• 제목/요약/키워드: CE

검색결과 3,019건 처리시간 0.027초

CeO2의 첨가량 변화에 따른 세리아 안정화 지르코니아 세라믹스의 기계적 특성 관찰 (Mechanical Properties Observation of Ce-TZP Ceramics by Quantity Change of CeO2)

  • 강종봉
    • 한국세라믹학회지
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    • 제47권5호
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    • pp.439-444
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    • 2010
  • The usual ceramic process of mixing and milling in state of oxide of $ZrO_2$ and $CeO_2$ was adopted in wet process to manufacture Ce-TZP in this study. The maximum dispersion point of every slurry manufactured with mixture of $ZrO_2$ and $CeO_2$ was neat at pH10. The stable slurry in average particle size of 90 nm can be manufactured when it is dispersed with use of ammonia water and polycarboxylic acid ammonium. The sintered Ce-TZP ceramics manufactured with addition of $CeO_2$ less than 10 mol% was progressed to the fracture of specimen due to the monoclinic phase existence more than 30% at the room temperature. More than 99% of tetragonal phase was created for the sintered body with addition of $CeO_2$ beyond 18 mol%, but the mechanical property degrade on the entire specimen was brought due to the $CeO_2$ existing above 3%. Consequently, the optimal Ce-TZP combined in oxide state was identified in 16 mol% of $CeO_2$ contents.

Ar/CF4/Cl2 플라즈마에 의한 CeO2 박막의 식각 특성 연구 (A Study on Etch Characteristics of CeO2 Thin Film in An Ar/CF4/Cl2 Plasma)

  • 장윤성;김동표;김창일;장의구
    • 한국전기전자재료학회논문지
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    • 제15권5호
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    • pp.388-392
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    • 2002
  • In this work, the etching of $CeO_2$ thin films has been performed in an inductively coupled $Ar/CF_4/Cl_2$ plasma. The highest etch rate of the $CeO_2$ thin film ws 250 ${\AA}/min$ and the selectivity of CeO$_2$to SBT was 0.4 at a 10% additive $Cl_2$ into Ar/($Ar+CF_4$)gas mixing ratio of 0.8. From result of X-ray photoelectron spectroscopy (XPS) analysis, there are Ce-Cl and Ce-F bonding by chemical reaction between Cl, F and Ce. During the etching of $CeO_2$ thin films in $Ar/CF_4/Cl_2$ plama, Ce-Cl and Ce-F bond is formed, and these prodcuts can be removed by the physical bombardment of Ar ions. The 10% additive $Cl_2$ into the Ar/($Ar+CF_4$)gas mixing ratio of 0.8 could enhance the reaction between Cl, F and Ce.

Inhibitory Effect of Benzoate-intercalated Hydrotalcite with Ce3+-loaded clay on Carbon Steel

  • Thuy Duong Nguyen;Thu Thuy Pham;Anh Son Nguyen;Ke Oanh Vu;Gia Vu Pham;To Thi Xuan Hang
    • Corrosion Science and Technology
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    • 제22권1호
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    • pp.1-9
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    • 2023
  • This work studied the inhibitory effect of the combination of benzoate-intercalated hydrotalcite (HT-BZ) and Ce3+-loaded clay (Clay-Ce) on carbon steel (CS). HT-BZ was prepared by the co-precipitation method and Clay-Ce was fabricated by a cation exchange reaction. HT-BZ and Clay-Ce were assessed by scanning electron microscopy (SEM) and X-ray diffraction (XRD) coupled with zeta potential measurement. Electrochemical measurements coupled with scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX) were used for studying the inhibitory action of the mixture of HT-BZ and Clay-Ce on steel electrodes immersed in 0.1 M NaCl. For comparison, the inhibitory effect of HT-BZ or Clay-Ce alone was also evaluated. The results showed that HT-BZ combined with Clay-Ce provided synergistic inhibition of the CS substrate. The mixture of 0.5 g/L HT-BZ + 0.5 g/L Clay-Ce provided 93.5% inhibition efficiency. The protective mechanism of the HT-BZ + Clay-Ce mixture consisted of the reaction of released BZ and Ce3+ and the deposition of HT-BZ and Clay-Ce structures on the CS substrate.

저항전분이 흰쥐의 에너지 영양소 이용효율에 미치는 영향 (Effect of Resistant Starch on Availability of Energy Nutrients in Rats)

