• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1994년도 Proceedings of the Korea Automatic Control Conference, 9th (KACC) ; Taejeon, Korea; 17-20 Oct. 1994
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• pp.207-212
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• 1994

A mathematical model is developed for a batch reactor in which the free radical bulk copolymerization of styrene and acrylonitrile takes place. In this model, we introduce the free volume theory to quantify the diffusion controlled termination and propagation reactions, and develop a model for the chain length dependent termination reaction in the context of the pseudo kinetic rate constant method(PKRCM). The simulation results from this model are found to be in good agreement with experimental data under different copolymerization conditions. The present model can predict both the copolymer composition and the number and weight average molecular weights. These kinetic approaches provide greater insight into the performance of the batch reactor used for the free radical bulk copolymerization of styrene and acrylonitirle.

• Journal of Information Display
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• 제10권4호
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• pp.143-148
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• 2009

The theoretical current density equations for organic semiconductors was derived according to the internal carrier emission equation based on the diffusion model at the Schottky barrier contact and the mobility equation based on the field dependence model, the so-called "Poole-Frenkel mobility model." The electric field becomes constant because of the absence of a space charge effect in the case of a higher injection barrier height and a lower sample thickness, but there is distribution in the electric field because of the space charge effect in the case of a lower injection barrier height and a higher sample thickness. The transition between the injection- and bulk-limited currents was presented according to the Schottky barrier height and the sample thickness change.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.831-832
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• 2006

Solid-state processing via the bulk mechanical alloying enables us to directly fabricate $Mg_2X$ semi-conductive material performs. Precise control of chemical composition leads to investigation on the dilution and enrichment of X in $Mg_2X$. Two types of solid-state reactivity are introduced: e.g. synthesis of $Mg_2Si$ from elemental mixture Mg-Si is nucleation-controlled process while synthesis of $Mg_2Sn$ from Mg-Sn, diffusion-controlled process. Thermoelectricity of these $Mg_2X$ is evaluated for discussion on the validity and effectiveness of this new PM route as a reliable tool for fabrication of thermoelectric compounds.

• 지질공학
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• 제3권2호
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• pp.203-214
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• 1993

액체 산업폐기물을 심층지하에 방출시, 폐기물의 이동은 지하매체의 낮은 투수율로 인하여 분자확산에 의해 좌우된다. 하편 확산에 의한 이동은 Fick의 제2법칙으로 예측할 수 있다. 본 연구에서는 실험을 통한 Cr(VI)의 확산 이동계수를 구하였다. 다공질내에서의 Cr(VI)이동을 추적하기 위해 방사성 동위원소인 $^{51}Cr$을 사용하였으며, Fick의 제2법칙에 대한 해석해를 구해 Cr(VI)의 확산계수를 결정하였다. 본 연구에서는 온도, $^{51}Cr$의 양, 염소 이온의 양, 매체의 건조밀도를 환경적 변화인자로 이용하였다.

• EDISON SW 활용 경진대회 논문집
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• 제3회(2014년)
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• pp.498-500
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• 2014

EDISON 나노물리 사이트에 탑재된 Drift-Diffusion 기반 bulk P/N Junction Diode 특성 해석용 SW를 이용해 P-N접합의 특성을 파악해보았다. n과 p영역에서의 순수 도너와 억셉터 농도를 통해 내부 전위 장벽을 구한다. 구한 내부 전위 장벽을 통해 공핍폭 W를 구할 수 있다. 이 논문에서는 일방접합의 공핍영역폭을 표현하는 식과 시뮬레이션을 통해 얻어진 공핍영역폭을 비교 분석하였다.

• Journal of Electrochemical Science and Technology
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• 제2권3호
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• pp.174-179
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• 2011

The mesoscopic $Sb_2S_3$-sensitized photoelectrochemical solar cells using cobalt redox electrolyte exhibit nonlinear behavior of power conversion efficiency with illuminated sun intensity. From the measurement of bulk diffusion and electrochemical impedance spectroscopy studies, we suggest that the nonlinearity of device performance with illuminated sun intensity is attributed not to the slow bulk diffusion problem of cobalt electrolyte but to the limited mass transport in narrowed pore volume in mesoscopic $TiO_2$ electrode.

• Computers and Concrete
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• 제16권6호
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• pp.865-880
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• 2015

Standard test method for bulk electrical conductivity (ASTM C1760) provides a rapid indication of the concrete's resistance to the penetration of chloride ions by diffusion. In this paper a new approach for assessing the bulk electrical conductivity of saturated specimens of hardened concrete is presented. The test involves saturating concrete specimens with a 5 M NaCl solution before measuring the conductivity of the samples. By saturating specimens with a highly conductive solution, they showed virtually the same pore solution conductivity. Different concrete samples yield different conductivity primarily due to differences in their pore structure. The feasibility of the method has been demonstrated by testing different concrete mixtures consisting ordinary and blended cement of silica fume (SF) and calcined perlite powder (CPP). Two standard test methods of RCPT (ASTM C1202) and Bulk Conductivity (ASTM C1760) were also applied to all of the samples. The results show that for concretes containing SF and CPP, the proposed method is less sensitive towards the variations in the pore solution conductivity in comparison with RCPT and Bulk Conductivity tests. It seems that this method is suitable for the assessment of the performance and durability of different concretes containing supplementary cementitious materials.

• 한국초전도ㆍ저온공학회논문지
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• 제22권1호
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• pp.1-6
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• 2020

This is a parameter study for the direct fabrication of a large grain YBCO bulk superconductors using Y₂O₃, BaCO₃ and CuO powders without any grinding step. The cracks, which have been formed due to volume contraction during calcination step, have been prevented by controlling the heating rate at 930~950 ℃. It has been observed that multi-grain growth has occurred due to the dissolution of Sm123 seed due to the retention of carbon in Ba-Cu-O melt. In order to accelerate the carbon release in prior calcination heat treatment, the reduction of pellet thickness and the drilling of artificial holes have been applied. Single-grain YBCO bulk superconductor has been successfully fabricated by stacking multiple thin slab. However, the crack formation has been rather prominent for the compact with artificial holes. The use of buffer pellet, which is supposed to act as diffusion barrier, has prevented the dissolution of Sm123 seed crystal and has led to the growth of single grain of high content of carbon containing specimen.

• 한국해양공학회지
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• 제11권2호
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• pp.39-47
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• 1997

Creep rate the elevated temperature is known to be controller by the softening process of microstructure especially in the solid solution alloys such as 125 Cr rotor steel. The change of structure is a decreasing process of the free energy of the state including stress, diffusivity of the material, and tmeperature. This study shows that diffusion coefficient, D of 12% Cr rotor steel at 953K with 74.8 MPa is 1.084~3.140*$10^{15}mm^2sec^1$ compared to $1.658*10^{24}mm^2sec^1$at 963K without stress. During creep, the growth of martensite laths accelerates the diffusion coefficient under stress due to incoherency of interface between carbides and matrix.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.1054-1056
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• 2002

High temperature Kermal diffusion from $POCl_3$ source usually used for conventional process through put of a cell manufacturing line and potentially reduce cell efficiency through bulk like time degradation. To fabricate high efficiency solar cells with minimal thermal processing, spin-on-doping(SOD) technique can be employed to emitter diffusion of a silicon solar cell. A technique is presented to emitter doping of a mono-crystalline solar cell using spin-on doping (SOD). Moreover it is shown that the sheet resistance variation with RTA temperature and time fer mono-crystalline and multi-crystalline silicon samples. This novel SOD technique was successfully used to produces 11.3% efficiency l04mm by 104mm size mono-crystalline silicon solar cells.