• Title/Summary/Keyword: Bulk samples

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The Study on Secondary Pollutants of $PM_{10}$ in Pocheon (포천지역에서 측정한 $PM_{10}$중 2차 생성입자에 관한 연구)

  • Park Tae-Sool
    • Journal of environmental and Sanitary engineering
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    • v.20 no.4 s.58
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    • pp.9-20
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    • 2005
  • The purpose of the study was characteristics of secondary pollutants of $PM_{10}$ collected in pocheon between August 2002 and June 2003. The ambient concentrations of $PM_{10}$ mass, 9 water-soluble anions and cations, and 13 bulk composition trace elements were determined from filter samples collected by $PM_{10}$ high volume air sampler(UV-15H, Graseby-Anderson Co., USA). During this period average $PM_{10}$ mass concentration was $83.8{\mu}g/m^3(49.8{\mu}g/m^3\~111.6{\mu}g/m^3)$ in Pocheon. Mechanism for transformation of secondary pollutants by soluble ion components is divided into two categories; $NaNO_3$ type by the reaction of sea salt and $HNO_3$ in the atmosphere, and nitrate salt or phosphate salt type such as $(NH_4)_2SO_4,\;NH_4NaSO_4,\;and\;(NH_4)_2SO_4(2NH_4O_3)$.

Structural and Dielectric Properties of Epoxy-Organoclay Nanocomposites using Power Ultrasonic Dispersion (초음파 분산을 이용한 Epoxy-Organoclay 나노콤포지트 구조적 그리고 유전특성에 관한 연구)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.9
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    • pp.1572-1578
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    • 2008
  • The effect of the organoclay_10A nanoparticles on the DSC and Structural and Dielectrics Properties(1Hz-1MHz) for epoxy/Organoclay_10A Nanocomposites has been studied. Dielectric properties of epoxy-Organoclay nanocomposites were investigated at 1, 3, 5, 7, 9 filler concentration by weight. Epoxy nanocomposites samples were prepared with good dispersion of layered silicate using power ultrasonic method in the particles. As structural analysis, the interlayer spacing have decreased with filled nanoparticles contents increase using power ultrasonic dispersion. The maximum increase interlayered spacing was observed to decease for above 5wt% clay loading. The other hand, as decrease with concentration filler of the layered silicate were increased dispersion degree of nanoparticles in the matrix. The interesting dielectric properties for epoxy based nanocomposites systems are attributed to the large volume fraction of interfacesin the bulk of the material and the ensuring interactions between the charged nanoparticle surface and the epoxy chains.

Synthesis of Novel Morpholine Appended Crystal violet lactone Derivatives and an Investigation of Their Thermochromic Behavior

  • Kim, Myeong Jin;Muthukumar, Palanisamy;Angupillai, Satheshkumar;Son, Young-A
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.1-8
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    • 2018
  • In the present study, three morpholine substituted crystal violet lactone (CVL) have been synthesized to monitor the thermochromic property. This work is explaining the role of substituent on the lactone ring. The methyl substituents induced greater chromic effects than the chloro substituents. Furthermore, the three-component mixtures that contained CVL, bisphenol-A, and methyl stearate were used to analyse the thermochromic effect of the CVLs as bulk samples with various temperature. The thermochromic properties of the CVLs were evaluated using solid-state UV-Vis and FT-IR spectroscopic techniques. Finally, one of the synthesized CVL has been successfully converted into the form of a test paper similar to pH paper for use as thermal indicators.

Single-cell Electroporation and Gene Transfection using MEMS-based Microdevice with Cantilever-type Microelectrode (멤스 기반의 캔틸레버 형 전극을 가진 마이크로 디바이스를 이용한 단일세포의 Electroporation 및 유전자 Transfection)

  • Cho, Young-Hak;Kim, Beom-Joon
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.5
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    • pp.85-91
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    • 2010
  • In this paper, we present details on fabrication of single-cell electroporation microdevice, practical experiments of single-cell electroporation with our fabricated microdevice. Also, the continuous electroporation for the continuous flow of cells is used for high-throughput electroporation. The delivery efficiency and cell viability tests are provided and the successful GFP transfection into cells is also evaluated with a fluorescent microscope after electroporation. This device enables to reduce the size of samples and thus the use of small amount of reagents. Also, it makes it possible to permit to avoid cell discrimination (transfected cells versus non-transfected cells) encountered when traditional bulk electroporation is held.

