• Title/Summary/Keyword: C-4

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Synthesis and structure of ($C_6CH_2NH_3)_2CUCl_4and \;(NH_3C_6C_4C_2H_4C_6NH_3)CUCl_4$ (($C_6CH_2NH_3)_2CUCl_4와 \;(NH_3C_6C_4C_2H_4C_6NH_3)CUCl_4$의 합성과 구조)

  • 김지현;권석순;현준원;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.4
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    • pp.135-139
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    • 2004
  • The layered organic-inorganic hybrid compounds($C_6H_5CH_2NH_3)_2CuCl_4$ and ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$ have been directly synthesized. From the X-ray diffraction data and the organic guest size, the orientation of the intercalated organic amine was determined. The inorganic sheets consist of $CuCl_4^{2-}$layers of comer-sharing octahedra copper chloride. The protonated organic amine was intercalated into the $CuCl_4^{2-}$layers with bilayer structure for ($C_6H_5CH_2NH_3)_2CuCl_4$ and monolayer structure for ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$.

An Implementation AXI4 Bus for Verification of SoC Platform Using Verilator and C/C++ (Verilator와 C/C++를 이용한 SoC 플랫폼 검증을 위한 AXI4 BUS 구현)

  • Lee, Jung-Yong;Lee, Kwang-Yeob
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2012.05a
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    • pp.364-367
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    • 2012
  • In this paper, AXI4 BUS was implemented using Verilator and C/C++ for verification of SoC platform H/W IP which is based on AXI4 BUS. In this paper we proposed a method to verify the AXI4 BUS based SoC platform H / W IP by implemented AXI4 BUS on PC using Verilator and C/C++. The result shows AXI4 BUS based H/W IP that is verified by implemented AXI4 BUS is to perform the same behavior on FPGA environment.

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Potential barrier height of Metal/SiC(4H) Schottky diode (Metal/SiC(4H) 쇼트키 다이오드의 포텐셜 장벽 높이)

  • 박국상;김정윤;이기암;남기석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.640-644
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    • 1998
  • We have fabricated Sb/SiC(4H) Schottky barrier diode (SBD) of which characteristics compared with that of Ti/SiC(4H) SBD. The donor concentration of the n-type SiC(4H) obtained by capacitance-voltage (C-V) measurement was about $2.5{\times}10 ^{17}{\textrm}cm^{-3}$. The ideality factors of 1.31 was obtained from the slope of forward current-voltage (I-V) characteristics of Sb/SiC(4H) SBD at low current density. The breakdown field of Sb/SiC(4H) SBD under the reverse bias voltage was about $4.4{\times}10^2V$/cm. The built-in potential and the Schottky barrier height (SBH) of Sb/SiC(4H) SBD were 1.70V and 1.82V, respectively, which were determined by the analysis of C-V characteristics. The Sb/SiC(4H) SBH of 1.82V was higher than Ti/SiC(4H) SBH of 0.91V. However, the current density and reverse breakdown field of Sb/SiC(4H) were low as compared with those of Ti/SiC(4H). The Sb/SiC(4H), as well as the Ti/SiC(4H), can be utilized as the Shottky barrier contact for the high-power electronic device.

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Studies on the Classification, Productivity, and Distribution of $C_3,;C_4 $ and CAM Plants in Vegetations of KoreaIII. The Distribution of $C_3 and C_4$Type Plants (한국의 식생에 있어서$C_3, C_4 $ 및 CAM 식물의 분류, 생산력 및 분포에 관한 연구 3. $C_3 와 C_4$ 형 식물의 식생분포와 종분포)

  • Chang, Nam-Kee;Sung-Kyu Lee
    • The Korean Journal of Ecology
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    • v.6 no.2
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    • pp.128-141
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    • 1983
  • The districbution of $C_3; and; C_4$ type plants in Korea were studied. In the standpoint of photosynthetic types, plant distribution in Korea is classified as $C_3; and; C_4$ type plant zones. The forest destroyed by man interference, cultivating areas, and seashore areas are characterized by the dominant of $C_4$ type plants.(Figs. 2, 3, 4, 5) According to the results of this study, $C_3; and; C_4$ type plant distribution in Korea has a great relation to the habitat of plant vegetation (Table 1). The arid areas were in high proportion of C4 flora percenntages, while the well-developed woody forests or the vegetation of humid areas were in lower proportion(Fig.8).

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Reaction Synthesis and Mechanical Properties of $B_4C$-based Ceramic Composites

  • Han, Jae-Ho;Park, Sang-Whan;Kim, Young-Do
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1080-1081
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    • 2006
  • In this investigation, $B_4C$ based ceramic composites were fabricated by in-situ reaction hot pressing using $B_4C$, TiC SiC powder as starting materials. The reaction synthesized composites by hot pressing at $1950^{\circ}C$ was found to posses very high relative density. The reaction synthesized $B_4C$ composites comprise $B_4C$, $TiB_2$, SiC and graphite by the reaction between TiC and $B_4C$. The newly formed $TiB_2$ and graphite was embedded both inside grain and at grain boundary $B_4C$. The mechanical properties of reaction synthesized $B_4C-TiB_2-SiC$-graphite composites were more enhanced compared to those of monolithic $B_4C$.

