• Title/Summary/Keyword: C-플레이트

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Thermal Curing and Electrical Properties of Epoxy/Graphite/Expanded Graphite Composite for Bipolar Plate of Pemfc (PEMFC 바이폴라 플레이트 제조용 EPOXY/GRAPHITE/EXPANDED GRAPHITE 복합재료의 열경화 및 전기적 성질)

  • Lee, Jae-Young;Lee, Hong-Ki
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.827-834
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    • 2011
  • Epoxy/graphite/expanded graphite composites have been prepared in various weight ratios and thermal degradation and electrical properties were estimated in order to use for the bipolar plate materials in PEMFC. Thermogravimetric analysis (TGA) showed that the epoxy/graphite system cured by a curing agent GX-533 was most proper because its weight loss until $80^{\circ}C$ at which PEMFC would be operated was 0.3 wt%, and differential scanning calorimetry (DSC) analysis showed its cure temperature would be sufficient at $80^{\circ}C$. The activation energy for the cure reaction was 132.0 kJ/mol and the pre-exponential factor was $1.76{\times}10^{17}min^{-1}$. Electrical conductivity on the surface of the bipolar plate prepared under a pressure of 200 $kgf/cm^2$ was increased from 4 to 25 $S/cm^2$ by increasing expanded graphite (EG) content from 50 phr to 90 phr. The percolation threshold was initiated around 75 phr and the corrosion rate at 80 phr was 1.903 $uA/cm^2$.

Study on R-l34a, R-407C, and R-410A Condensation Performance in the Oblong Shell and Plate Heat Exchanger (오블롱 셀 플레이트 열교환기에서의 R-l34a, R-407C, R-410A의 응축성능에 관한 실험적 연구)

  • Park, Jae-Hong;Kim, Young-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1535-1548
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    • 2004
  • Condensation heat transfer experiments were conducted with the oblong shell and plate heat exchanger without oil in a refrigerant loop using R-l34a, R-407C and R-410A. An experimental refrigerant loop has been developed to measure the condensation heat transfer coefficient h$_{r}$ and frictional pressure drop $\Delta$p$_{f}$ of the various refrigerants in a vertical oblong shell and plate heat exchanger. The effects of the refrigerant mass flux(40∼80kg/$m^2$s), average heat flux(4∼8kW/$m^2$), refrigerant saturation temperature(30∼4$0^{\circ}C$) and vapor quality of refrigerants on the measured data were explored in detail. Similar to the case of a plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. A comparison of the performance of the various refrigerants revealed that R-410A had the highest heat transfer performance followed by R-l34a, and R-407C had the lowest performance of the refrigerants tested. The pressure drops were also reported in this paper. The pressure drops for R-410A were approximately 45% lower than those of R-l34a. R-407C had 30% lower pressure drops than R-l34a. Experimental results were compared with several correlations which predicted condensation heat transfer coefficients and frictional pressure drops. Comparison with the experimental data showed that the previously proposed correlations gave unsatisfactory results. Based on the present data, empirical correlations of the condensation heat transfer coefficient and the friction factor were proposed.tor were proposed.sed.

Variation of Seismic Behavior of Continuous Skew Plate Girder Bridges According to the Arrangement of Bearings (받침배치에 따른 연속 플레이트 거더 사교의 지진거동 변화)

  • Moon, Seong Kwon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.5
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    • pp.124-135
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    • 2011
  • The capacity of bearings installed at abutments and piers for continuous bridges is usually determined by the magnitude of the maximum vertical reaction at each support and the capacity of bearings placed at piers is higher than that at abutments. In this study, the possibility of the improved seismic performance of base-isolated continuous skew bridges was investigated by analysing the variation of the seismic behavior of them according to three arrangements of bearings. Based on the conventional arrangement of bearings(Case A), three arrangements of bearings such as Case A, Case B and Case C were selected considering the variation of the horizontal stiffness of the lead rubber bearing(LRB) installed at the pier. The seismic behavior of the total 36 skew bridges was investigated by conducting the response spectrum analysis using the hybrid response spectrum considered the effect of LRB's damping. Results of analyses show that a more desirable seismic behavior of base-isolated continuous skew bridges can be obtained by reducing the magnitude of the horizontal stiffness of LRB placed at the pier to similar to or less than that of LRB installed at abutments. The variation of LRB's stiffness at the pier brings about period elongation and the change of mode shapes of base-isolated skew bridges and results in the reduction of the total base shear, the maximum base shear at the pier and the girder stresses. Although positive effects on the seismic behavior of base-isolated skew bridges caused by the change of arrangement of bearings decreased slighty with an increase in the flexibility of the substructure, the proposed arrangements of bearings bring about the improved seismic performance of base-isolated continuous skew plate girder bridges with less than 10m height of piers.

