• Title/Summary/Keyword: CMC

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Novel Phenol Resin Carbonizing Method for Carbon Interlayer Coating between Reinforcing Fiber and Matrix in Fiber Reinforced Ceramic Composite (페놀수지 탄화 코팅법을 이용한 섬유강화 복합재료 계면 형성에 관한 연구)

  • Kim, Se-Young;Woo, Sang-Kuk;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.301-305
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    • 2009
  • The novel carbon coating process for interlayer of fiber reinforced ceramic composites between fiber and matrix was performed by carbonizing phenolic resin solution that coated on fiber surface in $N_2$ atmosphere at $600^{\circ}C$ to improve the strength and fracture toughness of CMC(ceramic matrix composite). 160 nm carbon layer was coated on fiber surface with 5 vol% of phenolic resin solution. Since the process temperature ($600^{\circ}C$) is lower than chemical vapor deposition($900{\sim}1000^{\circ}C$), the strength and toughness could be preserved. Furthermore the coating thickness uniformity was improved to 8% of deviation along the stacking sequence. Therefore, prevention from fiber degradation during coating process and controlling coating thickness uniformity along the preform depth were achieved by coating with phenolic resin carbonizing method.

Surfactant enhanced filtration performances of monochlorophenol isomers through low-pressure membrane

  • Kumar, Yogesh;Brahmbhatt, H.;Trivedi, G.S.;Bhattacharya, A.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.137-145
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    • 2011
  • Membrane processes are major breakthrough for the removal of organic pollutants in water remediation. The separations of solutes depend on nature of the membranes and solutes. The separation performance depends on the nature of the solutes (i.e., molecular volume, polarity, and hydrophobicity) for the same membrane. As 4-chlorophenol is of more dipolemoment compared to 2-chlorophenol, the orientation of the molecule enables it pass through the pores of the membrane, which is of negatively charged and thus separation order follows: 2-chlorophenol > 4-chlorophenol. Hydrophobicity factor also supports the order. Addition of sodium dodecyl sulfate (SDS) to chlorophenol solution shows remarkable increase in separation performance of the membrane. The improvement in separation is 1.8 and 1.5 times for 4- and 2- chlorophenol consecutively in case of 0.0082 M SDS (1cmc = 0.0082 M) in the solution. 4-chlorophenol has better attachment tendency with SDS because of its relatively more hydrophobic nature and thus reflects in performance i.e. the separation performance of 4-chlorophenol with SDS through the membrane is better compared to 2-chlorophenol.

Vocabulary assessment based on construct definition in task-based language learning (과제 중심 학습에서 어휘 능력의 구성요소와 평가)

  • Kim, Yeon-Jin
    • English Language & Literature Teaching
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    • v.12 no.3
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    • pp.123-145
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    • 2006
  • The purpose of this study is to propose an efficient vocabulary assessment model in task-based language learning and to verify the viability of this assessment model. Bachman and Palmer (1996) pointed out the fact that many language tests focus on just one of the areas of language knowledge. However, researchers suggested that it is necessary to acknowledge the needs of several analytic scales, which can provide separate ratings for different components of the language ability to be tested. Although there were many studies which tried to evaluate the various aspects of vocabulary ability, most of them measured only one or two factors. Based on previous research, this study proposed an assessment model of general construct of vocabulary ability and tried to measure vocabulary ability in four separate areas. The subjects were two classes of university level Korean EFL students. They participated in small group discussion via synchronous CMC. One class used a lexically focused task, which was proposed by Kim and Jeong (2006) and the other class used a non-lexically focused task. The results showed that the students with a lexically focused task significantly outperformed those with a non-lexically focused task in overall vocabulary ability as well as four subdivisions of vocabulary ability. In conclusion, the assessment model of separate ratings is a viable measure of vocabulary ability and this can provide elaborate interpretation of vocabulary ability.

