• Title/Summary/Keyword: C-11

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A Study on the Degradation Characteristics of EPN (EPN의 분해특성에 관한 연구)

  • 이용두;김현희;김창영
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1103-1108
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    • 2002
  • In order to evaluate the degradation organophosphorus pesticide, EPN, in water environment, the effects of water temp.(10$^{circ}C,\;30^{\circ}C$), pH(3-11) and sunlight on its degradation were investigated during 10 days. The degradation rate of EPN(200 rpm) was faster at higher water temp. and higher pH, i.e., its degradation rate at pH 3, 5, 7, 9, 11 was 57, 63, 66, 69, 75%(1$0^{\circ}C$), and 70, 74, 79, 91, 97%(3$0^{\circ}C$) after 10 days, respectively. The effect of water temp. on its degradation was little in acidic condition, but was rather great in alkaline condition, with time. EPN was degraded fast at the alkaline condition by photolysis. At the condition of pH 11, EPN was degraded fast at the early stage in the first 2 days, but after that the degradation rate was weakened.

Mitochondria Activity and CXCR4 Collaboratively Promote the Differentiation of CD11c+ B Cells Induced by TLR9 in Lupus

  • Sung Hoon Jang;Joo Sung Shim;Jieun Kim;Eun Gyeol Shin;Jong Hwi Yoon;Lucy Eunju Lee;Ho-Keun Kwon;Jason Jungsik Song
    • IMMUNE NETWORK
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    • v.24 no.4
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    • pp.25.1-25.14
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    • 2024
  • Lupus is characterized by the autoantibodies against nuclear Ags, underscoring the importance of identifying the B cell subsets driving autoimmunity. Our research focused on the mitochondrial activity and CXCR4 expression in CD11c+ B cells from lupus patients after ex vivo stimulation with a TLR9 agonist, CpG-oligodeoxyribonucleotide (ODN). We also evaluated the response of CD11c+ B cells in ODN-injected mice. Post-ex vivo ODN stimulation, we observed an increase in the proportion of CD11chi cells, with elevated mitochondrial activity and CXCR4 expression in CD11c+ B cells from lupus patients. In vivo experiments showed similar patterns, with TLR9 stimulation enhancing mitochondrial and CXCR4 activities in CD11chi B cells, leading to the generation of anti-dsDNA plasmablasts. The CXCR4 inhibitor AMD3100 and the mitochondrial complex I inhibitor IM156 significantly reduced the proportion of CD11c+ B cells and autoreactive plasmablasts. These results underscore the pivotal roles of mitochondria and CXCR4 in the production of autoreactive plasmablasts.

One-dimensional Schottky nanodiode based on telescoping polyprismanes

  • Sergeyev, Daulet
    • Advances in nano research
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    • v.10 no.4
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    • pp.339-347
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    • 2021
  • In the framework of the density functional theory combined with the method of non-equilibrium Green functions (DFT + NEGF), the electric transport properties of a one-dimensional nanodevice consisting of telescoping polyprismanes with various types of electrical conductivity were studied. Its transmission spectra, density of state, current-voltage characteristic, and differential conductivity are determined. It was shown that C[14,17], C[14,11], C[14,16], C[14,10] show a metallic nature, and polyprismanes C[14,5], C[14,4] possess semiconductor properties and has a band gap of 0.4 eV and 0.6 eV, respectively. It was found that, when metal C[14,11], C[14,10] and semiconductor C[14,5], C[14,4] polyprismanes are coaxially connected, a Schottky barrier is formed and a weak diode effect is observed, i.e., manifested valve (rectifying) property of telescoping polyprismanes. The enhancement of this effect occurs in the nanodevices C[14,17] - C[14,11] - C[14,5] and C[14,16] - C[14,10] - C[14,4], which have the properties of nanodiode and back nanodiode, respectively. The simulation results can be useful in creating promising active one-dimensional elements of nanoelectronics.

