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IR Study on the Adsorption of Carbon Monoxide on Silica Supported Ruthenium-Nickel Alloy (실리카 지지 루테늄-니켈 합금에 있어서 일산화탄소의 흡착에 관한 IR 연구)

  • Park, Sang-Youn;Yoon, Dong-Wook
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.349-356
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    • 2006
  • We have investigated adsorption and desorption properties of CO adsorption on silica supported Ru/Ni alloys at various Ru/Ni mole content ratio as well as CO partial pressures using Fourier transform infrared spectrometer (FT-IR). For Ru-$SiO_{2}$ sample, four bands were observed at $2080.0cm^{-1}$, $2021.0{\sim}2030.7cm^{-1}$, $1778.9{\sim}1799.3cm^{-1}$, $1623.8cm^{-1}$ on adsorption and three bands were observed at $2138.7cm^{-1}$, $2069.3cm^{-1}$, $1988.3{\sim}2030.7cm^{-1}$ on vacumn desorption. For Ni-$SiO_{2}$ sample, four bands were observed at $2057.7cm^{-1}$, $2019.1{\sim}2040.3cm^{-1}$, $1862.9{\sim}1868.7cm^{-1}$, $1625.7cm^{-1}$ on adsorption and two bands were observed at $2009.5{\sim}2040.3cm^{-1}$, $1828.4{\sim}1868.7cm^{-1}$ on vacumn desorption. These absorption bands correspond with those of the previous reports approximately. For Ru/Ni(9/1, 8/2, 7/3, 6/4, 5/5; mole content ratio)-$SiO_{2}$ samples, three bands were observed at $2001.8{\sim}2057.7cm^{-1}$, $1812.8{\sim}1926.5cm^{-1}$, $1623.8{\sim}1625.7cm^{-1}$ on adsorption and three bands were observed at $2140.6cm^{-1}$, $2073.1cm^{-1}$, $1969.0{\sim}2057.7cm^{-1}$ on vacumn desorption. The spectrum pattern observed for Ru/Ni-$SiO_{2}$ sample at 9/1 Ru/Ni mole content ratio on CO adsorption and on vacumn desorption is almost like the spectrum pattern observed for Ru-$SiO_{2}$ sample. But the spectrum patterns observed for Ru/Ni-$SiO_{2}$ samples under 8/2 Ru/Ni mole content ratio on CO adsorption and vacumn desorption are almost like the pattern observed for $Ni-SiO_{2}$ sample. It may be suggested surfaces of alloy clusters on the Ru/Ni-$SiO_{2}$ samples contain more Ni components than the mole content ratio of the sample considering the above phenomena. With Ru/Ni-$SiO_{2}$ samples the absorption band shifts may be ascribed to variations of surface concentration, strain variation due to atomic size difference, variation of bonding energy and electronic densities, and changes of surface geometries according to surface concentration variation. Studies for CO adsorption on Ru/Ni alloy cluster surface by LEED and Auger spectroscopy, interation between Ru/Ni alloy cluster and $SiO_{2}$, and MO calculation for the system would be needed to look into the phenomena.

Dose distribution at junctional area abutting X-ray and electron fields (X-선과 전자선의 인접조사에서 접합 조사면에서의 선량분포)

  • Yang, Kwang-Mo
    • The Journal of Korean Society for Radiation Therapy
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    • v.16 no.1
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    • pp.91-99
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    • 2004
  • Purpose : For the head and neck radiotherapy, abutting photon field with electron field is frequently used for the irradiation of posterior neck when tolerable dose on spinal cord has been reached. Materials and methods : Using 6 MV X-ray and 9 MeV electron beams of Clinac1800(Varian, USA) linear accelerator, we performed film dosimetry by the X-OMAT V film of Kodak in solid water phantom according to depths(0 cm, 1.5 cm, 3 cm, 5 cm). 6 MV X-ray and 9 MeV electron(1Gy) were exposes to 8cm depth and surface(SSD 100cm) of phantom. The dose distribution to the junction line between photon($10cm{\times}10cm$ field with block) and electron($15cm{\times}15cm$ field with block) fields was also measured according to depths(0 cm, 0.5 1.5 cm, 3 cm, 5 cm). Results : At the junction line between photon and electron fields, the hot spot was developed on the side of the photon field and a cold spot was developed on that of the electron field. The hot spot in the photon side was developed at depth 1.5 cm with 7 mm width. The maximum dose of hot spot was increased to $6\%$ of reference doses in the photon field. The cold spot in the electron side was developed at all measured depths(0.5 cm-3 cm) with 1-12.5 mm widths. The decreased dose in the cold spot was $4.5-30\%$ of reference dose in the electron field. Conclusion : When we make use of abutting photon field with electron field for the treatment of head and neck cancer we should consider the hot and cold dose area in the junction of photon and electron field according to location of tumor.

