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Photo-Fenton Oxidation Treatment of Pilot Scale for the Decomposition of 1,4-dioxane Generated in a Polyester Manufacturing Process (폴리에스테르 중합 공정에서 발생되는 1,4-dioxane의 분해를 위한 파일럿 규모의 광펜톤산화처리)

  • So, Myung-Ho;Han, Ji-Sun;Han, Thi-Hiep;Seo, Jang-Won;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.9-14
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    • 2009
  • In this research, a polyester manufacturing company (i.e. K Co.) in Gumi, South Korea was investigated regarding the release of high concentrations of 1,4-dioxane(about 600 mg/L) and whether treatment prior to release should occur to meet with the level of the regulation standard (e.g., 5 mg/L in 2011). The pilot-scale (reactor volume, 10 $m^3$) treatment system using Photo-Fenton Oxidation was able to remove approximately 90% of 1,4-dioxane under the conditions that concentrations of 2,800 ppm $H_2O_2$ and 1,400 ppm $FeSO_4$ were maintained along with 10 UV-C lamps (240 ${\mu}W/cm^2$) illuminated during aeration. However, the effluent concentration of 1,4-dioxane was still high at about 60 mg/L. Thus, further investigation is needed to see whether the bench scale (reactor volume, 8.9 L) of activated sludge could facilitate the decomposition of 1,4-dioxane. As a result, 1,4-dioxane in the effluent has been decreased as low as about 2~3 mg/L. Consequently, Photo-Fenton Oxidation coupled with activated sludge process can make it possible to efficiently decompose 1,4-dioxane to keep up with that of the regulation standard.

Effects of Heat Treatment on Antioxidant Activity of Hydrolyzed Mung Beans (녹두 가수분해물의 항산화활성에 미치는 열처리 효과)

  • Kim, Min Young;Lee, Sang Hoon;Jang, Gwi Yeong;Kim, Hyun Young;Woo, Koan Sik;Hwang, In Guk;Lee, Junsoo;Jeong, Heon Sang
    • Korean Journal of Food Science and Technology
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    • v.45 no.1
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    • pp.34-39
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    • 2013
  • This study was performed to investigate the antioxidant activity of mung beans with heat treatment at $130^{\circ}C$ for 2 h after acid hydrolysis. The browning index of heating after hydrolysis was 2.31 whereas heating before hydrolysis was 0.17. 5-hydromethyl-2-furaldehyde (5'-HMF) content was the highest value of 81.61 mg/g in heating after hydrolysis. The highest total polyphenol content (55.95 mg/g) occurred in heating after hydrolysis and this value was 6.4-fold higher than that of heating before hydrolysis (8.79 mg/g). 2,2'-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) radical scavenging activity was the highest value of 22.19 mg AA eq/g sample in heating after hydrolysis whereas heating before hydrolysis was 1.75 mg AA eq/g sample.1,1-diphenyl-2-picrylhydrazyl (DPPH) radical-scavenging activity was the highest value of 3.64 mg Trolox eq/g sample in heating after hydrolysis whereas heating before hydrolysis was not shown. These results suggest that heat treatment of mung beans for increasing the antioxidant activity could be effective after hydrolysis.

Compounds Obtained from Sida acuta with the Potential to Induce Quinone Reductase and to Inhibit 7,12-Dimethylbenz-[a]anthracene-Induced Preneoplastic Lesions in a Mouse Mammary Organ Culture Model

  • Jang, Dae-Sik;Park, Eun-Jung;Kang, Young-Hwa;Su, Bao-Ning;Hawthorne, Michael-E.;Vigo, Jose-Schunke;Graham, James-G.;Cabieses, Fernando;Fong, Harry H.S.;Mehta, Rajendra-G.;Pezzuto, John-M.;Kinghorn, A.-Douglas
    • Archives of Pharmacal Research
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    • v.26 no.8
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    • pp.585-590
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    • 2003
  • Activity-guided fractionation of the EtOAc-soluble extract of the whole plants of Sida acuta using a bioassay based on the induction of quinone reductase (OR) in cultured Hepa 1c1c7 mouse hepatoma cells, led to the isolation of ten active compounds of previously known structure, quindolinone (1), cryptolepinone (2), 11-methoxyquindoline (3), N-trans-feruloyltyramine (4), vomifoliol (5), loliolide (6), 4-ketopinoresinol (7), scopoletin (8), evofolin-A (9), and evofolin-B (10), along with five inactive compounds of known structure, ferulic acid, sinapic acid, syringic acid, ($\pm$)-syringaresinol, and vanillic acid. These isolates were identified by physical and spectral data measurement. A new derivative of quindolinone, 5,10-dimethylquindolin-11-one (1a) was synthesized and characterized spectroscopically. Of the active substances, compounds 1-3 and 1a exhibited the most potent QR activity, with observed CD (concentration required to double induction) values ranging from 0.01 to 0.12 $\mu$ g/mL. Six compounds were then evaluated in a mouse mammary organ culture assay, with cryptolepinone (2), N-trans-feruloyltyramine (4), and 5,10-dimethylquindolin-11-one (1a) found to exhibit 83.3, 75.0, and 66.7% inhibition of 7,12-dimethylbenz[a]anthracene-induced preneoplastic lesions, respectively, at a dose of 10 $\mu\textrm{g}$/mL.

