• Title/Summary/Keyword: Bulk Combustion

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Fabrication of $\textrm{ZrB}_2$ by SHS Process and Reaction-bonded $\textrm{ZrB}_2$-ZrC Composite (SHS법에 의한 $\textrm{ZrB}_2$ 합성과 반응소결된 $\textrm{ZrB}_2$-ZrC계 복합체의 제조)

  • Lee, Yun-Bok;Kim, Jeong-Seop;Kim, Sang-Bae;Park, Hong-Chae;O, Gi-Dong
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.8-13
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    • 1999
  • $ZrB _2$ was prepared from a mixture of $ZrO_2$, $B_2$$O_3$and Mg by SHS method. The combustion products were successfully obtained from a mixture of $Zro_2$:$B_2$$O_3$:Mg=1:2.0:8.5(molar ratio). MgO, by-product, was removed to 92.7% by leaching with 1M HCl solution at 9$0^{\circ}C$, for 10 hours. After leaching, the mean particle size of the resultant $ZrB_2$powders was 23.6$\mu\textrm{m}$. $ZrB_2$-ZrC composite was suitably obtained from a mixture of C/Zr=1.2 molar ratio by arc-melting method. The density of arc-melted specimen increased by adding excess zirconium content(x). The bulk density was 6.17g/㎤ for x=0, and 6.37g/㎤ x=4. Vickers hardness of arc-melted specimen was /$1290kg\textrm{mm}^2$ for x=0, and fracture toughness increased to 4.2MPa.m\ulcornerforx=4 compared to 3.4MPa.m\ulcornerfor x=0.

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Development of a Receptor Methodology for Quantitative Assessment of Ambient PM-10 Sources in Suwon Area (수원지역 대기 중 PM-10 오염원의 정량평가를 위한 수용방법론의 개발)

  • 김관수;황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.2
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    • pp.119-131
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    • 2001
  • A total of 328 ambient PM-10 samples was collected by a PM-10 high volume air sampler during the periods of February 1997 to February 1999 from Kyung Hee University at Suwon Campus. The samples were analyzed for their bulk chemical compositions(Cu, Fe, Pb, Zn, Al, $Na^{+}$, $NH_{4}^{+}$, $K^{+}$, $Ca^{2+]$, $Mg^{2+}$, $Cl^{-}$, $NO_{3}^{-}$, and $SO_{4}^{2-}$ by both an atomic absorption spectrophotometer and an ion chromatograph. The purpose of this study was t develop a receptor methodology for quantitative assessment of PM-10 sources. The data obtained from this study were ex-tensively examined using the target transformation factor analysis(TTFA) and the chemical mass balance (CMB). When TTFA was initially applied seasonal basis. five sources(such as automobile-related, sulfate-related, incine-ration, soil and combustion-related) were identified both during winter and fall. Since the total number and the type of sources were resolved by TTFA for the four seasons, CMB was employed to cross-check the results of TTEA. The total of six source categories identified by TTEA was intensively investigated on the basis of source profiles acquired from various source libraries established both in Korea and abroad. The results of this study showed the applicability of two popular receptor models as a new methdology for quantitative assessment PM-10 sources in Korea. Seasonally segmented data sets with the combined application of TTFA and CMB yielded a physically reasonable source apportionment result and provided a mean to increase the number of potential sources. Furthermore, this study suggested the possibility of the CMB application to ambi-ent data from Korea after identifying potential sources through traditional factor analysis.

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Detonation Initiation via Surface Chemical Reaction of Laser-Ablated Aluminum Sample (표면화학 반응을 통한 Laser-Ablated 알루미늄의 Detonation 현상 연구)

  • Kim, Chang-Hwan;Yoh, Jai-Ick
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.2
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    • pp.197-204
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    • 2012
  • We explore the evolution of metal plasma generated by high laser irradiances and its effect on the surrounding air by using shadowgraph images after laser pulse termination and X-ray diffraction (XRD) of aluminum plasma ablated by a high-power laser pulse (>1000 mJ/pulse) and oxygen from air. Hence, the formation of laser-supported detonation and combustion processes has been investigated. The essence of this paper is in observing the initiation of chemical reaction between the ablated aluminum plasma and oxygen from air by the high-power laser pulse (>1000 mJ/pulse) and in conducting a quantitative comparison of the chemically reactive laser-initiated waves with the classical detonation of an exploding aluminum (dust) cloud in air. The findings in this work may lead to a new method of initiating detonation from a metal sample in its bulk form without any need to mix nanoparticles with oxygen for initiation.

