Browse > Article

Synthesis and structure of ($C_6CH_2NH_3)_2CUCl_4and \;(NH_3C_6C_4C_2H_4C_6NH_3)CUCl_4$  

김지현 (단국대학교 화학과)
권석순 (단국대학교 화학)
현준원 (단국대학교 응용물리학)
허영덕 (단국대학교 화학과)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.14, no.4, 2004 , pp. 135-139 More about this Journal
Abstract
The layered organic-inorganic hybrid compounds($C_6H_5CH_2NH_3)_2CuCl_4$ and ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$ have been directly synthesized. From the X-ray diffraction data and the organic guest size, the orientation of the intercalated organic amine was determined. The inorganic sheets consist of $CuCl_4^{2-}$layers of comer-sharing octahedra copper chloride. The protonated organic amine was intercalated into the $CuCl_4^{2-}$layers with bilayer structure for ($C_6H_5CH_2NH_3)_2CuCl_4$ and monolayer structure for ($NH_3C_6/H_4C_2H_4_6/H_4NH_3)CuCl_4$.
Keywords
Layered compounds; Inorganic-organic hybrid compound; Monolayer-bilayer structure;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Intercalation chemistry of layered double hydroxides: recent developments and applications /
[ A.I. Khan;D. O'Hare ] / J. Mater. Chem.
2 Anionic surfactants between double metal hydroxide layers /
[ H, Kopka;K. Beneke;G. Lagaly ] / J. Colloid Interface Sci.
3 Hybrid organic-inorganic layered compounds prepared by anion exchange reaction: correlation between structure and magnetic properties /
[ V. Laget;C. Hornick;P. Rabu;M. Drillon ] / J. Mater. Chem.
4 Tailing of energy levels in lead chloride based layered perovskites and energy transfer between the organic and inorganic planes /
[ M. Braun;W. Tuffentsammer;H. Wachtel;H.C. Wolf ] / Chem. Phys. Lett.
5 Preferential intercalation of isomers of anthraquinone sulfonate ions into layered double hydroxides /
[ W.K. Kuk;Y.D. Huh ] / J. Mater. Chem.
6 Organic-inorganic electronics /
[ D.B. Mitzi;K. Chondtousdis;C.R. Kagan ] / IBM J. Res. Dev.
7 A layered solution crystal growth technique and the crystal structure of <TEX>$(C_6H_5C_2H_4NH_3)_2PbCl_4$</TEX> /
[ D.B. Mitzi ] / J. Solid. State Chem.
8 Templating and structural engineering in organic-inorganic perovskites /
[ D.B. Mitzi ] / J. Chem. Soc. Dalton Trans.
9 Observation of spontaneous magnetization in the layered perovskite ferromagnet, (p-chloroanilinium)<TEX>$_2CuBr_4$</TEX> /
[ T. Sekine;T. Okuno;K. Awaga ] / Inorg. Chem.