• 제목/요약/키워드: C-flux

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The Effect of LSC/GDC (50 : 50 vol%) Active Layers on Oxygen Transport Properties of LSCF/GDC (20 : 80 vol%) Dual-phase Membrane (LSC/GDC (50 : 50 vol%) 활성층이 LSCF/GDC (20 : 80 vol%) 복합 분리막의 산소투과 거동에 미치는 영향)

  • Cha, Da-Som;Yoo, Chung-Yul;Joo, Jong Hoon;Yu, Ji Haeng;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.367-374
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    • 2014
  • In the present study, disc-type LSCF/GDC (20 : 80 vol%) dual-phase membranes having porous LSC/GDC (50 : 50 vol%) active layers were prepared and effect of active layers on oxygen ion transport behavior was investigated. Introduction of active layers improved drastically oxygen flux due to enhanced electron conductivity and oxygen surface exchange activity. As firing temperature of active layer increased from $900^{\circ}C$ to $1000^{\circ}C$, oxygen flux increased due to improved contact between membrane and active layer or between grains of active layer. The enhanced contact would improve oxygen ion and electron transports from active layer to membrane. Also, as thickness of active layer increased from 10 to $20{\mu}m$, oxygen flux decreased since thick active layer rather prevented oxygen molecules diffusing through the pores. And, STF infiltration improved oxygen flux due to enhanced oxygen reduction reaction rate. The experimental data announces that coating and property control of active layer is an effective method to improve oxygen flux of dual-phase oxygen transport membrane.

A Feasibility Study on Sewage Discharge Water Treatment for Water Reuse by Direct Contact Membrane Distillation (하수처리수 재이용을 위한 직접접촉식 막증발법 적용 가능성 연구)

  • Choi, Yongjun;Choi, Jihyuck;Shin, Yonghyun;Cho, Hyeongrak;Sohn, Jinsik;Lee, Sangho
    • Membrane Journal
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    • v.26 no.1
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    • pp.70-75
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    • 2016
  • The reuse of wastewater is being diffused to manage and develop the water resources. Generally, the treated wastewater is discharged to the river after being treated to meet the effluent quality standard or reused for diverse uses through the reprocessing. And recently, as the reuse of the treated wastewater is activated, the technologies to utilize for the high quality water resources such as industrial water by reusing the wastewater with Membrane Distillation (MD) are under development. In this study, the direct contact membrane distillation (DCMD) process has been applied to treat sewage discharge water for water reuse. The laboratory scale experiment was performed by using a hydrophobic PVDF membrane with the pore size of $0.22{\mu}m$. The influence of operating parameters, such as feed temperature, feed flow rate, feed concentration, on the permeate flux and rejection has been investigated. All filtration tests were conducted till the feed volume reached a concentration factor of 3.0. Thus, the operating period ranged between 19 hr and 49 hr depending on filtration performance. The results showed that above 92% of TN, TP, COD and TOC in the feed could be rejected regardless of an operating condition. The water flux was ranged from 13.8 to 20.3 LMH. The lowest flux was obtained at the operating condition with the feed temperature of $50^{\circ}C$ and feed flow velocity of 500 mL/min while the highest one was measured with $60^{\circ}C$ and 900 mL/min. When the concentration factor reached 3.0, water flux declined by approximately ranged from 14.5% to 33.3%. But the fouling in MD is almost fully reversible, with more than 90% recovery of permeate water flux following a DI water rinse without the addition of chemical cleaning reagents.

Evaluation of carbon flux in vegetative bay based on ecosystem production and CO2 exchange driven by coastal autotrophs

  • Kim, Ju-Hyoung;Kang, Eun Ju;Kim, Keunyong;Jeong, Hae Jin;Lee, Kitack;Edwards, Matthew S.;Park, Myung Gil;Lee, Byeong-Gweon;Kim, Kwang Young
    • ALGAE
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    • v.30 no.2
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    • pp.121-137
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    • 2015
  • Studies on carbon flux in the oceans have been highlighted in recent years due to increasing awareness about climate change, but the coastal ecosystem remains one of the unexplored fields in this regard. In this study, the dynamics of carbon flux in a vegetative coastal ecosystem were examined by an evaluation of net and gross ecosystem production (NEP and GEP) and $CO_2$ exchange rates (net ecosystem exchange, NEE). To estimate NEP and GEP, community production and respiration were measured along different habitat types (eelgrass and macroalgal beds, shallow and deep sedimentary, and deep rocky shore) at Gwangyang Bay, Korea from 20 June to 20 July 2007. Vegetative areas showed significantly higher ecosystem production than the other habitat types. Specifically, eelgrass beds had the highest daily GEP ($6.97{\pm}0.02g\;C\;m^{-2}\;d^{-1}$), with a large amount of biomass and high productivity of eelgrass, whereas the outer macroalgal vegetation had the lowest GEP ($0.97{\pm}0.04g\;C\;m^{-2}\;d^{-1}$). In addition, macroalgal vegetation showed the highest daily NEP ($3.31{\pm}0.45g\;C\;m^{-2}\;d^{-1}$) due to its highest P : R ratio (2.33). Furthermore, the eelgrass beds acted as a $CO_2$ sink through the air-seawater interface according to NEE data, with a carbon sink rate of $0.63mg\;C\;m^{-2}\;d^{-1}$. Overall, ecosystem production was found to be extremely high in the vegetated systems (eelgrass and macroalgal beds), which occupy a relatively small area compared to the unvegetated systems according to our conceptual diagram of a carbon-flux box model. These results indicate that the vegetative ecosystems showed significantly high capturing efficiency of inorganic carbon through coastal primary production.

