서 N330 카본 블랙 촉매를 이용한 프로판을 포함한 메탄의 촉매분해에 의한 수소 제조)

  • Lee, Seung-Chul;Lee, Kang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.761-764
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    • 2009
  • The thermocatalytic decomposition of methane is an environmentally attractive approach to $CO_2$-free production of hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbon from the reactor. The usage of carbon black was reported as stable catalyst for decomposition of methane. Therfore, carbon black (DCC-N330) is used as catalyst. A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was selected for the thermo-catalytic decomposition. The porpane-containg methnae decomposition reaction was operated at the temperature range of 850-900 $^{\circ}C$ methane gas velocity of 1.0 $U_{mf}$ and the operating pressure of 1.0 atm. In this work, propane was added as reactant to make methane conversion higher. Therefore we compared with methane conversion and pre-experiment methane conversion that using only methane as reactant. The carbon black, after experiment, was measured in particle size and surface area and analyzed surface of the carbon black by TEM.

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