Studies on the Application of Tissue Culture for Plant Breeding I. Effect of genotype and other combined factors on the callus induction and plant regeneration in anther culture of rice (농작물 조직배양의 육종학적 이용에 관한 연구 제1보 벼 약배양효율에 대한 유전자형과 다른 요인간의 복합효과)

  • Kim, K.H.;Rush, M.C.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.4
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    • pp.425-430
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    • 1983
  • Rice (Oryza sativa L.) anthers collected from different genotypes were cultured to investigate the priority to increase callus production rate among several factors affecting on callus formation. Rice varieties, F$_1$ hybrids and F$_2$ plants differed greatly in their abilities to produce callus from anthers, and it was confirmed that the culturability of rice anther was a heritable characteristic. Cold shock treatment before plating anthers promoted callus formation rate, but combined effect with genotype having high culturability was more significant. The response to sucrose concentration in culture medium in callus induction rate was different between rice genotypes, but combined effect with genotype was not significant. Single supplement of NAA to R$_2$ medium increased callus production rate remarkably only in rice genotype having high culturability. Conclusively selection of genotypes is most important to increase callus initiation frequency from rice anthers.

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Elevated Temperature Creep Behavior of Rapidly Solidified Al-9.45wt%Fe-4.45wt%Cr Alloy (급냉응고된 Al-9.45wt%Fe-4.45wt%Cr합금의 고온 크?거동)

  • Rhim, J.K.;Kim, K.H.;Kim, T.S.
    • Journal of the Korean Society of Safety
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    • v.14 no.1
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    • pp.208-215
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    • 1999
  • The creep behavior of a rapidly solidified and consolidated Al-9.45wt%Fe-4.45wt%Cr alloy were investigated in the stress range 40 to 115 MPa and temperature range 300(0.53Tm) to 441$^{\circ}C$(0.66Tm). It is of use to available aerospace and automobile industries for the improved performance of materials used at high temperature. Because Al alloys with improved creep resistance offer the potential for lower weight and reduced costs in aerospace and automobile components (e.g., structural members and engine parts) through the replacement of heavier and more costly materials, the safety in use at high temperature is good. The alloy is characterized by high stress exponents and activation energies for creep, which are greatly dependent on the stress and temperature. Because the creep stress is seen to cause a strongly significant enhancement of coarsening, the coarsening rate of the dispersed particles in all crept specimens is faster than that in isothermally annealed specimens. Dislocations connecting dispersoids are observed more cofrequently in crept specimens with higher stress and lower temperature. The creep strain rates in the power law creep regime were found to be predicted much better by the Shorty and Rosler/Arzt equation with the inclusion of a threshold stress and dislocation detachment mechanism. The dispersoids in this alloy were acting a source of void nucleation that finally leaded to ductile fracture within the grain so called intergranular. Each void was initiated, grown and failed at the dispersoids in the aluminium matrix. Grain boundary accommodation of the slip produced, which result in initiation of the void and then final transgranular fracture. Therefore, it was confirmed that these dispersoids played an important role in the fracture mechanism by the formation of $Al_{13}Fe_4$, $Al_{13}Cr_2$ and $Al_2O_3$.