Feasibility study on the application of membrane distillation process to treat high strength wastewater (막 증발법(Membrane Distillation)을 이용한 고농도 하·폐수처리 가능성 연구)

  • Kim, Se-Woon;Lee, Dong-Woo;Min, Kyung-Jin;Cho, Jinwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.2
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    • pp.261-269
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    • 2015
  • In this study, we applied a membrane distillation process to investigate a feasibility of treating a wastewater with high concentration of organic matters including nitrogen and phosphorus. The laboratory scale experiment was performed by using a hydrophobic PVDF membrane with the pore size of $0.22{\mu}m$ and porosity of 75%. The installation was direct contact type where the temperature difference between a feed and permeate side was controlled to have a range from 20 to $60^{\circ}C$. We observed a flux variation and a concentration changes of COD, $PO{_4}^{3-}$-P, $NH_4{^+}$-N and conductivity of feed side as well as permeate side with various temperature differences (20 to $60^{\circ}C$), cross flow velocities (0.09 to 0.27 m/s) through the module, and pH (6.6 to 12.0) of the feed that has the initial concentration of COD about 1,000 mg/L, total nitrogen 390 mg/L, total phosphorus 10 mg/L, conductivity of $7,000{\mu}s/cm$. The results showed that the average flux was ranged from 4 to $40L/m^2/hr$ which was almost similar with the flux of NaCl and deionized water used as a feed solution. The lowest flux was obtained at the operating condition with the temperature difference of $20^{\circ}C$ and cross flow velocity of 0.09 m/s while the highest one was measured with $60^{\circ}C$ and 0.27 m/s. Above 99% of COD and $PO{_4}^{3-}$-P in the feed could be rejected regardless of an operating condition. However, the removal rate of ammonium nitrogen was varied from 64 to 99% depending on the pH of feed solution.

Numerical Study of Heat Flux and BOG in C-Type Liquefied Hydrogen Tank under Sloshing Excitation at the Saturated State (포화상태에 놓인 C-Type 액체수소 탱크의 슬로싱이 열 유속과 BOG에 미치는 변화의 수치적 분석)

  • Lee, Jin-Ho;Hwang, Se-Yun;Lee, Sung-Je;Lee, Jang Hyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.5
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    • pp.299-308
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    • 2022
  • This study was conducted to predict the tendency for heat exchange and boil-off gas (BOG) in a liquefied hydrogen tank under sloshing excitation. First, athe fluid domain excited by sloshing was modeled using a multiphase-thermal flow domain in which liquid hydrogen and hydrogen gas are in the saturated state. Both the the volume of fluid (VOF) and Eulerian-based multi-phase flow methods were applied to validate the accuracy of the pressure prediction. Second, it was indirectly shown that the fluid velocity prediction could be accurate by comparing the free surface and impact pressure from the computational fluid dynamics with those from the experimental results. Thereafter, the heat ingress from the external convective heat flux was reflected on the outer surfaces of the hydrogen tank. Eulerian-based multiphase-heat flow analysis was performed for a two-dimensional Type-C cylindrical hydrogen tank under rotational sloshing motion, and an inflation technique was applied to transform the fluid domain into a computational grid model. The heat exchange and heat flux in the hydrogen liquid-gas mixture were calculated throughout the analysis,, whereas the mass transfer and vaporization models were excluded to account for the pure heat exchange between the liquid and gas in the saturated state. In addition, forced convective heat transfer by sloshing on the inner wall of the tank was not reflected so that the heat exchange in the multiphase flow of liquid and gas could only be considered. Finally, the effect of sloshing on the amount of heat exchange between liquid and gas hydrogen was discussed. Considering the heat ingress into liquid hydrogen according to the presence/absence of a sloshing excitation, the amount of heat flux and BOG were discussed for each filling ratio.

Flux pinning properties of rf-sputtered YBCO films with $BaZrO_3$ doping (스퍼터링법에 의한 $BaZrO_3$도핑 YBCO 박막의 자속고정 특성 연구)

  • Chung, K.C.;Kim, Y.K.;Wang, X.L.;Dou, S.X.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.374-374
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    • 2009
  • We have fabricated pure YBCO films and $BaZrO_3$ doped ones on $CeO_2$ buffered YSZ single crystal substrates using rf-sputtering method. In this work, pure YBCO and 2 vol% BZO doped YBCO target were used to investigate the flux pinning properties of BZO doped YBCO films compared to undoped ones. BZO nanodots within the superconducting materials was known to comprise the self-assembled columnar defects along the c-axis from the bottom of YBCO films up to the top surface, thus can be a very strong pinning sites in the applied magnetic field parallel to them. We will discuss the possibility of growing self-assembled columnar defects in the rf-sputtering method. It is speculated that BZO and YBCO phases can separate and BZO form nanodots surrounded by YBCO epitaxial layers and continuous phase separation and ordering between these two materials, which was well studied in Pulsed Laser Deposition method. For this purpose, some severe experimental conditions such as on-axis sputtering, shorter target-substrate distance, high rf-power, etc was adopted and their results will be presented.