  • 오승호
    • Journal of Nutrition and Health
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    • 제33권4호
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    • pp.365-373
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    • 2000
  • The purpose of this study was to compare the nutritional effects of resistant starch, cellulose and pectin on growth rate, metabolic energy and apparent digestibility in rats. Forty eight male Sprague-Dawley rats were randomly assigned to six dietary treatments, Rats were fed, ad libitum one of six experimental diets: 5% of resistant starch (RS), 5% of cellulose (CE), 5% of pection(PT), 2.5% resistant starch and 2.5% cellulose(RS+CE), 2.5% resistant starch and 2.5% pectin(RS+PT), and 2.5% cellulose and 2.5% pectin (CE+PT) during 4 weeks. The results obtained were as follows: body weight gain were higher in groups RS and CE, compared with that in the group PT, where other groups such as RS+CE, RS+PT and CE+PT showed no significant differences to the RS group. Food intake and food efficiency into showed the same patterns. Metabolic energy were similar in the RS and CE, and was the lowest the metabolic energy in the group CE+PT was significantly low. Apparent digestibility of protein was significantly higher in the group RS, compared with the groups CE and PT. Apparent digestibility of mixed dietary fiber groups such as the RS+CE, RS+PT and CE+PT group were also higher compared with the group PT. Apparent digestibility of lipid were significantly higher in the groups RS, CE and PT. Apparent digestibility of lipid in the mixed pectin groups such as the RS+PT and CE+PT growth rate, metabolic energy and apparent digestibility of lipid in the mixed pectin groups such as the RS+PT and CE+PT recorded the lowest, while that of the group RS+CE was significantly high. From above results, following was concluded: The growth rate, metabolic energy and apparent digestibility of protein and lipid of group RS were significantly higher in comparision with the group PT, while availability of energy nutrients of group CE was similar to that of the group RS. Also resistant starch fed with pectin(RS+PT) seemed to have increased the growth rate and the apparent digestibility of protein compared with those of the group PT fed with pectin(PT) alone, however RS+PT scemed to have the apparent digestibility of lipid.

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졸-겔 세라믹 코팅에 의한 스테인레스강의 내산화 및 내식성 향상에 관한 연구 (II);$CeO_2$ 안정화 지르코니아 박막의 내산화 및 내식성 효과 (A Study on the Improvement of Oxidation and Corrosion Resistance of Stainless Steel by Sol-Gel Ceramic Coating (II); Effect on Oxidation and Corrosion REsistance of $CeO_2$ Stabilized Zirconia Thin Film)

  • 이재호;우일기;김병호
    • 한국세라믹학회지
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    • 제32권1호
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    • pp.95-105
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    • 1995
  • Ceria(CeO2) stabilized zirconia(CeSZ) sol was synthesized with zirconium n-butoxide Zr(OC4H9)4 and cerium nitrate hexahydrate Ce(NO3)3.6H2O as precursors and ethylacetoacetate(EAcAc) as a chelating agent under atmosphere. CeSZ films were deposited on AISI 304 stainless steel using the prepared polymeric sol by dipcoating and the coating characteristics were investigated by XRD, ellipsometry, scratch test and SEM. The CeSZ film began to crystallize from amorphous to tetragonal phase at 40$0^{\circ}C$ and it was not converted into monoclinic phase up to 100$0^{\circ}C$ by the addition of 16mol% CeO2 as a stabilizer which could suppress phase transformation of zirconia. The CeSZ films were prepared by varying the EAcAc contents and the cncentration of CeSZ sol and measured the thickness and refractive index. From these results, it was found that the EAcAc contents and concentration of CeSZ coating sol evidently affect the densification of CeSZ film. The CeSZ film coated with 0.4M CeSZ sol and heat-treated at $600^{\circ}C$ for 10min had thickness of 50nm and 17% porosity. The CeSZ film on 304 stainless steel effectively acted as a protective layer against oxidation up to 80$0^{\circ}C$ and had superior corrosion resistance in 25% H2SO4 solution for 4.5 hrs.

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How did Elementary Teachers Handle Critical Experiments in Science Classrooms?

  • 권성기
    • 한국초등과학교육학회지:초등과학교육
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    • 제28권2호
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    • pp.105-120
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    • 2009
  • Critical Experiments (CE) in science classrooms mean, tentatively, critical situations as comparable to anomalous cases in scientific revolutions where the results of science experiments in schools are unclear, differ from the theory, or students misunderstand the purpose of the experiments. The purpose of this research is to identify what CE occurred during science classes and to investigate how elementary teachers handled them. To analyze how teachers recognized and handled CE, we selected nine typical CE from the $7^{th}$ Korean science curriculum. 125 teachers were selected from 8 districts' elementary schools in a local city. A questionnaire with photos of the nine CE above-mentioned was distributed to these teachers. The focus in this research was the way that each teacher handled the CE. We discovered that there were three basic ways in which teachers handled CE. When CE occurred, 51% of elementary teachers explained the correct result of the experiment (what should have happened) to the students while 40.7% of the teachers repeated to get the correct results. The focuses of handling CE varied. 57 % of the teachers focused on the 'materials' while 30% of the teachers focused on the 'theory'. The other focus was 'thinking'. Only 7.6% of the teachers answered that they gave students a chance to think about the reasons why the CE happened. By analyzing our survey results, we could determine what each teacher did as a follow up to the CE and their focus and reasoning for handling the CE this way. When the CE happened in the science class, few handled the CE with the point of view about purpose of doing experiment. As a result, students could not gain educational experience from the CE. If we use CE as a new method to teach science, it will be a good subject incorporating the nature of science in science education.