One-dimensional Schottky nanodiode based on telescoping polyprismanes

  • Sergeyev, Daulet
    • Advances in nano research
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    • v.10 no.5
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    • pp.471-479
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    • 2021
  • In the framework of the density functional theory combined with the method of non-equilibrium Green functions (DFT + NEGF), the electric transport properties of a one-dimensional nanodevice consisting of telescoping polyprismanes with various types of electrical conductivity were studied. Its transmission spectra, density of state, current-voltage characteristic, and differential conductivity are determined. It was shown that C[14,17], C[14,11], C[14,16], C[14,10] show a metallic nature, and polyprismanes C[14,5], C[14,4] possess semiconductor properties and has a band gap of 0.4 eV and 0.6 eV, respectively. It was found that, when metal C[14,11], C[14,10] and semiconductor C[14,5], C[14,4] polyprismanes are coaxially connected, a Schottky barrier is formed and a weak diode effect is observed, i.e., manifested valve (rectifying) property of telescoping polyprismanes. The enhancement of this effect occurs in the nanodevices C[14,17] - C[14,11] - C[14,5] and C[14,16] - C[14,10] - C[14,4], which have the properties of nanodiode and back nanodiode, respectively. The simulation results can be useful in creating promising active one-dimensional elements of nanoelectronics.

Studies on 5'-Phosphodiesterase produced by microoganisms - Part. I. On the 5'-Phosphodiesterase of Penicillium sclerotiorum - (미생물(微生物)에 의(依)한 5'-Phosphodiesterase생산(生産)에 관(關)한 연구(硏究) - 제1보(第一報) penicllium sclerotiornm의 5'-Phosphodiesterase에 대(對)하여 -)

  • Kim, Ho-Sik;Lee, Ke-Ho
    • Applied Biological Chemistry
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    • v.4
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    • pp.11-16
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    • 1963
  • (1) The 30 strains of Penicillia and the 52 strains of Aspergilli have been screened for their producibility of 5'-Phosphodiesterase, and Penicillium sclerotiorum 7321, Penicillium sp M-11 and Penicillium citrinum UV-mutant 2032-72 were selected as having high 5‘-Phosphodiesterase activity. (2) Using the wheat bran medium the 5‘-Phosphodiesterase production was reached at maximum state by the plate culture for 10 days at $30^{\circ}C$ (3) The optimum conditions of the 5'-Phosphodiesterase activity of Penicillium sclerotiorum 7321 and Penicillium sp M-11 were pH 4.0 at $62.5^{\circ}C$, while the optimum condition of the 5'-Phosphodiesterase activity of Penicillium citrinum UV-mutant 2032-72 was pH 5.0 at $50^{\circ}C$.

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4f spin dynamics in TbNi$_2$B$_2$C by $^{11}$B NMR

  • Lee, K.H.;Seo, S.W.;Kim, D.H.;Khang, K.H.;Seo, H.S.;Hwang, C.S.;Hong, K.S.;Cho, B.K.;Lee, W.C.;Lee, Moo-Hee
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.61-64
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    • 2000
  • $^{11}$B NMR measurements have been performed to investigate local electronic structure and 4f spin dynamics for TbNi$_2$B$_2$C single crystal. $^{11}$B NMR spectra show three resonance peaks due to the quadrupolar interaction. Shift and linewidth are huge and strongly temperature-dependent. In addition, both are proportional to magnetic susceptibility, indicating that the hyperfine field at the boron site originates from the 4f spins of Tb. $^{11}$B NMR shift and relaxation rates show high anisotropy for field parallel and perpendicular to the c-axis. Anisotropy of the shift and the relaxation rates suggests that the hyperfine field perpendicular to the c-axis is larger.

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Synthes is of 9,10-difluoro-5,6,6a,7,11b-pentahydroindano [2,1-c]isoquinoline (9,10- 디플루오르 -5,6,6a,7,11b- 펜타하이드로인다노[2,1-c] 이소퀴놀린의 합성)

  • Ma, Eun-Sook;Kim, Min-Jung
    • YAKHAK HOEJI
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    • v.44 no.6
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    • pp.505-510
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    • 2000
  • The synthesis of pentahydroindanoisoquinoline (4) compound has been achieved via the cyclization of 2-(N-benzylamino)-5,6-difluoro-1-indanol (10a, 10b), which was prepared by condensation and reduction of 2-amino-1-indanol and benzaldehyde in ethanol. The stereochemistry of $H_{6a}$ and $H_{11b}$ of 9,10-difluoro-5,6,6a,7,11b-pentahydroindano[2,1-c]isoquinoline (4) was the trans B/C ring fusion.