신문용지의 인쇄적성 계수에 관한 연구 I -최대 전이점에서 인쇄 색농도, 뒤비침-

  • Ha, Yeong-Baek;Kim, Chang-Geun;O, Seong-Sang;Yun, Jong-Tae
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2005.11a
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    • pp.187-196
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    • 2005
  • Newsprint is quantitatively the most important printing paper. The demands for its printability are continuously increasing. It is well known that the relationship between the physically tested paper properties and newspaper printability is unsatisfactory. In order to improve the printing quality of Korean newsprint, the printability coefficients such as maximum ink requirement($Y_{max}$), print through were investigated. Kinds of Korean newspapers and three kinds of news printing inks were tested by IGT printability tester. Experiment condition of IGT printability tester was 14 steps between $0.2{\sim}2.8g/m^2$ of ink requirement, printing pressure was .200 N and printing velocity was 1m/sec. The properties of newspaper samples(basis weight, bulk density, roughness, smoothness, porosity, i. e.) were examined in accordance with KS and TAPPI standard testing methods. The result of this study are respected for usefulness printing quality management of Korean newsprint.

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Nanoconfinement effects of MCM-41 on the thermal decomposition of metal borohydrides

  • Kim, Sanghoon;Song, Hyejin;Kim, Chul
    • Analytical Science and Technology
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    • v.31 no.1
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    • pp.1-6
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    • 2018
  • We used differential scanning calorimetry and a thermogravimetric analysis to investigate the effect of being confined in mesoporous MCM-41 on the decomposition of lithium borohydride and magnesium borohydride when heated. The confinement did not cause a phase transition of the metal borohydrides inside MCM-41, but did lower their decomposition temperature. With the exception of a lowering of the temperature, the decomposition reaction mechanism of the metal borohydrides was nearly the same for both the bulk and confined samples.

Product Phase Control During Interdiffusion Reactions (상호 확산 반응 중의 생성상 제어)

  • Park, Joon-Sik;Kim, Ji-Hoon;Perepezko, John R.
    • Journal of Korea Foundry Society
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    • v.26 no.1
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    • pp.27-33
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    • 2006
  • Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.

A Study on Ageing Characteristics of RTV Silicone Coating Materials by Corona Discharge (RTV 실리콘 코팅재의 코로나 방전 열화 특성)

  • 한세원;한동희;조한구
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.8
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    • pp.359-364
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    • 2003
  • Ageing characteristics of RTV coating materials by corona discharge have been studied. The hydrophobicity recovery of RTV coating materials with 300${\mu}{\textrm}{m}$ thickness was identical with a bulk silicone materials. The RTV coating materials hydrophobicity has been almost lost when its were discharged during 40 seconds by corona discharge of 10㎸, and recovered after about 45 hours. The resistivity of RTV coating materials has not been recovered after 45 hours, though after 80 hours the initiation resistivity value has been recovered up to 95%. There was no critical change of compounds(such as Si and Al) on RTV surfaces by the corona discharge treatment until 100 seconds. In the test of arc erosion, it was seen that the coating sample with silicone rubber as a base material have more longer burn-out time than other samples with FRP or glass base.

Sintering Properties of Hydroxyapatite Derived from Tuna Bone

  • Park, Jin-Sam;Huh, Jeung-Soo;Kim, Hyung-Sun
    • Journal of the Korean Ceramic Society
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    • v.37 no.12
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    • pp.1131-1134
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    • 2000
  • Hydroxyapatite (HA) ceramic was prepared using tuna bone powders and was characterized on properties of sintered samples. The aim was to prepare dense and bulk HA sintered suitable for clinical applications. Thermal analysis, X-ray diffraction analysis, microscopic observation, and mechanical evaluation were applied to characterize sintered HA to find optimum processing condition. The major phase of sintered HA was observed up to 1300$\^{C}$ and $\beta$-TCP was observed as temperature increased. The density of sintered HA was increased up to 1350$\^{C}$ and decreased with further increasing temperature. The flexural strength of sintered HA at 1350$\^{C}$ showed 58 MPa as the highest value in this work. The results suggest that the crystal phase and transformation characteristics of HA prepared from tuna bone are the same as the behavior of HA powders made by chemical synthesis.

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Oxygen Stoichiometry Modification by $O_2$-Plasma Treatment in $La_{0.7}Ca_{0.3}MnO_{3-\delta}$

  • Kim, H. S.;Lee, C. H.;Lee, Cheol-Eui;Y. H. Jeong;N. H. Hur
    • Journal of Magnetics
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    • v.5 no.3
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    • pp.99-101
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    • 2000
  • Oxygen-plasma effects of single crystal and thin film samples of $La_{0.7}Ca_{0.3}MnO_{3-\delta}$ have been studied. Our resistivity measurements indicate that oxygen plasma treatment gives rise to oxygen diffusion into bulk regions, which results in a decrease of $Mn^{3+}$ concentration in oxygen nonstoichiometric $La_{0.7}Ca_{0.3}MnO_{3-\delta}$ and in the activation energies of Holstein's small polarons in the paramagnetic region.

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