• Title/Summary/Keyword: C : N : P

Search Result 7,885, Processing Time 0.042 seconds

Reactions of Thianthrene Cation Radical Perchlorate with N-Arylbenzene- and N-Aryl-p-toluenesulfonamides. Synthesis of 5-(p-N-Arylbenzenesulfonamidephenyl)- and 5-(p-N-Aryl-p-toluenesulfonamidophenyl)thianthrenium Perchlorate (티안트렌 양이온 자유라디칼 과염소산염과 N-아릴벤젠술폰아미드 및 N-아릴-p-톨루엔술폰아미드의 반응. 5-(p-N-아릴술폰아미드페닐)티안트렌이움 과염소산염과 5-(p-N-아릴-p-톨루엔술폰아미드페닐)티안트렌이움 과염소산염의 합성)

  • Sung Hoon Kim;Kyongtae Kim
    • Journal of the Korean Chemical Society
    • /
    • v.25 no.6
    • /
    • pp.383-389
    • /
    • 1981
  • Thianthrene cation radical perchlorate reacts with N-arylsulfonamides such as p-toluenesulfonanilide, benzenesulfonanilide, N-(2-methylphenyl)benzenesulfonamide, and N-phenyl-p-toluenesulfonanilide to give 5-(p-N-p-toluenesulfonamidophenyl)-(1a), 5-(p-N-benzenesulfonamidophenyl)-(1b), 5-(4-N-benzenesulfonamido-3-methylphenyl)-(1c), and 5-(p-N-phenyl-N-p-toluenesulfonamidophenyl thianthrenium perchlorate (1d), respectively. In the meantime, 1d reacts further with thiathrene cation ratical to form diperchlorate(1e). The structure of 1a~1e is very similar to 5-(p-acetamidophenyl) thianthrenium perchlorate which has been obtained from the reaction with acetanilide. However, the discrepancy in the stoichiometry between two reactions indicates that the reaction with sulfonamide appears not to proceed with a single mechanism.

  • PDF

Temperature Effect on Nitrification and Interrelationship between Nitrifiable NO3-N and Tobacco Productivity in Some Tobacco Tillage Soils with Different Soil pH (토양(土壤)pH가 상이(相異)한 몇가지 연초경작지(煙草耕作地) 토양(土壤)에서 질산화작용(窒酸化作用)에 대한 온도효과(溫度效果) 및 NO3-N와 잎담배 생산성(生産性)과의 상호관계(相互關係))

  • Hong, Soon-Dal;Jeong, Hun-Chae;Lee, Yun-Hwan;Kim, Jai-Joung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.22 no.4
    • /
    • pp.290-295
    • /
    • 1989
  • An incubation study was conducted to examine the effect of soil pH and temperature on nitrification potential of 8 different soil series applied with no-N and 200 ugN/g soil as a compound fertilizer at 60 % moisture content of maximum water holding capacity for 8 weeks, whose series were ranged from acid to mild alkali as Gopyeong(Jincheon, pH 4.51), Yesan(Jincheon, pH 4.54), Jigog(Eumseong, pH 4.71), Songsan(Goesan, pH 5.01), Angye(Seongju, pH 5.34), Banho(Seongju, pH 5.73), Weongog(Jincheon, pH 5.93), and Banho(Seongju, pH 7.70), respectively. Interrelationship between the nitrifiable and the net $NO_3-N$(N added plot-no-N plot) accumulated in the soil and tobacco yield in the no fertilizer plot were investigated as well. 1. Nitrification response was various according to soil characteristics at each temperature condition showing that nitrifiable $NO_3-N$ values of the soils were much higher at $25^{\circ}C$ than $15^{\circ}C$. And difference of nitrification potential affected by temperature was markedly distinguishable from 2 weeks after incubation and was showing a tendency to reduce with increasing of soil pH. 2. At each temperature condition, net $NO_3-N$ accumulated at 2 and 4 weeks after incubation was positively correlated with soil pH. 3. Tobacco yield in the no fertilizer plot was more highly correlated with the values of nitrifiable and net $NO_3-N$ accumulated at $15^{\circ}C$ similar to soil temperature in rhizosphere of early stage of tobacco growth than those at optimum temperature($25^{\circ}C$).