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Flux pinning properties of Y-Ba-Cu-O thin films grown on STO substrates with assembled Au nanoparticles (금 나노입자가 배열된 STO기판에서 성장된 Y-Ba-Cu-O박막의 Flux pinning 특성)

  • Oh, Se-Kweon;Jang, Gun-Eik;Lee, Cho-Yeon;Hyun, Ok-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.375-375
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    • 2009
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. We report measurements of critical current in $YBa_2Cu_3O_{7-\delta}$ films deposited by PLD on $SrTiO_3$ substrates decorated with Au nanoparticles. Au nanoparticles were synthesized on STO substrates with self assembled monolayer. Microstructural analysis of the obtained YBCO films was performed by using cross-section transmission electron microscopy(TEM). Phase and textural analysis was done using X-ray diffraction. The surface morphology and surface roughness(Ra) of the layers was measured by atomic force microscopy(AFM).

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Evaporation pressure drop of $CO_2$ in a horizontal tube (수평관내 이산화탄소의 증발 압력강하)

  • Lee Dong-Geon;Son Chang-Hyo;Oh Hoo-Kyu
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.5
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    • pp.552-559
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    • 2005
  • The evaporation pressure drop of $CO_2$ (R-744) in a horizontal tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump. a mass flow meter, a pre-heater and evaporator (test section). The test section consists of a smooth. horizontal stainless steel tube of 7.75 mm inner diameter. The experiments were conducted at mass flux of 200 to $500\;kg/m^{2}s$, saturation temperature of $-5^{\circ}C\;to\;5^{\circ}C$. and heat flux of 10 to $40\;kW/m^2$. The test results showed the evaporation pressure drop of $CO_2$ are highly dependent on the vapor qualify, heat flux and saturation temperature. The evaporation pressure drop of $CO_2$ is very lower than that of R-22. In comparison with test results and existing correlations. the best fit of the present experimental data is obtained with the correlation of Choi et al. But existing correlations failed to predict the evaporation pressure drop of $CO_2$. Therefore, it is necessary to develop reliable and accurate predictions determining the evaporation pressure drop of $CO_2$ in a horizontal tube.

On the Warming Effects due to Artificial Constructions in a Large Housing Complex (대규모 주택단지내의 인공구조물에 의한 승온화효과에 관한 연구)

  • 김해동;이송옥;구현숙
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.705-713
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    • 2003
  • In mid-August 2002, under clear summer pressure patterns, we carried out an intensive meteorological observation to examine the warming effects due to artificial constructions in a large housing complex. We set an automatic weather system(AWS) at two places in a bare soil surface within a limited development district and an asphalt surface within a large apartment residence area, respectively. As a result of observation, it became clear that the difference of the surface air(ground) temperature between the bare soil surface and its peripheral asphalt area reached about 4$^{\circ}C$(13$^{\circ}C$) at the maximum from diurnal variation of surface temperatures on AWS data. Through the heat balance analysis using measurement data, it became clear that the thermal conditions at two places are dependent on the properties of surface material. The latent heat flux over the bare soil surface reached to about 300 W/㎡, which is more than a half of net radiation during the daytime. On the other hand, it was nearly zero over the asphalt surface. Hence, the sensible heat flux over the asphalt surface was far more than that of the bare soil surface. The sensible heat flux over the asphalt surface showed about 20∼30 W/㎡ during the night. It was released from asphalt surface which have far more heat capacity than that of bare soil surface.

Integrated 3-Channel Flux-Locked-Loop Electronics for the Readout of High-$T_c$ SQUID (고온초전도 SQUID 신호 검출을 위한 3채널용 FLL 회로)

  • 김진목;김인선;유권규;박용기
    • Progress in Superconductivity
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    • v.5 no.1
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    • pp.55-60
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    • 2003
  • We designed and constructed integrated 3-channel flux-locked-loop (FLL) electronic system for the control and readout of high-T$_{c}$ SQUIDs. This system consists of low noise preamplifiers, integrators, interface circuits, and software. FLL operation was carried out with biased signals of 19 KHz modulated current and 150 KHz modulated flux, which are reconstructed as detected signals by preamplifier and demodulator. Computer controlled interface circuits regulate FLL circuit and adjust SQUID parameters to the optimum operating condition. The software regulates interface circuits to make an auto-tuning for the control of SQUIDs, and displays readout data from FLL circuit. 3-channel SQUID electronic system was assembled with 3 FLL-interface circuit boards and a power supply board in the aluminum case of 56 mm ${\times}$ 53 mm${\times}$ 150 mm. Overall noise of the system was around 150 fT/(equation omitted)Hz when measured in the shielded room, 200 fT/(equation omitted)Hz in a weakly shielded room, respectively.y.

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