• Analytical Science and Technology
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• v.25 no.3
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• pp.159-163
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• 2012

A spectrofluorimetric method has been developed for the determination of free $CN^-$ in real samples with fluorescent safranine-O. When safranine-O interacts electrostatistically with $CN^-$, the fluorescent intensity of safranine-O is decreased. Several experimental conditions such as pH of the sample solution and the amount of safranine-O were optimized. $Ag^+$ interfered higher than any other ions. Interference of $Ag^+$ could be disregarded because $Ag^+$ was scarcely contained or mostly complexed with $CN^-$ in selected real samples. With this proposed method, the linear range of $CN^-$ was from 5.0 to 110 ng/mL and the detection limit of $CN^-$ was 2.9 ng/mL. For validating this technique, real samples (Cu, Ag, Au electroplating wastewater, and untreated wastewater in university and in sewage treatment plant) were used. Recovery yields of 91.5%~106.0% were obtained. Based on experimental results, it is proposed that this technique can be applied to the practical determination of free $CN^-$.

• Proceedings of the KSRS Conference
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• 2002.10a
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• pp.499-499
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• 2002

The goal of this study is to apply and evaluate the precipitation outflow in river basin using satellite data and GIS for proposing the efficient watershed management method. Not only precipitation outflow data but also various spatial data such as digital map, soil map, geologic map and multi-temporal TM images were used. Using landcover classification result and soil map were applied to estimate the average CN. The CN value of 63.37 by SCS method was produced in AMC-2 condition otherwise the result of direct estimation with observation method was 63 CN value. The relative error of two results was 0.59%. It can be possible to apply the satellite data for precipitation outflow analysis. For more accurate and credible analysis of this, the more multi-temporal satellite and real observation data will be needed.

• Journal of the Korean Electrochemical Society
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• v.23 no.1
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• pp.11-17
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• 2020

The Prussian blue analogues of Fe₂(CN)₆ and Na_xFe₂(CN)₆ are prepared by precipitation method and evaluated the electrochemical characteristics as positive electrode materials for lithium-ion batteries (LIBs) because of their low cost. Fe₂(CN)₆ shows a low reversible capacity of 34.6 mAh g^-1, whereas sodium-containing Na_xFe₂(CN)₆ exhibits a reversible capacity of 107.5 mAh g^-1 when the discharge process proceeds first. When charging is first carried out to remove sodium in the structure, the reversible capacity of 114.1 mAh g^-1 is achieved and the cycle performance is further improved. In addition, Na_x-Fe₂(CN)₆ is synthesized at 0℃, room temperature (RT), and 60℃, respectively. Regardless of the synthesis temperature, Na_xFe₂(CN)₆ shows similar initial reversible capacity, but the crystallite size is formed smaller and improved cycle performance when synthetic temperature is lower. The sample synthesized at 0℃ shows a reversible capacity of 86.4 mAh g^-1 at the 120^th cycle and maintains 76.8% of the initial capacity.

• Clean Technology
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• v.27 no.2
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• pp.168-173
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• 2021

The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

• Journal of Korea Water Resources Association
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• v.48 no.6
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• pp.491-500
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• 2015

In order to improve the runoff estimation accuracy of the Natural Resources Conservation Service (NRCS) curve number (CN) model, this study incorporated rainfall and maximum potential retention as contributors for initial abstraction. The modification was proposed based on 658 rank-order data of rainfall and subsequent runoff from 15 watersheds. The NRCS-CN model (M1), one of its inspired modified model (M2), and the proposed model (M3) were analyzed employing different CN approaches. Using tabulated, calculated and least squares fitted CNs ($CN_T$, $CN_C$, $CN_{LSF}$, respectively), the models' performances were evaluated based on Root Mean Square Error (RMSE), Nash-Sutcliffe Efficiency (NSE), and Percent Bias (PBIAS). Applications of model M1, M2, and M3, respectively exhibited watershed cumulative mean [RMSE (23.60, 18.12, 16.04), NSE (0.54, 0.73, 0.79), and PBIAS (36.54, 20.25, 12.00)]. Similarly, using CNC (for M1 and M2 model) and $CN_{LSF}$ (for M3 model), the performance of three models respectively were assessed based on watershed cumulative mean [RMSE (17.17, 15.88, 13.82), NSE (0.76, 0.80, 0.85), and PBIAS (3.06, 4.47, 0.11)]. The proposed model (M3) that linked all of the NRCS-CN variants showed more statistically significant agreement between the observed and estimated data.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.9 s.180
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• pp.2167-2173
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• 2000

The HANARO (High-flux Advanced Neutron Application Reactor) has operated since 1995. The Cold Neutron(CN) hole was implanted in the reflector tank from the design stage. Before a vacuum chamber and a moderator cell for the cold neutron source are installed into the CN hole, it is necessary to measure the exact size of the inside diameter and thickness of the CN hole to prevent the interference problem. Due to inaccessibility and high radiation field in the CN hole, a mechanical measurement method is not permitted. The immersion ultrasonic technique is considered as the best method to measure the thickness and the diameter. The 4 axis manipulator of the 2 channel of a sensor module was fabricated. The transducer of 10 MHz results in 0.03 nun of resolution. The inside diameter and thickness for 550 points of the CN hole were measured using 2 channel ultrasonic sensors. The results showed that the thickness is in the range of 13-6.7 mm and inside diameter is in the range of o 156-165. These data will be a good reference in the design of a cold neutron source facility.

