• Textile Coloration and Finishing
• /
• v.19 no.4
• /
• pp.26-31
• /
• 2007

Nanocomposite resin(PUD-CNT) composed of Carbon nanotube(CNT) and Polyurethane Dispersion (PUD) was prepared by different contents of CNT($0{\sim}5%$). PUD-CNT was coated on samples, and their electrical conductivity was investigated. With increasing CNT content, static change, half life and surface resistance decreased. Composites having 5% CNT showed $10^9{\Omega}/cm$(surface resistance), and 40V (stactic charge). Respectively, From this results, PUD-CNT can be used as a antistatic material.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.12
• /
• pp.1062-1067
• /
• 2007

In this paper, we have investigated thermal properties of semiconductive shield materials for power cables. EEA (Ethylene Ethyl Acrylate) was used for base polymer and TGA (Thermal Gravimetric Analysis) and AFM (Atomic Force Microscope) were investigated with various carbon black and CNT (carbon nanotube) contents. When CNT reinforced composites and conventional composite were investigated with TGA, we knew that thermal properties of CNT reinforced composite were better than them of conventional composite. To investigate roughness, we used AFM. Before and after aging, AFM was applied and after aging, roughness was increased. As a result, suitable CNT and CB(carbon black) content is CNT:CB=50:50.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2011.11a
• /
• pp.536-538
• /
• 2011

In this study, the moisture absorption behaviors of the CNT reinforced unsaturated polyester composites were investigated along with exposure temperature and time. The tensile properties of the specimens were evaluated to identify the effect of absorbed moisture on the mechanical properties. The exposure temperatures of $25^{\circ}C$ and $75^{\circ}C$ were considered and the exposure time up to 600 hours was applied. According to the results, moisture absorption rate was increased as CNT content and exposure temperature were increased. The rate of decrease in tensile strength of the CNT reinforced unsaturated polyester composites was reduced due to the reinforcing effect of CNT compared to the unsaturated polyester resin.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2003.04a
• /
• pp.117-120
• /
• 2003

Electro-micromechanical techniques were applied using four-probe method for carbon nanotube (CNT) or nanofiber (CNF)/epoxy composites with their content. Carbon black (CB) was used to compare with CNT and CNF. The fracture of carbon fiber was detected by nondestructive acoustic emission (AE) relating to electrical resistivity for double-matrix composites test. Sensing for fiber tension was performed by electro-pullout test under uniform cyclic strain. The sensitivity for fiber damage such as fiber fracture and fiber tension was the highest for CNT/epoxy composites, and in CB case they were the lowest compared with CNT and CNF. Reinforcing effect of CNT obtained from apparent modulus measurement was the highest in the same content. The results obtained from sensing fiber damage were correlated with the morphological observation of nano-scale structure using FE-SEM. The information on fiber damage and matrix deformation and reinforcing effect of carbon nanocomposites could be obtained from electrical resistivity measurement as a new concept of nondestructive evaluation.

• Journal of the Korean GEO-environmental Society
• /
• v.23 no.9
• /
• pp.5-16
• /
• 2022

In recent years due to the development of urban and underground space, the number of ground disasters is increasing, and it is also leading to social problems. To solve the problem, a grouting method is generally used. However, the grouting method has material (grout) limitations in permeability, gelation properties and tensile resistance. Therefore, research on grout materials mixed with fibers is actively carried out to improve the problems. However, in the actual ground injection process, many difficulties have been faced causing the blockage of the inlet port and the injection tube. In this study, 'CNT-mixed grout material' was developed using CNT powder that can reinforce the tensile strength of soils. The uniaxial compressive and tensile strength tests were performed to obtain the optimal content and mechanical properties of the CNT Powder-mixed grout. It was found that the optimal CNT powder content is 0.5% that gives the average maximum strength. A one-dimensional injection test and the bulb formation test were carried out, and it was identified that the injection rate and bulb form could be controlled by pressure and mixing ratio. Field application of the CNT-Mixed grout is simulated using numerical analysis of slopes, foundations, and tunnels reinforced in several types. The positive effect of reducing plastic ranges and settlements was confirmed.