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Poly(benzyl-L-histidine)-b-Poly(ethylene glycol) Micelle Engineered for Tumor Acidic pH-Targeting, in vitro Evaluation

  • Lee, Eun-Seong;Youn, Yu-Seok
    • Bulletin of the Korean Chemical Society
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    • v.29 no.8
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    • pp.1539-1544
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    • 2008
  • A polymeric micelle, based on the poly(benzyl-L-histidine)-b-poly(ethylene glycol) (polyBz-His-b-PEG) diblock copolymer, was designed as a tumor-specific targeting carrier. The micelles (particle size: 67-80 nm, critical micelle concentration (CMC); 2-3 $\mu$g/mL) were formed from the diafilteration method at pH 7.4, as a result of self-assembly of the polyBz-His block at the core and PEG block on the shell. Removing benzyl (Bz) group from polyBz-His block provided pH-sensitivity of the micellar core; the micelles were physically destabilized in the pH range of pH 7.4-5.5, depending on the content of the His group free from Bz group. The ionization of His group at a slightly acidic pH promoted the deformation of the interior core. These pHdependent physical changes of the micelles provide the mechanism for pH-triggering anticancer drug (e.g., doxorubicin: DOX) release from the micelle in response to the tumor’s extracellular pH range (pH 7.2-6.5).

Effects of Lignocellulosic Growing Media to The Prevention of Forest Soil Erosion

  • Jo, Jong-Soo;Ha, Si Young;Jung, Ji Young;Kim, Ji-Su;Nam, Jeong Bin;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.4
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    • pp.419-431
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    • 2017
  • The forest slopes cause substantial local changes in soil properties and an increase in soil erosion after extreme rainstorms. The high soil erosion rates on forest slopes need the effective use of growing media to control the soil runoff. Therefore, we prepared six different lignocellulosic growing media such as peat, perlite, and wood meal as the base materials and carboxymethyl cellulose (CMC), glucomannan, starch, old corrugated containerboard, and computer printout as the additional materials for the prevention of simulated rainfall-induced runoff. The growing media containing old corrugated containerboard efficiently reduced the percentage of soil runoff; however, it could not completely cushion the influence of crust. The best results for plant growth, except in the leaf area, were also obtained with the growing media containing old corrugated containerboard, suggesting an interesting way of paper recycling and an economic benefit for plant or crop growth in forest slope.

진공 플라즈마 용사 코팅 조건에 따른 초고온 세라믹 코팅의 미세구조

  • Yu, Yeon-U;Jeon, Min-Gwang;Nam, Uk-Hui;Byeon, Eung-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.135-135
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    • 2016
  • 차세대 가스터빈 엔진 및 초음속 항공기 내 고온부의 온도가 증가함에 따라, 기존의 초내열합금 기반 소재를 사용하기 어려워지고 있다. 초고온 세라믹스는 높은 기계적 물성, 화학적 안정성 등 우수한 고온 특성을 가지고 있어 기존의 초고온 소재를 대체 할 수 있는 물질로 부상되고 있다. 하지만 기존의 금속 기반 소재 대비 높은 밀도로 인하여 초고온 세라믹 단일체를 비행체 부품에 적용하기에는 어려움이 있다. 이에 초고온 세라믹스와 탄소섬유를 포함하는 세라믹 복합체(Ceramic Matrix Composite, CMC)를 제작하여 동등한 기계적 물성을 보이면서 무게를 감소시키는 연구들이 진행 중에 있다. 초고온 세라믹스가 함침 된 세라믹 복합체의 경우 우수한 내삭마, 내산화 특성을 보이지만, 장시간 고온에 노출되어 탄소 섬유가 드러나게 되면 급격한 산화로 인해 소재 특성의 열화가 진행되는 단점을 가지고 있다. 따라서, 탄소 섬유가 드러나지 않도록 복합체 표면에 코팅층을 형성하여 세라믹 복합체 모재를 보호하는 방법이 활발히 연구되고 있다. 본 연구에서는 진공 플라즈마 용사 공정을 이용하여 다양한 공정조건 하에서 초고온 세라믹 코팅층을 형성하였다. 수십 마이크론 크기 분포를 갖는 HfC 분말을 Ar 유송 가스를 이용하여 플라즈마 화염 내부로 투입하였다. 플라즈마 화염 가스는 Ar 과 H2를 혼합하여 구성되었으며, 분위기 가스로는 N2를 사용하였다. 코팅에 사용된 모재로는 ZrB2 단일체와 SiC가 미량 포함된 HfC 단일체를 사용하였다. 다양한 공정 조건하에서 형성된 HfC 코팅층의 두께, 미세 조직구조를 SEM을 이용하여 관찰하였으며, XRD를 이용하여 형성된 HfC 코팅층의 결정구조를 분석하였다.