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Analysis of Structure and Expression of Grapevine 2-oxoglutarate Oxygenase Genes in Response to Low Temperature

  • Kim, Seon Ae;Ahn, Soon Young;Yun, Hae Keun
    • 원예과학기술지
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    • 제34권1호
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    • pp.46-54
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    • 2016
  • 2-Oxoglutarate (2OG) acts as a signaling molecule and plays a critical role in secondary metabolism in a variety of organisms, including plants. Six 2-oxoglutarate (2OG) and Fe(II) oxygenase (2OGO) genes, VlCE2OGO1 [Vitis labruscana 2-oxoglutarate (2OG) and Fe(II) oxygenase 1], VlCE2OGO2, VlCE2OGO3, VlCE2OGO4, VlCE2OGO5, and VlCE2OGO6, which show different expression patterns upon transcriptome analysis of 'Campbell Early' grapevine exposed to low temperature for 4 weeks, were analyzed for their structure and expression. Comparison of the deduced amino acid sequences of the 2OGO genes from the V. labruscana transcripts revealed sequence similarities of 38.6% (VlCE2OGO1 and VlCE2OGO2) to 19.2% (VlCE2OGO2 and VlCE2OGO3). The lengths of these genes ranged from 1053 to 2298 bp, and they encoded 316 to 380 amino acids. The prediction of the secondary structure of the encoded proteins by Self-Optimized Prediction Method with Alignment (SOPMA) indicated that all the genes contained alpha helix (23.95 to 41.71%), extended strand (16 to 22.34%), beta turn (6.65 to 9.22%), and random coil (32.97 to 51.58%) in the analysis. Specific primers from unique regions in each gene obtained by alignment of nucleotide sequences were used in real time PCR for analysis of gene expression. All tested genes showed differential expression in grapevines exposed to low temperature. Of the six transcripts, VlCE2OGO1, VlCE2OGO2, and VlCE2OGO3 were up-regulated and VlCE2OGO4, VlCE2OGO5, and VlCE2OGO6 were down-regulated in response to cold treatments at all tested time points. The 2OG genes can be used for elucidation of mechanisms of tolerance to cold and as valuable molecular genetic resources for selection in breeding programs for cold-hardy grapevines.

PDA 용 Windows CE 파일 시스템 설계 (Design of the Windows CE File System for PDA System)

  • 김기환;남진우;장승주
    • 한국정보과학회:학술대회논문집
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    • 한국정보과학회 2004년도 봄 학술발표논문집 Vol.31 No.1 (A)
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    • pp.142-144
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    • 2004
  • 본 논문은 Windows CE의 파일 시스템을 개발하기 위해 필요한 Windows CE .NET 4.0이 제공하는 Platform Builder 통합 개발 환경 툴을 이용하여 파일 시스템 필터를 사용하여 파일시스템을 설계한다. 그리고, Windows CE 에서 사용하는 파일 시스템 필터 encfilt.dll를 이용하여 Windows CE 파일 시스템을 개발할 수 있는 환경을 설정한다.

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고밀도 유도결합 $C1_2CF_4Ar$ 플라즈마를 이용한 $CeO_2$ 박막 식각후 표면반응에 관한 연구 (An Investigation on the Surface Reactions after the Etching of $CeO_2$ Thin Films using High Denstity Inductively Coupled $C1_2CF_4Ar$Ar Plasmas)

  • 장윤성;김남훈;김경섭;이병기;엄준철;김태형;장의구
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
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    • pp.255-258
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    • 2002
  • In this study, $CeO_2$thin films were etched with an addition of $Cl_2$gas to $Ar/CF_4$gas mixing in an inductively coupled plasma(ICP) etcher. The surface reactions of the etched $_CeO2$thin films were investigated by X-ray photoelectron spectroscopy(XPS). It was analyzed that Ce peaks were mainly observed in Ce-O bonds formed $CeO_2$or $CeO_3$compounds. Cl peaks were detected by the peaks of Cl $2p_{3/2}$ and Cl $2p_{1/2}$. Almost all of Cl atoms were combined with Ce atoms like $CeCl_{x}$ compounds.

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Fabrication and thermal conductivity of CeO2-Ce3Si2 composite

  • Ahn, Jungsu;Kim, Gyeonghun;Jung, Yunsong;Ahn, Sangjoon
    • Nuclear Engineering and Technology
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    • 제53권2호
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    • pp.583-591
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    • 2021
  • Various compositions of CeO2-Ce3Si2 (0, 10, 30, 50, and 100 wt%Ce3Si2) composites were fabricated using conventional sintering and spark plasma sintering. Lower relative density, enhanced interdiffusion of oxygen and silicon, and silicide agglomerations from the congruent melting of Ce3Si2 at 1390 ℃ were only observed from conventionally-sintered pellets. Thermal conductivity of spark plasma sintered CeO2-Ce3Si2 composites was calculated from the measured thermal diffusivity, specific heat, and density, which exhibited dense (>90 %TD) and homogeneous microstructure. The composite with 50 wt%Ce3Si2 exhibited 55% higher thermal conductivity than CeO2 at 500 ℃, and 81% higher at 1000 ℃.