Effect of AC Electric Fields on Counterflow Diffusion Flame of Methane (메탄의 대향류 확산화염에 대한 AC 전기장의 영향)

  • Choi, Byung-Chul;Kim, Hyung-Kuk;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.8
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    • pp.849-855
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    • 2012
  • The effect of electric fields on the response of diffusion flames in a counterflow has been investigated experimentally by varying the AC voltage and frequency. The result showed that the flame was stationary with high AC frequency above the threshold frequency, and it increased with the applied voltage and then leveled off at 35 Hz. Below the threshold frequency, however, the flame oscillated with a frequency that was synchronized with the applied AC frequency. This oscillation can be attributed to the ionic wind effect due to the generation of bulk flow, which arises from the momentum transfer by molecular collisions between neutral molecules and ions, where the ions in the reaction zone were accelerated by the Lorentz force.

Study on Fabrication and Photoluminescent Properties of Fine Phosphor Film for Application of Radiation Image Sensor (방사선 영상센서 적용을 위한 미세 발광체 필름 제조 및 광학적 특성에 관한 연구)

  • Kang, Sang-Sik;Choi, Young-Zoon;Lee, Kwang-Oop;Moon, Yong-Soo;Kim, Mi-Young;Lee, Sang-Bong;Jung, Bong-Jae;Park, Ji-Koon
    • Journal of the Korean Society of Radiology
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    • v.4 no.4
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    • pp.25-28
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    • 2010
  • In this paper, the fabrication and feasibility study of clinical application with euripium doped gadollium oxide ($Gd_2O_3$:Eu) nano phosphor derived by low-temperature solution combustion method. From the fabricated phosphor, the photoluminescent characteristic and linearity as a function of phosphor film thickness were investigated to evaluate x-ray converstion properties. From the experimental results, the luminescent intensity was $2945pC/cm^2$-mR at $270{\mu}m$ $Gd_2O_3$:Eu film and this value is higher 1.2 time the conventional bulk phosphor, which is possible to imaging acquisition. And good linearity was shown at x-ray exposure range for clinical diagnostic application.

A Study on the Comparison of Injection Rate Measurement by the Bosch`s Method and the Zeuch`s Method (Bosch법과 Zeuch법에 의한 분사율 , 측정의 비교연구)

  • Ra, Jin-Hong;Kim, Jun-Hyo;An, Su-Gil
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.26 no.1
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    • pp.65-75
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    • 1990
  • There have been many methods for measuring the injection rate of diesel engines, but the results of them are not always identical and the reason for the discordance is not clear. Besides, a single shot injection equipment has been used for the fuel spray and the combustion research of diesel engines, but the results of experiment using the equipment don't apply to a volleyed shot injection of real engines. This paper investigates the merits and faults of the Bosch's method and the Zeuch's method, at the same, this paper also compares the injection rates of single shot inject rates of single shot injection and a volleyed shot injected by the Bosch's method. the results are summarized as follows: (1) The measurement error of the Bosch's method is about $\pm$1%, therefore, its accuracy is reliable. (2) By the Bosch's method, as the speed and the load of fuel pump increase, the injection rate becomes higher, on the contrary, the injection period(ms) shortens as the speed increases and the load decreases. (3) In this experiment, the injection rate of a single shot injection is lower than that of a volleyed shot injection under the same conditions. (4) The bulk modulus of elasticity using the Zeuch's method increases in proportion to the back pressure. (5) The Zeuch's method is less accurate than the Bosch's method.

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Assessment of Fire Risk Rating for Wood Species in Fire Event (화재 발생 시 목재 수종의 화재위험성 등급 평가)

  • Jin, Eui;Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.32 no.4
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    • pp.423-430
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    • 2021
  • In order to evaluate the fire risk and fire risk rating of wood for construction materials, this study focused on fire performance index-III (FPI-III), fire growth index-III (FGI-III), and fire risk index-IV (FRI-IV) according to Chung's equations-III and -IV. Western red cedar, needle fir, ash, and maple were used as the specimens. The fire characteristics were investigated using a cone calorimeter (ISO 5660-1) equipment on the specimen. The FPI-III measured after the combustion reaction was 0.86 to 12.77 based on polymethylmethacrylate (PMMA). The FGI-III was found to be 0.63 to 5.26 based on PMMA. The fire rating according to the FRI-IV, which is the fire rating index, was 0.05 to 6.12, and the western red cedar was 122.4 times higher than that of the maple. The fire risk rating according to the FRI-IV increased in the order of maple, ash, needle fir, PMMA and western red cedar. The CO peak concentration of all specimens was measured as 103 to 162 ppm, and it was 2.1 to 3.2 times higher than 50 ppm, the permissible exposure limits of the US occupational safety and health administration. Materials such as western red cedar, which have a low bulk density and contain a large amount of volatile organic substances, have a low FPI-III and a high FGI-III, so they have a high fire risk rating.