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An Study on the Transitional Flows in a Concentric Annulus with Rotating Inner Cylinder (안쪽축이 회전하는 환형관내 천이 유동 연구)

  • Hwang, Young-Kyu;Kim, Young-Ju
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.45-50
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    • 2001
  • This experimental study concerns the characteristics of a transitional flow in a concentric annulus with a diameter ratio of 0.52, whose outer cylinder is stationary and inner one rotating. The pressure losses and skin-friction coefficients have been measured for the fully developed flow of a 0.2 % aqueous solution of sodium carbomethyl cellulose (CMC) at a inner cylinder rotational speed of $0{\sim}600$ rpm. The transitional flow has been examined by the measurement of pressure losses, to reveal the relation of the Reynolds numbers with the skin-friction coefficients, in the laminar and transitional flow regimes. The occurrence of transition has been checked by the gradient change of pressure losses and skin-friction coefficient with respect to the Reynolds numbers. The increasing rate of skin-friction coefficient due to the rotation is uniform for laminar flow regime, whereas it is suddenly reduced for transitional flow regime and, then, it is gradually declined for turbulent flow regime. Consequently, the critical(axial-flow) Reynolds number decrease as the rotational speed increases. Thus, the rotation of inner cylinder promotes the early occurrence of transition due to the onset of taylor vortices.

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Influence of the Binder Types on the Electrochemical Characteristics of Si-C Composites Electrode in LIBs (Si-C 복합체 전극의 바인더 종류에 따른 전기화학적 특성 변화)

  • Jung, Sung-Hun;Ji, Mijung;Park, Geunyeong;Hong, Jongill;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.168-172
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    • 2013
  • This work presents the effects of binders on the electrochemical performance of Si-C composites as the anode of lithium ion batteries. PAI (polyamide-imide) was used as an organic binder, and PAN (polyacrylonitrile), PAA (polyacrylic acid) and CMC + SBR (carboxymethyl cellulose + styrene-butadiene rubber) were used as aqueous binders. As a result, stabilization time for the cell with a Si-C composite anode synthesized using aqueous binders became shorter than an organic binder. Particularly in the case of the cell using PAA binder, better performance was observed in terms of adhesion strength, initial efficiency, the volume expansion ratio, Coulombic efficiency, and capacity retention.

Experimental Study on the Vortex Flow in a Concentric Annulus with a Rotating Inner Cylinder

  • Kim, Young-Ju;Hwang, Young-Kyu
    • Journal of Mechanical Science and Technology
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    • v.17 no.4
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    • pp.562-570
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    • 2003
  • This experimental study concerns the characteristics of vortex flow in a concentric annulus with a diameter ratio of 0.52, whose outer cylinder is stationary and inner one is rotating. Pressure losses and skin friction coefficients have been measured for fully developed flows of water and of 0.4% aqueous solution of sodium carboxymethyl cellulose (CMC), respectively, when the inner cylinder rotates at the speed of 0~600 rpm. Also, the visualization of vortex flows has been performed to observe the unstable waves. The results of present study reveal the relation of the bulk flow Reynolds number Re and Rossby number Ro with respect to the skin friction coefficients. In somehow, they show the existence of flow instability mechanism. The effect of rotation on the skin friction coefficient is significantly dependent on the flow regime. The change of skin friction coefficient corresponding to the variation of rotating speed is large for the laminar flow regime, whereas it becomes smaller as Re increases for the transitional flow regime and. then, it gradually approach to zero for the turbulent flow regime. Consequently, the critical (bulk flow) Reynolds number Re$\_$c/ decreases as the rotational speed increases. Thus, the rotation of the inner cylinder promotes the onset of transition due to the excitation of Taylor vortices.

Studies on the N-Acyl Amino Acid Type Surfactants(4) Surface Active Properties of N-Acyl-N-Methyl-β-Alanine Salts (N-아실 아미노산계 계면활성제에 관한 연구 (제 4 보) N-아실-N-메틸-β-알라닌 염류의 계면활성)

  • No, Seung-Ho;Lee, Sun-Ju;Kim, Tae-Young;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.2 no.3
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    • pp.216-221
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    • 1991
  • Surface activities of four potassium N-acyl-N-methyl-${\beta}$-alaninate including surface tension, foaming power, foam stability, emulsifying power and dispersion power were measured respectively, and critical micelle concentration(cmc) was evaluated. Consequently these anionic surfactants with long chain acyl amide showed good emusifying power of O/W type, foaming, foam stability and dispersion effect.

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