Improvement of Flexural Performance for Deep-Deck Plate using Cap Plate (캡플레이트를 이용한 장스팬용 춤이 깊은 데크의 휨성능 개선)

  • Park, K.Y.;Nam, Y.S.;Choi, Y.H.;Kim, Y.H.;Choi, S.M.
    • Journal of Korean Society of Steel Construction
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    • v.25 no.5
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    • pp.555-567
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    • 2013
  • Slim floor system using deep decks has been developed and employed in Europe to reduce the floor height of steel structures. Although long span buildings involving the issue of reducing floor height are being increasingly built in Korea, employing deep decks in more than 7m long span structures is likely to cause problems associated with excessive deflection. This study is applied to the long-span concrete casting of the deep deck plate usability of deflection due to bending and torsional instability of open cross-section, as a way to improve the problem of cap plates are suggested, and the optimum length of reinforcement and location are derived from theoretic estimation. The cap plates are placed on the deep decks with regular intervals to overcome the instability of open sections, improve the stiffness of the sections and control the deflection at the centers. The improvement in flexural capacity associated with the location of the cap plates and the length of reinforcement are verified through analysis and test.

Study on Evaporation Heat Transfer of R-l34a, R-407C, and R-410A in the Oblong Shell and Plate Heat Exchanger (오블롱 셀 플레이트 열교환기에서의 R-l34a, R-407C, R-410A의 증발 열전달에 관한 실험적 연구)

  • 박재홍;김영수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.9
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    • pp.845-854
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    • 2004
  • The evaporation heat transfer coefficient for R-l34a, R-407C (a mixture of 23wt% R-32, 25 wt% R-125, and 52 wt% R-l34a) and R-410A (a mixture of 50 wt% R-32 and 50 wt% R-125) flowing in the oblong shell and plate heat exchanger were investigated experimentally in this study. Four vertical counterflow channels were formed in the exchanger by four plates of commercial geometry with a corrugated sinusoid shape of a chevron angle of 45 degree. The effects of the mean vapor quality, mass flux, heat flux, and saturation temperature of different refrigerants on the evaporation heat transfer were explored in detail. Similar to the case of a Plate heat exchanger, even at a very low Reynolds number, the flow in the oblong shell and plate heat exchanger remains turbulent. It is found that the evaporation heat transfer coefficient in the plates is much higher than that in circular pipes. The present data show that the evaporation heat transfer coefficients of all refrigerants increase with the vapor quality. At a higher mass flux h, is higher than for the entire range of the vapor quality. Raising the imposed wall heat flux was found to slightly improve h$_{r}$, while h$_{r}$ is found to be lower at a higher refrigerant saturation temperature. A comparison of the performance of the various refrigerants reveals that R-410A has the highest heat transfer performance followed by R-l34a, and R-407C had the lowest performance of the refrigerants tested. Based on the present data, empirical correlations of the evaporation heat transfer coefficient were proposed.sed.

Preparation and Polymerization of Alkenylsilanes (Alkenylsilane의 제조와 고분자화반응)

  • Kim, Chung Kyun;Choi, Soon Kyu;Park, Eun Mi;Jung, In Kyung
    • Journal of the Korean Chemical Society
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    • v.41 no.2
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    • pp.88-97
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    • 1997
  • The silyltriflates$(Ph_{3-n}SiH(OTf)_n)$have been produced by the reaction of triphenylsilane and triflic acid$(CF_3SO_3H)$at low temperature. These highly reactive compounds are a valuable reagent for the synthesis of numerous new functional substituted silane derivatives. The reaction of silyltriflates with alkenyl- and alkynylmagnesium bromide as well as organolithium compounds gave new silanes$Ph_2SiHR(R=\;C(CPh,\;CH=CH_2,\;CH_2CH=CH_2,\; (CH_2)_2CH=CH_2,\;(CH_2)_3CH=CH_2)$in high yields. The hydrosilation of prepared alkenyl- and alkynylsilanesPh_2SiHR$in the presence of a platinum catalyst(Pt/C) at high temperature$(200{\circ}C)$gave carbosilane polymers$((Ph_2SiCH=CPh)_n$and$(Ph_2Si(CH_2)m)n;\;m=2∼4, n{\ge}10)$along with five- and six-membered silaalkane ring compounds derived from intramolecular hydrosilation reactions. All of the prepared compounds are confirmed by NMR, UV, IR and mass spectroscopy as well as elemental analysis.

