• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.3
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• pp.308-310
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• 2022

Ultrawide bandgap gallium oxide (Ga₂O₃) semiconductors are known to have excellent photocatalytic properties due to their high redox potential. In this study, CO₂ reduction is demonstrated using nanostructured Ga₂O₃ photocatalyst under ultraviolet (254 nm) light source conditions. After the CO₂ reduction, C₂H₄ remained as a by-product in this work. Nanostructured Ga₂O₃ photocatalyst also showed an excellent endurance characteristic. Photogenerated electron-hole pairs boosted the CO₂ reduction to C₂H₄ via nanostructured Ga₂O₃ photocatalyst, which is attributed to the ultrawide and almost direct bandgap characteristics of the gallium oxide semiconductor. The findings in this work could expedite the realization of CO₂ reduction and a simultaneous C₂H₄ production using a low cost and high performance photocatalyst.

• Korean Journal of Materials Research
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• v.33 no.2
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• pp.29-46
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• 2023

The electrochemical reduction of carbon dioxide (CO₂) to value-added products is a remarkable approach for mitigating CO₂ emissions caused by the excessive consumption of fossil fuels. However, achieving the electrocatalytic reduction of CO₂ still faces some bottlenecks, including the large overpotential, undesirable selectivity, and slow electron transfer kinetics. Various electrocatalysts including metals, metals oxides, alloys, and single-atom catalysts have been widely researched to suppress HER performance, reduce overpotential and enhance the selectivity of CO₂RR over the last few decades. Among them, single-atom catalysts (SACs) have attracted a great deal of interest because of their advantages over traditional electrocatalysts such as maximized atomic utilization, tunable coordination environments and unique electronic structures. Herein, we discuss the mechanisms involved in the electroreduction of CO₂ to carbon monoxide (CO) and the fundamental concepts related to electrocatalysis. Then, we present an overview of recent advances in the design of high-performance noble and non-noble singleatom catalysts for the CO₂ reduction reaction.

• Journal of the Microelectronics and Packaging Society
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• v.30 no.4
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• pp.91-97
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• 2023

Electrochemical (EC) CO₂ reduction is a promising method to convert CO₂ into valuable hydrocarbon fuels and chemicals ecofriendly. Here, we report on a facile method to synthesize surface-controlled SnO₂/Cu(OH)₂ nanowires (NWs) and its EC reduction of CO₂ to HCOOH and CO. The SnO₂/Cu(OH)₂ NWs (-16 mA/cm²) showed superior electrochemical performance compared to Cu(OH)2 NWs (-6 mA/cm²) at -1.0 V (vs. RHE). SnO₂/Cu(OH)₂ NWs showed the maximum Faradaic efficiency for conversion to HCOOH (58.01 %) and CO (29.72 %). The optimized catalyst exhibits a high C1 Faradaic efficiency stable electrolysis for 2 h in a KHCO₃ electrolyte. This study facilitates the potential for the EC reduction of CO₂ to chemical fuels.

• New & Renewable Energy
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• v.19 no.4
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• pp.20-26
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• 2023

Emitted CO₂ is an attractive material for microbial electrochemical CO₂ reduction. Microbial electrochemical CO₂ reduction (i.e., microbial electrosynthesis, MES) using biocatalysts has advantages compared to conventional CO₂ reduction using electrocatalysts. However, MES has several challenges, including electrode performance, biocatalysts, and reactor optimization. In this study, an MES system was investigated for optimizing reactor types, counter electrode materials, and CO₂-converting microorganisms to achieve effective CO₂ upcycling. In autotrophic cultivation (supplementation of CO₂ and H₂), CO₂ consumption of Rhodobacter sphaeroides was observed to be four times higher than that with heterotrophic cultivation (supplementation of succinic acid). The bacterial growth in an MES reactor with a single-chambered shape was two times higher than that with a double chamber (H-type MES reactor). Moreover, a single-chambered MES reactor equipped with titanium mesh as the counter electrode (anode) showed markedly increased current density in the graphite felt as a working electrode (cathode) compared to that with a graphite felt counter electrode (anode). These results demonstrate that the optimized conditions of a single chamber and titanium mesh for the counter electrode have a positive effect on microbial electrochemical CO₂ reduction.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.215-216
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• 2012

Emissions of CO₂ occur during the production of cement manufacturing process. During the production of clinker, limestone is mainly calcium carbonate, is heated to produce lime and CO₂ as a by-product. It has a major problem, CO₂ uptake is not considered in concrete carbonation, just focus in CO₂ emission. This study is to develop a simulation model for CO₂ uptakes in concrete structures based on carbonation reduction coefficient considering finishing materials. CO₂ uptakes unit of concrete cubic meter is calculated by CO₂ emissions unit of concrete materials and usage of concrete materials in mix proportion. From the simulation result, CO₂ uptake ratios is 2.04 percent in carbonation models of concrete structure during 40 years.