• Korean Journal of Remote Sensing
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• v.24 no.1
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• pp.35-43
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• 2008

The purpose of this study is to evaluate the hydrological impact due to temporal land cover change by gradual urbanization of upstream watershed of Pyeongtaek gauging station of Anseong-cheon. WMS HEC-1 was adopted, and OEM with 200 m resolution and hydrologic soil group from 1:50,000 scale soil map were prepared. Land covers of 1986, 1990, 1994 and 1999 Landsat TM images were classified by maximum likelihood method. The watershed showed a trend that forest & paddy areas decreased and urban/residential area gradually increased during the four selected years. The model was calibrated at 2 locations (Pyeonglaek and Gongdo) by comparing observed with simulated discharge results for 5 summer storm events from 1998 to 2001. The watershed average CN values varied from 61.7 to 62.3 for the 4 selected years. To identify the impact of streamflow by temporal area change of a target land use, a simple evaluation method that the CN values of areas except the target land use are unified as one representative CN value was suggested. By applying the method, watershed average CN value was affected in the order of paddy, forest and urban/residential, respectively.

• The Journal of the Korea Contents Association
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• v.10 no.12
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• pp.236-242
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• 2010

The porcelain fused metal was made through the progressive fused process of porcelain on substructure of metal material. The substructure was made using novel SLM method. The objective of this study was to observe the color change of porcelain using spectrophotometer equipment according to porcelain fused step and production methods after conducting the process of casting and SLM method of the substructure. The color change by step was indicated that fused opaque porcelain groups(CN1, CC1, CT1, SC1, ST1) had color difference(${\Delta}E$=30) by comparison with fused body porcelain groups(CN2, CC2, CT2, SC2, ST2) and fused glazing porcelain groups(CN3, CC3, CT3, SC3, ST3) (p<0.05). and there was no color difference between the substrates(CN, CC, CT) made by the casting method and the substrates(SC, ST) made by the SLM method. so, the color change was expressed by fused change of porcelain, and this study showed that the color of porcelain fused metal made by the SLM method can be applied clinical trials.

• Microbiology and Biotechnology Letters
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• v.38 no.4
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• pp.373-378
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• 2010

Studies on standardization and quality upgrade of nuruk which is a basic component in brewing are required to increase the quality level of Korean traditional rice wines and to develop the technology for practical use of it. It is important to isolate best strains, to improve the properties and effectively preserve them for brewing industry. In this study, 16 commercial nuruk samples were obtained from the commercial markets located in Chungcheong areas in Korea. 174 fungal strains were isolated from the samples on DG18 medium using a dilution plating method and then screened for enzyme activity and acid production. The active strains were identified based on the morphological characteristics and ITS sequence analysis. Out of 174 strains, 12 strains showed high amylase activity. Especially, Rhizopus sp. CN084, CN174, Aspergillus sp. CN161 and Mycocladus sp. CN042 showed high saccharogenic power and dextrinogenic enzyme activity on cooked wheat bran medium. On the other hand, Aspergillus sp. CN010, CN161, Rhizopus sp. CN105, CN168 and Rhizomucor sp. CN088 produced high acid production on the same medium. Our results showed that the active strains may be used as microbial sources for nuruk starter with good quality in brewing.

• Journal of Korea Water Resources Association
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• v.37 no.5
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• pp.397-406
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• 2004

It is necessary to estimate the groundwater recharge rate properly to evaluate the reasonable development amount of groundwater in a specific site. A small basin in Wicheon River Basin located in the Province of Kyungsangbuk-Do is selected to calculate the groundwater recharge rate. Average annual groundwater recharge rates are calculated from 1992 to 1997 because wet and draught year are contained during this period. In the calculation, baseflow separation method and SCS-CN method are applied to this area. As a result of estimation by baseflow separation method, the value of groundwater recharge ratio is varied between 11.9% and 18.7%. The average annual recharge rate is 14.5%. The average annual recharge rate calculated by SCS-CN method is varied between 7.9% and 20.9%. The average annual recharge rate in the calculation period is 15.1%. The results show that the average annual recharge amount from infiltration in the study basin is 141.6mm and 147.4mm in each estimation method. It appears that the average annual recharge amount calculated for the long period containing wet and draught year by the two methods is useful for groundwater development.