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Reliability Analysis of Single and Continuous Span Composite Plate and Box Girder Designed by LRFD Method under Flexure (LRFD법으로 설계된 단경간 및 연속경간 강합성 플레이트 거더 및 박스 거더의 휨에 대한 신뢰도해석)

  • Shin, Dong Ku;Roh, Joon Sik;Cho, Eun Young
    • Journal of Korean Society of Steel Construction
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    • v.20 no.1
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    • pp.183-193
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    • 2008
  • The reliability analysis of simply-supported and continuous composite plate girder and box girder bridges under flexure was performed to provide a basic data for the development of LRFD c ode. The bridges were designed based on LRFD specification with newly proposed design live load which was developed by analyzing traffic statistics from highways and local roads. A performance function for flexural failure was expressed as a function of the flexural resistance of composite section and the design moments due to permanent load and live load. For the flexural resistance, the statistical parameters obtained by analyzing over 16,000 domestic structural steel samples were used. Several different values of bias factors for the live load moment from 1.0 to 1.2 were used. Due to the lack of available domestic measured data on the moment by permanent loads, the same statistical properties used in the calibration of ASHTO-LRFD were ap plied. The reliability indices for the composite girder bridges with various span lengths, different live load factors, and bias fact or for the live load were obtained by applying the Rackwitz-Fiessler technique.

A Study on Characteristic Analysis of C-Plate Cover and Examination of Weak Parts (C-Plate 커버의 구조해석 및 취약부 규명)

  • 김옥구;송준엽;강재훈;박화영
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.373-377
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    • 2003
  • Recently, advanced manufacturing systems with high speed and intelligence have been developed for the betterment of machining ability. In this case, reliability prediction work with motion characteristic evaluation of sliding cover(C-plate, Bellows, etc) has also important role from design procedure to manufacturing and assembly process. Accordingly in this study, H/W test-bed system for reliability evaluation of sliding cover has been developed to obtain proper reference data for design of new model, prevention trouble (failure mode), and improvement of quality and lift cycle extremely for advanced mother machinery.

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Preventive effects of shiitake mushroom extract on candida stomatitis (칸디다성 구내염에 대한 표고버섯 추출물의 예방효과)

  • Yoo, Hyun-Jun
    • Journal of Dental Rehabilitation and Applied Science
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    • v.37 no.3
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    • pp.123-129
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    • 2021
  • Purpose: The purpose of this study was to investigate antifungal activity of shiitake mushroom yeast and hyphal type of Candida albicans. Materials and Methods: The extract from shiitake mushroom was collected by drying the supernatant after soaking shiitake mushrooms in water or ethanol. The antifungal activity of the extracts against yeast type of C. albicans was investigated by the susceptibility assay using microplate. C. albicans biofilm was formed on 12-well plate using Ham's F-12 medium in CO2 incubator and treated with the ethanol extract. Furthermore, C. albicans biofilm was formed on denture base resin disk and treated with or without the ethanol extract in the presence of denture cleanser. Live C. albicans in biofilm was counted by cultured colony forming unit value after inoculated on agar plate. Results: Ethanol extract from shiitake mushroom showed stronger antifungal activity against yeast type of C. albicans compared to its water extract. The ethanol extract significantly reduced count of C. albicans in hyphal biofilm (P < 0.05). Also, the ethanol extract showed synergistically antifungal effect with denture cleanser on candidal biofilm on denture base resin disk (P < 0.05). Conclusion: The ethanol extract of shiitake mushroom may be a candidate for preventing candidal stomatitis as well as denture-related stomatitis.