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Physiochemical and Microbiological Changes of the Fermented Dandelion (Taraxacum officinale) Extracts with Raw Sugar (당 첨가 민들레(Taraxacum officinale) 발효 추출물의 발효과정 중 이화학적 및 미생물학적 변화)

  • Kim, Kyung-Min;Kim, Young-Nam;Choi, Byoung-Kon;Oh, Deog-Hwan
    • Food Science and Preservation
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    • v.19 no.1
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    • pp.131-137
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    • 2012
  • This study was carried out to investigate the physiochemical and microbiological changes of dandelion during fermentation. Thirty and fifty percentage raw sugar groups (SFE30 and SFE50) were introduced into dandelions and fermented for 120 days at $15-20^{\circ}C$. This study was conducted to investigate the utilization of sucrose on lactic acid bacteria from dandelions and their effect on the pH, titratable acidity, microorganism and formation of organic acids in dandelions during fermentation. The number of lactic acid bacteria increased remarkably up to 15 days of fermentation and then decreased rapidly thereafter. The maximum number of lactic acid bacteria, 7.9 log CFU/mL was reached at pH 4.17 and the pH of dandelion showed a slight decrease during fermentation and decreased steadily up to 90 days to reach an optimum pH of 4.0. The titratable acidity of dandelions fermented increased during fermentation. The concentration of organic acid, amino acid and free sugar in SFE30 was higher than both SFE50 and DWE. The results of dandelions fermented were remarkably retarded in the 50% raw sugar group compared to the 30% raw sugar group.

Tritium Concentrations of Tritiated Water Vapor and Tritiated Hydrogen in the Atmosphere in Taejon (대전지역 대기중 수증기상태 (HTO) 및 가스상태 (HT) 삼중수소의 농도)

  • Kim, C.K.;Han, M.J.;Kim, K.H.
    • Journal of Radiation Protection and Research
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    • v.22 no.2
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    • pp.97-101
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    • 1997
  • During the period of March 1995 to December 1995, tritium concentrations of tritiated water vapor (HTO) and tritiated hydrogen (HT) in the atmosphere in Taejon were measured to evaluate present background levels of tritium in the atmosphere. Air samples were collected continuously for three weeks with a sampling system for tritium in the atmosphere and were analyzed by a liquid scintillation counting system. The range of the atmospheric HTO concentrations was 3.2-36 mBq $m^{-3}$ with a mean value of 16.2 mBq $m^{-3}$. The atmospheric HTO concentrations were the highest in summer and the lowest in winter. This trend was similar to the variation of atmospheric absolute humidity. The specific activities of tritium in atmospheric water vapor in Taejon ranged from 0.62 Bq $L^{-1}$ to 3.82 Bq $L^{-1}$ with a mean value of 2.04 Bq $L^{-1}$. The atmospheric HT concentrations were in the range of 35.7 mBq $m^{-3}$ to 48.9 mBq $m^{-3}$ with a mean value of 41.1 mBq $m^{-3}$.

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Influence on Composting of Waste Mushroom Bed from Agaricus bisporus by using Mixed Organic Materials (혼용자재 특성이 양송이 폐상배지를 이용한 퇴비제조에 미치는 영향)

  • Kyung, Ki-Cheon;Lee, Hee-Duk;Jung, Young-Pil;Jang, Kab-Yeul;Yoon, Min-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.3
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    • pp.335-340
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    • 2010
  • This study was conducted to select organic materials (OM) and nitrogen sources in composting of waste mushroom bed from Agaricus bisporus. We examined physio-chemical properties of the organic materials and the mixture ratio for preparing the wasted mushroom bed (M) compost. The carbon content of sawdust was higher than those of rice straw (R) as OM source and the nitrogen content was high in the order of fowl manure (F)>> pig manure (P)> cow manure (C). The compost was prepared to maintain the criteria of above 25% organic matter and then the change of their ingredients was estimated during the process of fermentation. The temperature of waste mushroom bed+pig manure+rice straw (MRP) treatment was varied fast throughout fermentation, on the other hand the temperature of waste mushroom bed+pig manure+sawdust (MSP) treatment was steadily elevated to the middle of composting. The pH of the compost was somewhat high to pH 8.5~9.0 at the early stage, but decreased to 7.5 at the end stage of composting. The content of OM after fermentation was decreased to the level of 19~21% in rice straw, but the sawdust treatment maintained 25~27% organic matter. The waste mushroom bed+fowl manure+rice straw (MRF) treatment, which contains 26.2% organic matter and 0.68% nitrogen, was the highest among them. The volume of compost was reduced to 50% by using rice straw as organic matter, but reduced to 30% by using the sawdust. The contents of heavy metal in the compost were suitable within the legal criteria. The number of microorganisms were higher in the rice straw than those in the sawdust. It was high in the order of fowl manure> pig manure> cow manure. The major groups consisted of aerobic bacteria, gram negative bacteria and Bacillus sp. and their populations after fermentation were increased to $1{\times}10^1{\sim}1{\times}10^2\;cfu\;g^{-1}$ rather than those before fermentation. Therefore we concluded that the waste mushroom bed+fowl manure+sawdust (MSF 3:9:1 v/v/v) treatment was suitable combination for high organic matter and nitrogen source, and the periods of composting were 50~60 days.

