Browse > Article
http://dx.doi.org/10.4191/KCERS.2010.47.5.439

Mechanical Properties Observation of Ce-TZP Ceramics by Quantity Change of CeO2  

Kang, Jong-Bong (Nano Egineering, Kyungnam University)
Publication Information
Journal of the Korean Ceramic Society / v.47, no.5, 2010 , pp. 439-444 More about this Journal
Abstract
The usual ceramic process of mixing and milling in state of oxide of $ZrO_2$ and $CeO_2$ was adopted in wet process to manufacture Ce-TZP in this study. The maximum dispersion point of every slurry manufactured with mixture of $ZrO_2$ and $CeO_2$ was neat at pH10. The stable slurry in average particle size of 90 nm can be manufactured when it is dispersed with use of ammonia water and polycarboxylic acid ammonium. The sintered Ce-TZP ceramics manufactured with addition of $CeO_2$ less than 10 mol% was progressed to the fracture of specimen due to the monoclinic phase existence more than 30% at the room temperature. More than 99% of tetragonal phase was created for the sintered body with addition of $CeO_2$ beyond 18 mol%, but the mechanical property degrade on the entire specimen was brought due to the $CeO_2$ existing above 3%. Consequently, the optimal Ce-TZP combined in oxide state was identified in 16 mol% of $CeO_2$ contents.
Keywords
Cerium dioxide; Ce-TZP; Dispersion; Tetragonal phase; DTS;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By SCOPUS : 1
연도 인용수 순위
1 H.S. Shin and S.J. Kwon, "Ritveld Analysis of Powder Xray diffraction Pattern," Sci. Technol. Ceram., 8 [2] 166 (1993).
2 E. Dow Whitney, "Effect of Pressure on Monoclinic-Tetragonal Transition of Zirconia; Thermodynamics," J. Am. Ceram. Soc., 45 [12] 612-13 (1962).   DOI
3 Y.H Kim, D.Y. Heo, W.P Tai, and J. S. Lee, "Effect of High Energy Ball Milling on the Piezoelectric Properties of Leadfree $(K_{0.44}Na_{0.52})(Nb_{0.86}Ta_{0.10})-0.04LiSbO_3$ Ceramics.," J. Kor. Ceram. Soc., 45 [6] 363-67 (2008).   DOI
4 R.C. Garvie, "The Occurrence of Metastable Tetragonal Zirconia as a Crystalite Size Effect," J. Phy. chem., 69 [4] 1238-43 (1965).   DOI
5 R.C. Garvie, "Stabilization of the Tetragonal Structure in $ZrO_2$ Microcrystals," J. Hhys. Chem., 82 [2] 218-24 (1978).   DOI
6 F.F. Lange, "Transformation Toughening-Part 1 Size Effects Associated with the Thermodynamics of Constrained Transformation," J. Mater. Sci., 17 225-34 (1982).   DOI
7 D.B. Marshall and M.V Swain, "Crack Resistance Curves in Magnesia-Partially-Stabilized Zirconia," J. Am. Ceram. Soc., 71 [6] 399-407 (1988).   DOI
8 F.F. Lange, "Transformation Toughening-Part 3 Experimental Observations in the $ZrO_2-Y_2O_3$ System," J. Mater. Sci., 17 240-46 (1982).   DOI
9 F.F. Lange, "Transformation Toughening-Part 1 Size Effects Associated with the Thermodynamics of Constrained Transformation," J. Mater. Sci., 17 225-34 (1982).   DOI
10 K. Tsukuma and M. Shimada, "Strength, Fracture Toughness and Vickers Hardness of $CeO_2$ Stabilized Tetragonal $ZrO_2$ Polycrystals (Ce-TZP)," J. Mater. Sci., 20 1178-84(1985).   DOI
11 I. Nettleship and R. Stevens, "Tetragonal Zirconia Polycrystal( TZP)-A Review," Int. J. High Technology Ceramics, 8 1-32 (1987).
12 M. Ruehle, N. Claussen, and A.H. Heuer, "Transformation and Microcrack Toughening as Complementary Processes in $ZrO_2$ Toughened $Al_2O_3$," J. Am. Ceram. Soc., 69 [3] 195-97(1986).   DOI
13 H. Toraya, M. Yoshimura and S. Somiya, "Calibration Curve for Quantitative analysis of the Monoclinic-Tetragonal $ZrO_2$ System by X-ray Diffraction," J. Am. Ceram. Soc., 67 [6] C-119-21 (1984).
14 E. Tani, M. Yoshimura, and S. Somiya, "Revised Phase Diagram of the System $ZrO_2$-$CeO_2$ Below 1400$^{\circ}C$," J. Am. Ceram. Soc., 66 [7] 506-10 (1983).   DOI
15 T.W. Coyle, W.W. Coblenz, and B.A. Bender, "Transformation Toughening in Large-Grain-Size $CeO_2$ Doped $ZrO_2$ Polycrystals," J. Am. Ceram. Soc., 71 [2] C-88-92 (1988).
16 R.C Garvie and P.S. Nicholson, "Phase Analysis in Zirconia System," J. Am. Ceram. Soc., 67 [6] 303-05 (1972).
17 R.M. Dikerson, M.V. Swain, and A.H. Heuer, "Microstructural Evolution in Ca-PSZ and the Room-Temperature Instability of Tetragonal Zirconia," J. Am. Ceram. Soc., 70[4] 214-20 (1987).   DOI
18 T.K. Gupta, J.H. Bechtold, R.C. Kuznickie, L.H. Cadoff, and B.R. Rossing, "Stabilization of Tetragonal Phase in Polycrystalline Zirconia," J. Mater. Sci., 12 2421-26 (1977).   DOI