• Applied Chemistry for Engineering
• /
• v.22 no.1
• /
• pp.109-113
• /
• 2011

${\alpha},{\omega}$-Hydroxypropylpoly(dimethylsiloxane) was prepared from the reaction of a ${\alpha},{\omega}$-hydrogen polydimethylsiloxane with an allyl alcohol. MPE-g-poly(dimethylsiloxane) copolymer (MPES) was prepared from the graft copolymerization of MPE with ${\alpha},{\omega}$-hydroxypropyl group terminated PDMS. MPES/HDPE/EtO-CNT need to varify was prepared from the compounding of MPES, HDPE, and surface treated MWCNT with 4-ethoxybenzoic acid at $180^{\circ}C$. Melting point of the MPES/HDPE/EtO-CNT composite was decreased from 130 to $129^{\circ}C$ as increasing the content of MWCNT 10 to 20 wt% in the composite PTC characteristic of the MPES/HDPE/EtO-CNT composite was appeared at $120^{\circ}C$ as abruptly increasing the electrical resistivity at this temperature. The heighest PTC intensity of MPES/HDPE/EtO-CNT compsite at 10 wt% loading of EtO-CNT was 1.9.

• Carbon letters
• /
• v.13 no.4
• /
• pp.243-247
• /
• 2012

A fabrication method to improve the processability of thermoplastic carbon nanotube (CNT) mat composites was investigated by using in-situ polymerizable and low viscous cyclic butylene terephthalate oligomers. The electrical conductivity of the CNT mat composites strongly depended on the compression pressure, and the trend can be explained in terms of two cases, low and high compression pressure, respectively. High CNT mat content in the CNT mat composites and the surface of the CNT mat composites with fully contacted CNTs was achieved under high compression pressure, and direct contact between four probes and the surface of the CNT mat composites with fully contacted CNTs gave resistance of $2.1{\Omega}$. In this study the maximum electrical conductivity of the CNT mat composites, obtained under a maximum applied compression pressure of 27 MPa, was 11 904 S $m^{-1}$, where the weight fraction of the CNT mat was 36.5%.

• Journal of Electrochemical Science and Technology
• /
• v.2 no.4
• /
• pp.211-215
• /
• 2011

Flexible sheets consisting of acrylonitrile-butadiene rubber (NBR) and carbon nanotube (CNT) are newly prepared varying the composition (CNT 20-25 wt.%) for use as a current collector of supercapacitor electrodes. The as-prepared CNT/NBR is electrodeposited with aniline using potentiodynamic cyclic voltammetry to yield a polyaniline (PANI)/CNT/NBR composite electrode. It is confirmed that the electrical conductivity of CNT/NBR current collector can be enhanced as the content of CNT increases. Cyclic voltammetry result shows that the sample of PANI/CNT(25 wt.%)/NBR composite achieves a maximum specific capacitance ($134.9\;F\;g^{-1}$) at $5\;mV\;s^{-1}$. Such supercapacitor application is possibly originated from the synergistic effects consisting of higher polarity of nitrile groups in NBR, conducting pathway of CNT, and electroactive property of PANI.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.06a
• /
• pp.223-224
• /
• 2007

In this paper, we investigated resistant immunity of semiconductive shield materials in power cables' ordinary operation temperature. It used EEA(Ethylene Ethyl Acrylate) in base polymer and measured TGA(Thermal Gravimetric Analysis) in controlling contents. It increased pyrolysis temperature in content increasement of CNT(Carbon Nanotubes). As a result, we knew superiority that CNT:CB is 10:0.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.423-428
• /
• 2010

To reduce polarization of electrochemical capacitor based on carbon nanotube, titanium oxide nanoparticles were deposited by ultrasound. The pore distribution of $TiO_2$/CNT nanoparticle exhibited surface area of $341\;m^2g^{-1}$ when $TiO_2$ content was 4 wt %, which was better than that of pristine CNT with surface area of $188\;m^2g^{-1}$. The analyses indicated that titanium oxide (particle diameter < 20 nm) was deposited on the CNT surface. The electrochemical performance was evaluated by using cyclic voltammetry (CV), impedance measurement, and constant-current charge/discharge cycling techniques. The $TiO_2$/CNT composite electrode showed relatively better electrochemical behaviors than CNT electrode by increasing the specific capacitance from $22\;Fg^{-1}$ to $37\;Fg^{-1}$ in 1 M $H_2SO_4$ solution. A symmetric cell assembled with the composite electrodes showed the specific capacitance value of $11\;Fg^{-1}$ at a current loading of $0.5\;mAcm^{-2}$ during initial cycling.