  • PDF

Conjugal Transfer of NAH, TOL, and CAM::TOL* Plasmid into n-Alkane Assimilating Pseudomonas putida (방향족 탄화수소 분해 Plasmid의 n-Alkane 자화성 Pseudomonas putida에로의 전이)

  • Kho, Yung-Hee;Chun, Hyo-Kon;Cho, Kyong-Yun;Bae, Kyung-Sook
    • Microbiology and Biotechnology Letters
    • /
    • v.17 no.1
    • /
    • pp.51-55
    • /
    • 1989
  • The conjugally transferred TOL plasmid or NAH plasmid was stably maintained and expressed in n-alkane assimilating Pseudomonas putida KCTC 2405. However, these plasmids were not able to coexist in this strain because of incompatibility. The incompatibility of TOL and NAH plasmid was bypassed using CAM::TOL* plasmid, which was constructed by the transposition of only tol gene without incompatibility system in TOL plasmid into CAM plasmid. p. putida 3SK capable of growing on m-toluate, naphthalene, camphor, and n-alkane(C8-C24) was constructed by the conjugal transfer of NAH plasmid into n-alkane assimilating p. putida SK carrying CAM:: TOL* plasmid. CAM::TOL* plasmid in p. putida 3SK was stable on the selective media but unstable on the nonselective media.

  • PDF

Identification and Characterization of Alginate Lyase Producing Pseudomonas sp. N7151-6 (Alginate Lyase 생산 균주 Pseudomonas sp. N7151-6의 분리 및 특성)

  • Lee, Jae-Hyung;Bae, Min-Ji;Kim, Yang-Choon;Nam, Soo-Wan
    • Microbiology and Biotechnology Letters
    • /
    • v.37 no.4
    • /
    • pp.350-354
    • /
    • 2009
  • A Gram-negative, alginate lyase-producing bacterium was isolated from the Haeundae Coast, Korea. The isolated strain N7151-6 produced alginate lyase. The optimal temperature and pH for growth were found to be $30^{\circ}C$ and pH 8.0, respectively. This strain can be grown at the NaCl concentration of 0-7% (w/v). Analysis of 16S rDNA sequence and physiological profiling indicated that the strain N7151-6 belonged to Pseudomonas sp. The enzyme alginate lyase produced by Pseudomonas sp. N7151-6 was partially purified by ultrafiltration (MWCO= 30 kDa). The optimum pH and temperature for the activity of the purified enzyme were found to be 7.0 and $30^{\circ}C$, respectively. The enzyme was stable at the pH range of 5.0-9.0 and temperature range of $23-30^{\circ}C$. The total activity of alginate lyase produced was reached about 110 unit/L.

Determination of cimetidine injection by square wave voltammetry (네모파 전압전류법에 의한 Cimetidine 주사액의 정량분석)

  • Lee, Soo-Jung;Hahn, Young-Hee
    • Analytical Science and Technology
    • /
    • v.23 no.1
    • /
    • pp.68-73
    • /
    • 2010
  • In order to develop the square wave voltammetric method determining cimetidine in an ampoule for injection, $5.00{\times}10^{-4}\;M$ cimetidine HCl solutions prepared with phosphate buffers of various pH values (3.01~8.97) were investigated by SWV. The well defined single peak due to the electrochemical reduction of -C=N-C$\equiv$N- in the structure of cimetidine moved towards the cathodic direction by -0.051V/pH as the pH values were increased indicating the involvement of hydrogen in its reduction. The calibration curves of cimetidine HCl in the concentration range between $1.00{\times}10^{-5}\;M$ and $5.00{\times}10^{-3}\;M$ prepared using three phosphate buffers yielded the slopes of 127,407nA/M (pH 3.01), 115,125nA/M (pH 5.00) and 111,287nA/M(pH 7.00) with excellent linearities of $R^2{\geqq}0.9997$. When one ampoule of Tagma Inj.$^{(R)}$ was analyzed by standard addition method by SWV, the within-day precision study (n=4) on the day of sample preparation resulted in the contents of cimetidine as $203{\pm}3.8\;mg$ (102% of the specified contents, RSD of 1.9%) and the inter-day precision (n=4) through 5 days was reasonable as 1.3% of RSD.

SOME RESULTS ON UNIQUENESS OF MEROMORPHIC SOLUTIONS OF DIFFERENCE EQUATIONS

  • Gao, Zong Sheng;Wang, Xiao Ming
    • Communications of the Korean Mathematical Society
    • /
    • v.32 no.4
    • /
    • pp.959-970
    • /
    • 2017
  • In this paper, we investigate the transcendental meromorphic solutions with finite order of two different types of difference equations $${\sum\limits_{j=1}^{n}}a_jf(z+c_j)={\frac{P(z,f)}{Q(z,f)}}={\frac{{\sum_{k=0}^{p}}b_kf^k}{{\sum_{l=0}^{q}}d_lf^l}}$$ and $${\prod\limits_{j=1}^{n}}f(z+c_j)={\frac{P(z,f)}{Q(z,f)}={\frac{{\sum_{k=0}^{p}}b_kf^k}{{\sum_{l=0}^{q}}d_lf^l}}$$ that share three distinct values with another meromorphic function. Here $a_j$, $b_k$, $d_l$ are small functions of f and $a_j{\not{\equiv}}(j=1,2,{\ldots},n)$, $b_p{\not{\equiv}}0$, $d_q{\not{\equiv}}0$. $c_j{\neq}0$ are pairwise distinct constants. p, q, n are non-negative integers. P(z, f) and Q(z, f) are two mutually prime polynomials in f.

