• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.1
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• pp.42-52
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• 2013

Carbon Capture and Storage (CCS) is a mitigation technology essential in tackling global climate change. In Korea, many research projects are aimed to commercialize CCS business around 2020. Public acceptance can be a key factor to affect the successful proceeds of CCS near future. Therefore this paper provides a concise insight into the application of environmental impact assessment and risk assessment procedures to support the sustainable CCS projects. Futhermore, bottlenecks regarding the environmental impacts assessment and related domestic and foreign legislation are revised. Finally, suggestions to overcome these bottlenecks and recommendations for future research are made in conclusion.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.5
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• pp.499-506
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• 2015

Recently the Korean government announced its decision to select the $3^{rd}$ proposal, which targets reducing $CO_2$ by 37% of the BAU level by 2030, for the Intended Nationally Determined Contribution (INDC). According to this proposal, natural gas (or equivalent gas) combined cycle (NGCC) are suggested as alternatives for conventional pulverized coal (PC). In this study, we analyzed the environmental, economic, and energy mixing aspects of synthetic natural gas combined cycle(SNGCC) using NETL material (2011~2012 version) and other domestic materials (2014 version). We found the following conclusions: 1) Considering carbon capture and storage (CCS) integration, $CO_2$ emission factors of SNGCC and supercritical PC are the same. However, 60% of $CO_2$ from SNGCC is produced as high pressure and high purity (99%) gas, making it highly suitable for CCS, which is now strongly supported by the government. 2) Based on the economic analysis for SNGCC using domestic materials and comparison with NGCC, it was found that the settlement price of SNGCC was 30% lower than that of NGCC.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.690-695
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• 2012

Gas hydrate is an inclusion compound consisting of water and low molecular weight gases, which are incorporated into the lattice structure of water. Owing to its promising aspect to application technologies, gas hydrate has been widely studied recently, especially $CO_2$ hydrate for the CCS (Carbon Capture and Storage) issue. The key point of $CO_2$ hydrate technology for the CCS is how to produce gas hydrate in an efficient and economic way. In this study, we have tried to study the characteristic of gas hydrate formation using micro-sized ice through an ultrasonic nozzle which generate 2.4 MHz frequency wave. $CO_2$ as a carrier gas brings micro-sized mist into low-temperature reactor, where the mist and carrier gas forms $CO_2$ hydrate under $-55^{\circ}C$ and atmospheric pressure condition and some part of the mist also remains unreacted micro-sized ice. Formed gas hydrate was average 10.7 of diameter at average. The starting ice particle was set to constant pressure to form $CO_2$ hydrate and the consumed amount of $CO_2$ gas was simultaneously measured to calculate the conversion of ice into gas hydrate. Results showed that the gas hydrate formation was highly suitable because of its extremely high gas-solid contact area, and the formation rate was also very high. Self-preservation effect of $CO_2$ hydrate was confirmed by the measurement of $CO_2$ hydrate powder at normal and at pressed state, which resulted that this kind of gas storage and transport could be feasible using $CO_2$ hydrate formation.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.166-167
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• 2022

The International Energy Agency(IEA) recommends that intergovernmental agreements reduce CO2 emissions by 2050 to about 50% in 2005 in its report. To realize these demands, it is suggested to actively utilize energy efficiency improvement technology, renewable energy, nuclear power, carbon dioxide capture & storage technology (CCS). In the field of building materials and cement, mineral carbonization technology is widely used. Inorganic by-products applicable to greenhouse gas storage include waste concrete, slag, coal ash, and gypsum. If the Mineral Carbonation Act is used, it is expected that about 12 million tons of greenhouse gases can be immobilized every year. Greenhouse gas immobilization using cement hydrate can be immobilized by injecting carbon dioxide into the hydrated products C-S-H, and Ca(OH)2. In the case of immobilization through concrete carbonization, a carbon dioxide promotion test is used, which is often different from the actual carbon dioxide carbonization reaction. If the external carbon dioxide concentration is abnormally higher than the reality, it is thought that it will be different from the actual reaction. In this study, the carbonation phenomenon according to the concentration and identification of the carbon dioxide reaction mechanism of cement hydrate was to be considered.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.65-68
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• 2015