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Pressureless Infiltration Processing of B4C/Al Composite by Surface Modification (표면 개질에 의한 상압에서의 B4C/Al복합체 제조 방법)

  • 임경란;강덕일;김창삼
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.128-131
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    • 2003
  • Formation of$B_4C/Al$composite by pressureless infiltration was investigated by lowering wetting angle via surface modification of $B_4C$powder with alumina precursor. Surface modification was confirmed by zeta potential analysis. The$B_4C/Al$composite was prepared by placing an Al 6061 disk on the$B_4C$preform and heating at $1030{\circ}C$/20 min under a flowing argon, but no infiltration took place for a bare $B_4C$ preform even at$1250{\circ}C$/30 min. Analysis of XRD and SEM showed the $Al_3BC$phase besides$B_4C$and Al, but no trace of deteriorative$A1_4C_3$.

A Study on the Chemically Vapor Deposited TiC, TiN, and TiC(C, N) on $Si_3N_4$-TiC Ceramic Tools. ($Si_3N_4-TiC$ Ceramic 공구에 화학증착된 TiC, TiN 및 Ti(C, N)에 관한 연구)

  • 김동원;김시범;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.36-43
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    • 1988
  • Titanium carbide(TiC) and titanium nitride(TiN) flims were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$ and $TiCl_4-H_2-N_2$ gas mixtures, respectively. The nonmetal to metal ratio of deposit increases with increasing $m_{C/Ti}$(mole ratio of CH$_4$ to TiCl$_4$ in the input) for TiC coatings and $m_{N/Ti}$(mole ratio of N$_2$ to TiCl$_4$ in the input) for TiN coatings. The nearly stoiahiometric films could be obtained under the deposition condition of $m_{C/Ti}$ between 1.15 and 1.61 for TiC, and that of $m_{N/Ti}$ between 25 and 28 for TiN. Also maximum microhardness of the coatings can be obtained in these ranges. The interfacial region of TiC coatings on $Si_3N_4$-TiC ceramics is wider than that of TiN coatings according to Auger depth profile analysis, which indicates good interfacial bonding for TiC. Experimental results show that TiC coatings have an randomly equiaxed structure and Columnar structure with(220) preferred orientation can be obtained for TiN coatings. And, multilayer coatings have a dense and equiaxed structure.

Measurement of elastic constants of single crystal PbMoO_4$ by using brillouin scattering experiment (브릴루앙 산란실험을 이용한 단결정 PbMoO_4$의 탄성계수 측정)

  • 박주일;이석목;유윤식;김성철
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.363-369
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    • 1996
  • We have performed Brillouin scattering experiments to investigate the elastic properties of tetragonal symmetry single crystal $PbMoO_4$ and could determine the value of birefringence as well as the whole elastic constants. As a result, $c_11=111.4{\pm}4.4,$$, $c_12=64.7{\pm}3.4$, $c_44=27.0{\pm}0.8$, $c_13=51.9{\pm}2.5$, $c_33=95.5{\pm}1.9$, $c_66=34.5{\pm}4.6$ and $c_16=15.8{\pm}1.2({\times}10^9N/m^2)$ and $n_o-n_e=0.151{\pm}0.018$.

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Effect of TiB2 Coating on the Mechanical Properties of B4C/Al Composites Prepared by Infiltration Process (TiB2코팅이 함침법으로 제조되는 B4C/Al 복합체의 기계적 특성에 미치는 영향)

  • 김선혜;임경란;심광보;김창삼
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.777-783
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    • 2003
  • The mechanical properties of B$_4$C/Al composites normally depend on the species and quantity of reaction products between B$_4$C and Al and then the control of reaction products is necessary to make desirable composites for lightweight advanced or armor materials. TiB$_2$ is chemically inert with aluminum and has a lower contact angle (85$^{\circ}$ at 100$0^{\circ}C$) to liquid aluminum than B$_4$C. Thus, TiB$_2$ coating on B$_4$C may lower infiltration temperature of aluminum when the B$_4$C/Al composites is fabricated by infiltration process. In this study, the effects of TiB$_2$ on the microstructure and mechanical properties of the B$_4$C/Al composites have been investigated. TiB$_2$ coated B$_4$C powder was prepared using the sol-gel technique. It was found that the B$_4$C surface is homogeneously covered with TiB$_2$ having a particles size of 20-50 nm. While the B$_4$C/Al composites prepared by infiltration after TiB$_2$ coating had 17 wt% of unreacted Al, on the other hand, the B$_4$C/Al composites without coating included 14 wt% of Al. As a result, the composites infiltrated after the coating showed higher fracture toughness and lower hardness. This strongly suggests that TiB$_2$ not only lowers the infiltration temperature, but also inhibits the reaction between B$_4$C and Al.

Microstructure and mechanical properties of B4C-SiC composites (탄화붕소-탄화규소 복합체의 미세구조와 기계적 특성)

  • So, Sung Min;Kim, Kyoung Hun;Park, Joo Seok;Kim, Min Suk;Kim, Hyung Sun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.338-344
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    • 2019
  • B4C-SiC composites were fabricated using hot press sintering method without sintering additives at 1,900~2,000℃ under a pressure of 40 MPa. The crystal phase, relative density, microstructure, and mechanical properties of B4C-SiC composites were evaluated. When B4C and SiC were uniformly dispersed in the composite, grain growth was inhibited, and a sintered body with a fine and uniform microstructure, with improved mechanical properties, was fabricated. The relative density of B4C-SiC composites sintered under 2,000℃ of temperature and 40 MPa of pressure was over 99.8 %, and the bending strength and Vicker's hardness at 50 wt% of B4C were 645 MPa and 30.6 GPa, respectively.