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Measurement of Ultrasonic Field Propagation Characteristics in Biological Tissues Using a Two-dimensional Array Hydrophone (2차원 배열 수중청음기를 이용한 생체조직에서의 초음파 음장 전파특성 측정)

  • ;;;;Xiu-Fen Gong
    • The Journal of the Acoustical Society of Korea
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    • v.20 no.5
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    • pp.76-82
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    • 2001
  • Because the biological tissue with inhomogeneous acoustic properties does not keep a particular shape, the measurement of propagation characteristics of ultrasonic fields by the conventional scanning method with a miniature hydrophone is difficult. In this study, a two-dimensional may hydrophone was fabricated using the PVDF (Polyvinylidene fluoride) piezo-electric film and a ultrasonic field measurement system with it was established. For the acoustic field produced by a circular plan transducer with center frequency of 2.25㎒ and 13㎜ in diameter, it was possible to make a fairly accurate field measurement using the hydrophone system. The attenuation coefficients at 2.25 ㎒ for biological tissues were 0.7∼1.3 dB/cm(average; 1.0 dB/cm) in bovine liver, 1.0∼1.8 dB/cm (average; 1.6 dB/cm) in pig liver, 0.9∼2,9 dB/cm(average: 2.1 dB/cm) in bovine muscles, 1.7∼3.3 dB/cm (average; 2.5 dB/cm) in pig muscles.

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Effects of Seedling Ages on Growth and Yield of Cynanchum wilfordii $H_{EMSLY}$ (백하수오(白何首烏)의 묘령(苗齡)에 따른 생육(生育)과 수량(收量))

  • Choi, In-Sik
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.2
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    • pp.121-125
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    • 1998
  • This experiment was carried out to investigate the effects of direct seeding and planting of seedlings in different ages on yield and yield characteristics of Cynanchum wilfordii $H_{EMSLY}$. Emergence date was three days earlier in direct seeding compared to May 14 in plots planted with one - or three - year - old seedlings. Petiole length was 16cm and 26cm longer in direct seeding and 1 - year - old seedlings, respectively, compared to 279cm in plot of 3 - year - old seedling. Root diameter was 0.4cm thicker in direct seeding and 0.5cm thicker in 1 - year - old seedlings compared to 1.0cm in seedlings of three years old. Root length was 7.2cm shorter in direct seeding, but was 0.6cm longer in 1 - year - old seedlings than 32.2cm in seedlings of three years old. Yield increased by 29 % in direct seeding and 55% in seedlings of one year old compared to 1,403kg/l0a in 3 - year - old seedlings. In cultivation of Cynanchum wilfordii $H_{EMSLY}$, the suitable planting methods were direct seeding or the use of 1 - year - old seedlings which were profitable at higher density as $50{\times}10cm$.

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Effect of Planting Density on Growth and Yield in Cyanachum wilfordii (백가수도의 재식밀도에 따른 생육 및 수량)

  • 최인식
    • Korean Journal of Plant Resources
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    • v.8 no.2
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    • pp.209-215
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    • 1995
  • This experiment was carried out to elucidate the effect of row width and hill space on growth and yield in cynanchum wilfordii on experimental fields of chungbuk Provincial Rural Development Administration. Emergence date was May 25 and had no differences between planting density. Vine length was 219cm with row 40cm, 220cm, with 50cm and 225cm with 60cm, and in hill spaces, it was 225cm with hill space 10cm, 219cm with 15cm, and 218cm with 20cm. No. of leaves was same tendencies to vine length and was more increased as the hill space was narrower. Root length was longer about 0.9cm to 1.4cm as the hill space was wider, and no. of root had no difference between planting tensity. Yield was more increased row width was wider and was decreased hill space was wider. And the profitalble planting density was row width 50cm and hill space 10cm in the cultivation cynanchum wilfordii.