Effect of Pre-NH3 Stripping on the Advanced Sewerage Treatment by BNR (BNR에 의한 하수의 고도처리에 미치는 NH3 스트리핑 전처리의 영향)

  • Seo, Jeong-Beom;An, Kwang-Ho
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.5
    • /
    • pp.846-850
    • /
    • 2006
  • The biological nutrient removal from domestic wastewater with low C/N ratio is difficult. Therefore, this study was performed to increase influent C/N ratio by ammonia stripping without required carbon source and for improving treatment efficiencies of sewerage by the combination process of ammonia stripping and BNR (StripBNR). The results of this study were summarized as follows. BOD removal efficiencies of BNR and StripBNR were 95.3% and 93.2%, respectively. T-N and T-P removal efficiencies of BNR were 53.3% and 40.8%, respectively. T-N and T-P removal efficiencies of StripBNR were 72.8% and 62.9%, respectively. Concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at BNR effluent were 0.03 mg/L, 0.08 mg/L and 9.12 mg/L, respectively. On the other hands, concentrations of $NH_3-N$, $NO_2-N$ and $NO_3-N$ at StripBNR effluent were 5.79 mg/L, 0.01 mg/L and 0.14 mg/L, respectively. Consequently, influent C/N ratio of BNR process was increased by ammonia stripping. Removal efficiency of T-N and T-P was improved about 20% by the process of StripBNR.

Realistic Simulations on Reverse Junction Characteristics of SiC and GaN Power Semiconductor Devices

  • Wei, Guannan;Liang, Yung C.;Samudra, Ganesh S.
    • Journal of Power Electronics
    • /
    • v.12 no.1
    • /
    • pp.19-23
    • /
    • 2012
  • This paper presents a practical methodology for realistic simulation on reverse characteristics of Wide Bandgap (WBG) SiC and GaN p-n junctions. The adjustment on certain physic-based model parameters, such as the trap density and photo-generation for SiC junction, and impact ionization coefficients and critical field for GaN junction are described. The adjusted parameters were used in Synopsys Medici simulation to obtain a realistic p-n junction avalanche breakdown voltage. The simulation results were verified through benchmarking against independent data reported by others.

I-V Characteristics of Epitaxial $CoSi_2$-contacted p+/n Junctions (Epitaxial $CoSi_2$접촉 p+/n 접합의 I-V 특성)

  • 구본철;김시중;김주연;배규식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.13 no.11
    • /
    • pp.908-913
    • /
    • 2000
  • CoSi$_2$/p+/n diodes(bilayer diodes) were fabricated by using epitaxial CoSi$_2$grown from Co/Ti bilayer as a diffusion source. The I-V characteristics of p+/n diodes were measured and compared with those of diode made from Co monolayer (monolayer diode). Monolayer diodes showed typical p+n junction characteristics with the leakage current of as low as 10$^{-12}$ A and forward current 6-orders higher than the leakage current, when drive-in annealed at 90$0^{\circ}C$ for 20 sec.. On the other hand, bilayer diodes showed the Schottky-like behaviors with forward currents rather higher than those of monolyer diodes, but with too high leakage currents, when drive-in annealed at $700^{\circ}C$ or higher. However, when the annealing temperature was lowered to $700^{\circ}C$ and annealing time was increased to 60 sec., the leakage current was reduced to 10$^{-11}$ A and thus sho3wed typical diode characteristics. The high leakage currents for diodes annealed at $700^{\circ}C$ or higher was attributed to Shannon contacts formed due to unremoved Co-Ti-Si precipitates. But when annealed at 50$0^{\circ}C$, B ions diffused in the direction of the surface layer, and thus the leakage currents were reduced by removing Shannon contacts.

  • PDF

AN ESCAPE CRITERION FOR THE COMPLEX POLYNOMIAL, WITH APPLICATIONS TO THE DEGREE-n BIFURCATION SET

  • Kim, Young Ik
    • Journal of the Chungcheong Mathematical Society
    • /
    • v.16 no.1
    • /
    • pp.7-14
    • /
    • 2003
  • Let $P_c(z)=z^n+c$ be a complex polynomial with an integer $n{\geq}2$. We derive a criterion that the critical orbit of $P_c$ escapes to infinity and investigate its applications to the degree-n bifurcation set. The intersection of the degree-n bifurcation set with the real line as well as with a typical symmetric axis is explicitly written as a function of n. A well-defined escape-time algorithm is also included for the improved construction of the degree-n bifurcation set.

  • PDF