Agreeable to the latest enviromental problem, CCS(Carbon Capture&Storage) technology is more significant. As these issues, Oxy-Combustion is one of the technology that realize the CCS technology and large scale field test proceeding at other places. The aims of this research were to evaluate the combustion characteristics of pressurized oxy-combusition that is attract attention as the next generation power plant. The experiments were conducted using a laboratory-scale pressuized oxy-combustor. The fuel used was low calorific value syn-gas that is mainly composed of CO(60%), $H_2$(27%). The burner was used co-axial burner, to investigate combustion characteristics, temperature in the reactor and the flue gas compositions were measured.

• Clean Technology
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• v.20 no.1
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• pp.1-6
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• 2014

$CO_2$ is generated by the combustion reaction, when getting the energy from fossil fuel. If the carbon dioxide emissions increases more, the global warming problem will become more serious. CCS (carbon capture storage) needs to be developed for the prevention of this. When liquefied $CO_2$ is transported, BOG (boil-off gas) is generated because of several problems. In the study, by injecting liquefied $CO_2$ in two tanks which contains $40m^3$each, the amount of BOG and its composition were measured during 30 days when generating pressure changes and external heat, loading, unloading. In result, 16,040 kg of BOG was generated and the composition has been found out to be 99.95% $CO_2$ and 0.05 % $N_2$. Also, we conducted simulation process for reliquefaction of generated BOG with vapor compression cycle using the PRO/II with PROVISION version 9.2. As a result, the refrigeration cycle of the total circulation flow rate was 42.07 kg/h and the condenser utility consumption was 48.85 kg/h.

• The Journal of Engineering Geology
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• v.28 no.2
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• pp.207-215
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• 2018

Almost all countries of the world have recently made great efforts to reduce green-house gases to alleviate the global warming threatening human survival, because a huge amount of carbon dioxide as one of the main green-house gases has been emitted from the combustion processes of fossil fuels such as coal and oil. $CO_2$ capture and storage (CCS) technology is a representative method to diminish the green-house gases, and actively investigated by many countries. This study focuses on the design and construction of a high pressure $CO_2$ injection facility to store it to underground, which is the first $CO_2$ injection in Korea following the steps of the $CO_2$ capture from large $CO_2$ emission sources and transportation to the sea. Injection tests of $CO_2$ on the platform on the sea were carried out in Yeongil Bay of Pohang city in the early 2017. Thus, we were able to perceive the necessary operating conditions of the injection facility, injection characteristic, and knowhow of the injection facility. The results obtained from the injection test shall be utilized for facility upgrades and scale-ups.

• Economic and Environmental Geology
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• v.54 no.4
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• pp.409-425
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• 2021

Carbon dioxide has been known to be a typical greenhouse gas causing global warming, and a number of efforts have been proposed to reduce its concentration in the atmosphere. Among them, carbon dioxide capture and storage (CCS) has been taken into great account to accomplish the target reduction of carbon dioxide. In order to commercialize the CCS, its safety should be secured. In particular, if the stored carbon dioxide is leaked in the arable land, serious problems could come up in terms of crop growth. This study was conducted to investigate the effect of carbon dioxide leaked from storage sites on soil fertility. The leakage of carbon dioxide was simulated using the facility of its artificial injection into soils in the laboratory. Several soil chemical properties, such as pH, cation exchange capacity, electrical conductivity, the concentrations of exchangeable cations, nitrogen (N) (total-N, nitrate-N, and ammonia-N), phosphorus (P) (total-P and available-P), sulfur (S) (total-S and available-S), available-boron (B), and the contents of soil organic matter, were monitored as indicators of soil fertility during the period of artificial injection of carbon dioxide. Two kinds of soils, such as non-cultivated and cultivated soils, were compared in the artificial injection tests, and the latter included maize- and soybean-cultivated soils. The non-cultivated soil (NCS) was sandy soil of 42.6% porosity, the maize-cultivated soil (MCS) and soybean-cultivated soil (SCS) were loamy sand having 46.8% and 48.0% of porosities, respectively. The artificial injection facility had six columns: one was for the control without carbon dioxide injection, and the other five columns were used for the injections tests. Total injection periods for NCS and MCS/SCS were 60 and 70 days, respectively, and artificial rainfall events were simulated using one pore volume after the 12-day injection for the NCS and the 14-day injection for the MCS/SCS. After each rainfall event, the soil fertility indicators were measured for soil and leachate solution, and they were compared before and after the injection of carbon dioxide. The results indicate that the residual concentrations of exchangeable cations, total-N, total-P, the content of soil organic matter, and electrical conductivity were not likely to be affected by the injection of carbon dioxide. However, the residual concentrations of nitrate-N, ammonia-N, available-P, available-S, and available-B tended to decrease after the carbon dioxide injection, indicating that soil fertility might be reduced. Meanwhile, soil pH did not seem to be influenced due to the buffering capacity of soils, but it is speculated that a long-term leakage of carbon dioxide might bring about soil acidification.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.4
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• pp.307-319
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• 2009