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Synthesis and de-pigmentation effect of phenolic glucoconjugates

  • Kim, Ki-Ho;Kim, Ki-Soo;Lee, Jae-Soeb;Ko, Kang-Il;Lee, Soo-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.27 no.1
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    • pp.99-109
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    • 2001
  • Novel glucoconjugates phenolic moiety, 3-(methoxycarbonyl)-4-(hydroxyphenyl)-$\beta$-D-glucopyranoside(4), 3-(methoxyacetyl)-4-(hydroxyphenyl)-$\beta$-D-glucopyranoside(7), 4-(hydroxyphenyl)-$\beta$-D-ribofuranoside(11), were synthesized. In order to investigate their depigmentation effect, inhibitory activity against mushroom tyrosinase and inhibitory activity of melanin synthesis in B16 melanoma cell were evaluated in vitro. Compound 11 showed 92.0$\mu\textrm{g}$/㎖ of tyrosinase inhibitory activity whereas compound 4 and 7 showed very low activity not less than 300$\mu\textrm{g}$/㎖. Inhibitory activities of melanin synthesis in B16 melanoma cell of compound 4, 7, and 11 were 8.7, 15.1, and 36.0%, respectively, at the concentration of 100$\mu\textrm{g}$/㎖. Inhibitory activity of compound 11 was much higher than that of arbutin at the same concentration.

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IEEE802.11g WLAN 시스템을 위한 OFDM 알고리즘의 DSP(TMX320C6416) 구현

  • 김세현;조성호
    • Proceedings of the Korean Information Science Society Conference
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    • 2003.04d
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    • pp.316-318
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    • 2003
  • 본 논문에서는 무선랜 프로토콜 IEEE802.11g에서 사용되는 변조방식인 OFDM (Orthogonal frequency division multiplexing) 방식을 TMX320C6416을 사용하여 구현하였다. 통신 시스템의 발달에 따라 고속으로 데이터를 전송하는 방식이 요구되었고, 유선망 없이 장소에 구애 받지 야고 데이터를 송수신할 수 있는 무선랜 시스템의 필요성이 증가하고 있다. 이러한 필요성에 따라 2002년 6월 현재 발표된 IEEE 802.11g 규격 Draft 2.8은 2.4GHz 주파수 대역에서 기존 IEEE 802.11b규격과 호환성은 유지하며 전송속도를 최소 20Mbps 이상을 목표로 한다. IEEE802.119에 정의된 규정에 따라 OFDM방식의 기저대역 알고리즘을 TMX320C6416 을 사용하여 각 블록별로 C언어로 구현하였고, TMX320C6416에 대한 리니어 어셈블리 언어로 구현하는 최적화 작업을 통해 연산속도를 향상시키는 것을 목적으로 하며, 구현한 알고리즘의 비트 오류 확률을 매트랩 시뮬레이션 결과와 비교해 보도록 한다.

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Mosquito Larvicidal Activity of Synechocystis PCC6803 Transformed with the cry11Aa gene to Culex tritaeniorhynchus and Anopheles sinensis (Cry11Aa 유전자로 형질전환된 Synechocystis PCC6803의 작은빨간집모기와 중국얼룩날개모기 유충에 대한 살충효과)

  • 이대원
    • Korean journal of applied entomology
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    • v.43 no.1
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    • pp.35-41
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    • 2004
  • Bacillus thuringiensis produces crystal proteins toxic to medically and agriculturally important pests during sporulation. To improve the activity of insecticidal crystal protein in applying to mosquito larval control, an expression vector, pSyn4D harboring the mosquitocidal cry11Aa gene under control of psbA promoter of Amaranthus hybridus was constructed. This expression vector was transformed into Synechocystis PCC6803 and a transformant, Tr2C was selected with kanamycin. The mosquitocidal cry11Aa gene was stably integrated Into genomic DNA of Tr2C in PCR detection using cry11Aa-specific primers. The transformant expressed 72-kDa Cry11Aa protein and median lethal time (LT$\sub$50/) was approximately 2.1 days for Culex tritaeniorhynchus larvae and 0.7 day for Anopheles sinensis larvae, respectively. These results suggest this transformant can be used for mosquito larval control as a biological control agent.