• Journal of Electrochemical Science and Technology
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• v.13 no.4
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• pp.462-471
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• 2022

In this study, the electrochemical impedance characteristics of CO₂/H₂O co-reduction to produce CO/H₂ syngas were investigated in a low-temperature single cell. The effect of the operating conditions on the single-cell performance was evaluated at different feed concentrations and cell voltages, and the corresponding electrochemical impedance spectroscopy (EIS) data were collected and analyzed. The Nyquist plots exhibited two semicircles with separated characteristic frequencies of approximately 1 kHz and tens of Hz. The high-frequency semicircles, which depend only on the catholyte concentration, could be correlated to the charge transfer processes in competitive CO₂ reduction and hydrogen evolution reactions at the cathodes. The EIS characteristics of the CO₂/H₂O co-reduction single cell could be explained by the equivalent circuit suggested in this study. In this circuit, the cathodic mass transfer and anodic charge transfer processes are collectively represented by a parallel combination of resistance and a constant phase element to show low-frequency semicircles. Through nonlinear fitting using the equivalent circuit, the parameters for each electrochemical element, such as polarization resistances for high- and low-frequency processes, could be quantified as functions of feed concentration and cell voltage.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.05a
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• pp.5-6
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• 2011

CO₂ reduction is the most urgent issue the world is facing. So, there should be a measure to reduce the CO₂ emission in construction industry which has more released CO₂ gas than other industries. CO₂ emission of building depend on using energy. Then efficient energy use process working efficiently at CO₂ reduction. Therefore In this study, author find the technical possibility of saving the building energy using the PCM which is able to control heat, storage heat and potential heat. So, it considered that apply to floor heating type which is major heating system of living space in Korea. And evaluate the Using possibility.

• Nuclear Engineering and Technology
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• v.54 no.1
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• pp.220-225
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• 2022

Perlite is one of the major constituents of the radioactive thermal insulation waste (RTIW) originating from nuclear power plants and, for proper waste management, a significant reduction in its volume is required prior to disposal. In this work, the volume reduction of perlite is studied by high-temperature treatment method with using K₂CO₃ as a flux. The perlite is ground with 0-30 wt% K₂CO₃, and differential thermal analysis/thermogravimetric analysis is used to monitor the glass transition temperature (T_g) and weight loss. The Tg varied between ~772.2 and 837.1 ℃ with the minima at ~643.5 ℃ with the addition of ~10 wt% K₂CO₃. It is observed that compared to the pure perlite the volume reduction ratio (VRR) increases with the addition of K₂CO₃. The VRR of 11.20 is observed with 5 wt% K₂CO₃ at 700 ℃, as compared to VRR of 5.56 without K₂CO₃ at 700 ℃. The X-ray photoelectron spectroscopy and scanning electron microscopy are used to characterize perlite samples heat-treated without/with 5 wt% K₂CO₃ at 700 ℃. Moreover, the atomic absorption spectroscopy indicates that the proposed heat-treatment procedure is able to completely retain the radionuclides present in the perlite RTIW.

• Korean Journal of Materials Research
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• v.30 no.11
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• pp.581-588
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• 2020

Reducing CO₂ into high value fuels and chemicals is considered a great challenge in the 21st century. Efficiently activating CO₂ will lead to an important way to utilize it as a resource. This article reviews the latest progress of g-C₃N₄ based catalysts for CO₂ reduction. The different synthetic methods of g-C₃N₄ are briefly discussed. Article mainly introduces methods of g-C₃N₄ shape control, element doping, and use of oxide compounds to modify g-C₃N₄. Modified g-C₃N₄ has more reactive sites, which can significantly reduce the probability of photogenerated electron hole recombination and improve the performance of photocatalytic CO₂ reduction. Considering the literature, the hydrothermal method is widely used because of its simple equipment and process and easy control of reaction conditions. It is foreseeable that hydrothermal technology will continue to innovate and usher in a new period of development. Finally, the prospect of a future reduction of CO₂ by g-C₃N₄-based catalysts is predicted.

• Journal of the Korean Society of Industry Convergence
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• v.25 no.4_2
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• pp.549-563
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• 2022

Continuous global warming is causing ecosystem destruction and direct damage to human life. The main cause of global warming is greenhouse gases, which account for more than 90 % of carbon dioxide. The leaders of each country signed the Paris Agreement at the United Nations Convention on Climate Change (UNFCCC) to reduce greenhouse gas emissions. Currently, the total amount of CO₂ emitted from South Korea is 664.7 million tons as of 2018, ranking eighth in the world. 37 % of South Korea's total CO₂ emissions come from the construction & building field, especially the cement production, which is a construction material. Carbon reduction technologies can be largely divided into four types: carbon reduction (CC), carbon reduction and storage technology (CCS), carbon reduction and utilization technology (CCU), and carbon reduction, storage and utilization technology (CCUS). Overseas, CCUS technology is mainly applied to reduce and store CO₂ emitted from construction and construction field. A technology for permanently storing CO₂ through mineralization by capturing CO₂ and utilizing CO₂ into a cement production process was developed, and this technology is applied to the entire cement industry. However, the development of CCUS technology applicable to the cement industry is still insignificant in South Korea. In this study, carbon dioxide reduction technology and methods for reducing carbon dioxide emitted during the cement manufacturing process, which is the main component of concrete mainly used in civil engineering construction, were investigated. Overseas, it has reached the commercialization stage beyond the demonstration stage as a way to reduce carbon dioxide by vomiting carbonation reactions. Accordingly, if carbon dioxide reduction plan technology generated during cement manufacturing is developed based on domestic technology differentiated from foreign technology, it is expected to contribute one more step to the carbon neutrality policy.