Carbon dioxide capture and storage (CCS) technology has been regarded as one of the most possible and practical option to reduce the emission of carbon dioxide ($CO_2$) and consequently to mitigate the climate change. Korean government also have started a 10-year R&D project on $CO_2$ storage in sea-bed geological structure including gas field and deep saline aquifer since 2005. Various relevant researches are carried out to cover the initial survey of suitable geological structure storage site, monitoring of the stored $CO_2$ behavior, basic design of $CO_2$ transport and storage process and the risk assessment and management related to $CO_2$ leakage from engineered and geological processes. Leakage of $CO_2$ to the marine environment can change the chemistry of seawater including the pH and carbonate composition and also influence adversely on the diverse living organisms in ecosystems. Recently, IMO (International Maritime Organization) have developed the risk assessment and management framework for the $CO_2$ sequestration in sub-seabed geological structures (CS-SSGS) and considered the sequestration as a waste management option to mitigate greenhouse gas emissions. This framework for CS-SSGS aims to provide generic guidance to the Contracting Parties to the London Convention and Protocol, in order to characterize the risks to the marine environment from CS-SSGS on a site-specific basis and also to collect the necessary information to develop a management strategy to address uncertainties and any residual risks. The environmental risk assessment (ERA) plan for $CO_2$ storage work should include site selection and characterization, exposure assessment with probable leak scenario, risk assessment from direct and in-direct impact to the living organisms and risk management strategy. Domestic trial of the $CO_2$ capture and sequestration in to the marine geologic formation also should be accomplished through risk management with specified ERA approaches based on the IMO framework. The risk assessment procedure for $CO_2$ marine storage should contain the following components; 1) prediction of leakage probabilities with the reliable leakage scenarios from both engineered and geological part, 2) understanding on physio-chemical fate of $CO_2$ in marine environment especially for the candidate sites, 3) exposure assessment methods for various receptors in marine environments, 4) database production on the toxic effect of $CO_2$ to the ecologically and economically important species, and finally 5) development of surveillance procedures on the environmental changes with adequate monitoring techniques.

• Clean Technology
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• v.20 no.3
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• pp.321-329
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• 2014

In this study, Indonesia low rank coal, which has moisture content of around 26%, is dried less than 5% by using a laboratory-scale (batch type) steam fluidized-bed dryer in order to produce the low-moisture, high rank coal. Normally, CCS (carbon capture and storage) process discharges $CO_2$ and steam mixture gas around $100-150^{\circ}C$ of temperature after regeneration reactor. The final purpose of this research is to dry low rank coal by using the outlet gas of CCS process. At this stage, steam is used as heat source for drying through the heat exchanger and $CO_2$ is used as fluidizing gas to the dryer. The experimental variables were the steam flow rate ranging from 0.3 to 1.1 kg/hr, steam temperature ranging from 100 to $130^{\circ}C$, and bed height ranging from 9 to 25 cm. The characteristics of the coal, before and after drying, were analyzed by a proximate analysis, the heating value analysis and particle size analysis. In summary, the drying rate of low rank coal was increased as steam flow rate and steam temperature increased and increased as bed height decreased.