Effect of Dietary Bacillus sp. Inoculated Feather Meal on the erformance and Nutrient Utilization in Broiler (Bacillus sp. 접종 우무분이 Broiler 의 생산성과 영양소 이용율에 미치는 영향)

  • Kim, J.H.;Kim, S.C.;Ko, Y.D.
    • Journal of Animal Science and Technology
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    • v.46 no.4
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    • pp.603-612
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    • 2004
  • This study was carried out to investigate the replacing fish meal or soybean meal effect of with feather meal or Bacillus sp. inoculated feather meal in broiler diets on the performances and nutrient utilization. One hundred and eighty broilers were randomly allotted to six dietary treatments(1) control, basal diet; (2) BFMl00, Fish meal replacing at 100% level with bacillus sp. inoculated feather meal; (3) BSM20, Soybean meal replacing at 20% level with bacillus sp. inoculated feather meal; (4) BFMl00+BSM20, Fish meal and soybean meal replacing at 100% level and 20% level with bacillus sp. inoculated feather meal, respectively; (5) GFMl00, Fish meal replacing at 100% level with general feather meal; and (6) GSM20, Soybean meal replacing at 20% level with general feather meal) in a 5 week feeding trial. In overall period, body weight gain of control was the highest(1,623g) and those of BFM 100, BFM 100+ BSM 20 and GFM 100 were 1,572g, 1,564g, and 1,078g, respectively. And that of GFM 100(1,078.3g) was the lowest(p<0.05) among treatments. Digestibility of dry matter for BFM 100+BSM 20(81.46%) was higher(p<0.05) than that for other treatments, and that of crude protein was the lowest (p<0.05). Digestibilities of organic matter were significantly(p<0.05) improved when Bacillus sp. inoculated feather meal was replaced at 100% level with fish meal in the basal diet. Methane and hydrogen sulfide gases from the feces were significantly(p<0.05) decreased in chicks fed the control, BFM 100 and GFM 100 diets, when observed after 3 weeks of feeding trials. Feed costs of the control and BFM 100 were 417 and 384 won, respectively but that of BSM 20 was 558 won. Therefore, replacement of fish meal with Bacillus sp. inoculated feather meal in the diets for chicks could be useful for economic production.

Antioxidative, Antimicrobial and Anticytotoxic Activities of Seungmagalgeuntang and Fermented Seungmagalgeuntang (승마갈근탕과 발효 승마갈근탕에 의한 항산화, 항미생물 및 항세포독성 효과)

  • In, Jae Pyung;Shin, Jung Mi;Hur, Sun Jin;Lee, Si Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.7
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    • pp.980-988
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    • 2014
  • Seungmagalgeuntang (SG) is broadly used in traditional Oriental medicine especially in Korea, China, and Japan, for its many pharmacological effects. This study was carried out to investigate the antioxidative, antimicrobial, and anticytotoxic activities of SG and fermented seungmagalgeuntang (FSG). DPPH radical scavenging activities of SG and FSG were 70% and 74%, respectively, which increased slightly by fermentation. Nitrite scavenging activities were strongly altered at pH 1.2, (36.4% in SG and 38.3% in FSG) by addition of $200{\mu}g/g$. Superoxide dismutase-like activities were from 21.5% to 23.3% at a concentration of 0.4 mg/mL, and the highest value were observed in FSG. Total flavonoid contents of SG and FSG were 47.1 and $52.1{\mu}g/L$, respectively which shows an increase upon fermentation. In the antimicrobial activity test, $MIC_{50}$ values of SG and FSG were $800{\mu}g/mL$ for Candida albicans and 3,200 and $1,600{\mu}g/mL$ for Staphylococcus epidermidis and Staphylococcus aureus, respectively. Antibacterial effects were higher in FSG compared to SG. Anticytotoxic cadmium toxicities ranged from 63.5% to 76.1% at $10{\mu}g/mL$ of SG and FSG, and the highest value was observed in FSG. In the sensory evaluation, color, flavor, and overall preference values were higher in FSG.