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Annual Carbon Storage by Fine Root Production in Quercus variabilis Forests (충주지역 굴참나무림의 세근에 의한 탄소축적)

  • 박관수;임재구
    • Korean Journal of Environment and Ecology
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    • v.17 no.4
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    • pp.360-365
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    • 2004
  • This study was carried out to estimate net fine root carbon production in Quercus variabilis natural stands in Chungiu area. Soil samples were taken in 0-30cm, 30-60cm, and 60-90cm soil depths from April to November using soil sampler. Fine root carbon biomass was higher in 0-30cm soil depth than the other soil depths. Net fine root carbon production (kg/㏊/yr) were 671kg in 0-30cm soil depth, 599kg in 30-60cm soil depth, and 479kg in 60-90cm soil depth, and 1749kg in 0-90cm soil depth. fine root turnover rates were 0.43 in 0-30cm soil depth, 0.96 in 30-60cmsoil depth, and 1.03 in 60-90cm soil depth. N, p, K, and Mg input into the soil (kg/㏊/yr) due to fine root turnover at 0-90cm soil depth in this study were 33.9kg, 1.8kg, 11.4kg and 20.1kg, respectively.

Seasonal Changed of Microbial Population in the Field Soil (계절에 따른 토양중 미생물의 밀도 변화)

  • Park, Dong-Jin;Lee, Sang-Hwa;Kim, Chang-Jin
    • Korean Journal of Microbiology
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    • v.34 no.3
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    • pp.144-148
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    • 1998
  • Soil microorganisms including bacteria, fungi, and actinomycetes were seasonally isolated at depths (0.5~2, $10{\pm}1$, $50{\pm}1cm$) of field. The frequency of microbial isolates was employed for the determination of microbial population (CFU/g dry soil) and distribution ratio (%) in soil. Both bacteria (24-fold) and actinomycetes (7-fold) exhibited the biggest change at the depth of $50{\pm}1cm$, whereas fungi showed the maximum (13-fold) at $10{\pm}1cm$. On the whole, the bacterial population was high in spring soil, fungi in winter, and actinomycetes in autumn. Soil microorganisms also exhibited the seasonal variation on their distribution ratio (%). The maximum distribution ratio (85.7%) of bacteria was observed at the depth of $50{\pm}1cm$ in spring, whereas bacteria showed the minimum (35.2%) at the depth of $10{\pm}1cm$ in spring. The maximum distribution ratio (23.0%) of fungi was found at the depth of $50{\pm}1cm$ in spring, whereas its minimum (0.5%) at the depth of $10{\pm}1cm$ in spring. Actinomycetes exhibited the maximum distribution ratio (45.2%) at the depth of $10{\pm}1cm$ in spring, whereas its minimum (12.2%) was showed at the depth of $50{\pm}1cm$ in spring.

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Using Image J program, compared of focusing distance and grid rate (Image J 프로그램을 이용한 격자집속거리와 격자비에 따른 영상비교평가)

  • Seo, Won-Joo;Seo, Jeong-Beom;Lee, Jong-Woong
    • Korean Journal of Digital Imaging in Medicine
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    • v.14 no.1
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    • pp.37-42
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    • 2012
  • Pediatric head and neck phantom, using the rate by focusing distance and grid images, Image J using the Quality Assessment and Dose Area Product compared. X-ray laboratory equipment due to the Philips Digital DIAGNOST a 110 cm FFD set and using ACE Non-grid, focusing distance 110 cm (12 : 1), 140 cm (12 : 1), 180 cm (8 : 1) Focused grid, Acryl Phantom (Fluke Model 76-2 Series Phantom) 15.24 cm, by resolution chart image acquisition, image evaluation program (Image J Ver. 1.4.3.67, USA) imaging experiments were analyzed using. Dose Area Product in the Non Grid 0.028 $mGy{\cdot}cm^2$, focusing distance 110 cm (12 : 1), the 0.129 $mGy{\cdot}cm^2$, 140 cm (12 : 1), the 0.135 $mGy{\cdot}cm^2$, 180 cm (8 : 1) was measured with a 0.110 $mGy{\cdot}cm^2$ Non Grid, focusing distance 110 cm (12 : 1), 140 cm (12 : 1), 180 cm (8 : 1) Image obtained when grid using the image J program focusing distance 110 cm with grid based on the measured SNR and PSNR Non Grid if the SNR the 17.307 dB, PSNR of the 20.002 dB, if the SNR 28.755 dB, PSNR was measured by the 31.451 dB. Image J image analysis through the streets, rather than focusing on grid by the rate that could see an increase in dose. Select the grid by a small dose rate reduction is possible.

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A Study of Gait Imbalance Determination System based on Encoder, Accelerometer and EMG sensors (인코더, 가속도, 근전도 센서 기반의 보행불균형 판단 시스템 연구)

  • Park, Yong-Deok;Kim, Sang-Kyun;Kwon, Jang-Woo;Lee, Sang-Min
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.10 no.2
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    • pp.155-162
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    • 2016
  • The purpose of this study was to determine the walking imbalance using the EMG(electromyogram). To confirm the effectiveness of the proposed encoder and acceleration, EMG sensor based gait imbalance determination system. This experiment was carried out to evaluation with a healthy adult male to 10 people. The Encoder device is attached to the hip and knee joint in order to measure the gait signal. The Accelerometer sensors are attached on the ankle. The EMG sensors are attached on the vastus lateralis and anterior tibialis. SI(Symmetry Index) was used as an index for determining the gait imbalance. To confirm if the judgment has been made correctly, the heel, regarded as the cause of unbalanced ambulation, was adjusted from 0 cm to 6 cm with intervals of 1.5 cm. In the cases of the encoder and the EMG, the difference of 0 cm and 1.5 cm is determined into normal walk but the other difference is distinguished into gait imbalance. In the case of the accelerometer, the difference of 0 cm, 1.5 cm and 3 cm is determined into normal walk but the other difference is distinguished into gait imbalance.

A Study on the Development of Ready-to-wear Garment Size for their Early 20's by Body type and Basic Blocks for Women's Dress (20대 전반 여성의 체형별 기성복 치수설정과 원형개발에 관한 연구)

  • 이형숙;임영자
    • Journal of the Korean Society of Costume
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    • v.50 no.3
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    • pp.87-104
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    • 2000
  • The women's apparel sizing system, currently used in the Korean industry, does not reflect measurement differences associated with varying body types and age. Forty five body meaqsurements were taken on 560 subjects, whoes eages ranged from 18-24. STatistical analysis of the data was coducted by using frequences, crosstables, correlation, oneway ANOVA, Regressio analysis. The results of this study were as follow. 1. Average height of women in their early 20's is 160cm, average bust girth 82cm, average hip girth 90cm and average drop 809. The correlation between height and grth items were low and the correlation of length items in the superior and inferior body were shown to bo high respectively. 2. The average Rhrer index is 1.28 and they ussually seem to be in the thin and standard body group. 3. body types were divided by differences between hip and bust sizes. N type(medium hip), A type (large hip), H type(small hip). A classification by body type showed that N type made up 58% while a type made up 24%. 4. The garment sizes for women in their early 20's were developed. 5. The new basic blocks and garment sizes for women in their early 20's were developed as follows : Bust girth (1/2) = 76N, 76A, 79A type($\frac{1}{2}$B+ 4cm) 79N type($\frac{1}{2}$B+ 3.5cm) 82N, 85N type ($\frac{1}{2}$B +3cm) Hip girth($\frac{1}{2}$) =N type($\frac{1}{2}$H + 2~2.5cm) Atype($\frac{1}{2}$H +1.5~2cm) Waist girth($\frac{1}{2}$)=$\frac{1}{2}$W + 2-3cm Back length =extimated measure -0.5cm Front length=76A, N (Back length + 2.2cm) 79A, N(back length +2.7cm) 82N(Back length +3.2cm) 85N(Back length + 3.7cm) Sleeve length=Sleeve length +3cm.

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