Rating Evaluation of Fire Risk for Combustible Materials in Case of Fire (화재 시 연소성 물질에 대한 화재 위험성 등급 평가)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.75-82
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    • 2021
  • This study investigated the fire risk assessment of woods and plastics for construction materials, focusing on the fire performance index-III (FPI-III), fire growth index-III (FGI-III), and fire risk index-IV (FRI-IV) by a newly designed method. Japanese cedar, red pine, polymethylmethacrylate (PMMA), and polyvinyl chloride (PVC) were used as test pieces. Fire characteristics of the materials were investigated using a cone calorimeter (ISO 5660-1) equipment. The fire performance index-III measured after the combustion reaction was found to be 1.0 to 15.0 with respect to PMMA. Fire risk by fire performance index-III increased in the order of PVC, red pine, Japanese cedar, and PMMA. The fire growth index-III was found to be 0.5 to 3.3 based on PMMA. Fire risk by fire growth index-III increased in the order of PVC, PMMA, red pine, and Japanese cedar. COpeak concentrations of all specimens were measured between 106 and 570 ppm. In conclusion, it is understood that Japanese cedar with a low bulk density and PMMA containing a large amount of volatile organic substances have a low fire performance index-III and high fire growth index-III, and thus have high fire risk due to fire. This was consistent with the fire risk index-IV.

Study of Oil Palm Biomass Resources (Part 5) - Torrefaction of Pellets Made from Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 V - 오일팜 바이오매스 펠릿의 반탄화 연구 -)

  • Lee, Ji-Young;Kim, Chul-Hwan;Sung, Yong Joo;Nam, Hye-Gyeong;Park, Hyeong-Hun;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Yim, Hyun-Tek;Lee, Min-Seok;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.34-45
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    • 2016
  • Global warming and climate change have been caused by combustion of fossil fuels. The greenhouse gases contributed to the rise of temperature between $0.6^{\circ}C$ and $0.9^{\circ}C$ over the past century. Presently, fossil fuels account for about 88% of the commercial energy sources used. In developing countries, fossil fuels are a very attractive energy source because they are available and relatively inexpensive. The environmental problems with fossil fuels have been aggravating stress from already existing factors including acid deposition, urban air pollution, and climate change. In order to control greenhouse gas emissions, particularly CO2, fossil fuels must be replaced by eco-friendly fuels such as biomass. The use of renewable energy sources is becoming increasingly necessary. The biomass resources are the most common form of renewable energy. The conversion of biomass into energy can be achieved in a number of ways. The most common form of converted biomass is pellet fuels as biofuels made from compressed organic matter or biomass. Pellets from lignocellulosic biomass has compared to conventional fuels with a relatively low bulk and energy density and a low degree of homogeneity. Thermal pretreatment technology like torrefaction is applied to improve fuel efficiency of lignocellulosic biomass, i.e., less moisture and oxygen in the product, preferrable grinding properties, storage properties, etc.. During torrefacton, lignocelluosic biomass such as palm kernell shell (PKS) and empty fruit bunch (EFB) was roasted under an oxygen-depleted enviroment at temperature between 200 and $300^{\circ}C$. Low degree of thermal treatment led to the removal of moisture and low molecular volatile matters with low O/C and H/C elemental ratios. The mechanical characteristics of torrefied biomass have also been altered to a brittle and partly hydrophobic materials. Unfortunately, it was much harder to form pellets from torrefied PKS and EFB due to thermal degradation of lignin as a natural binder during torrefaction compared to non-torrefied ones. For easy pelletization of biomass with torrefaction, pellets from PKS and EFB were manufactured before torrefaction, and thereafter they were torrefied at different temperature. Even after torrefaction of pellets from PKS and EFB, their appearance was well preserved with better fuel efficiency than non-torrefied ones. The physical properties of the torrefied pellets largely depended on the torrefaction condition such as reaction time and reaction temperature. Temperature over $250^{\circ}C$ during torrefaction gave a significant impact on the fuel properties of the pellets. In particular, torrefied EFB pellets displayed much faster development of the fuel properties than did torrefied PKS pellets. During torrefaction, extensive carbonization with the increase of fixed carbons, the behavior of thermal degradation of torrefied biomass became significantly different according to the increase of torrefaction temperature. In conclusion, pelletization of PKS and EFB before torrefaction made it much easier to proceed with torrefaction of pellets from PKS and EFB, leading to excellent eco-friendly fuels.

Effects of the Fractionated Raw Cow Manure on Mobility of NO3--N in A Double-Layered Soil Column with Constant Water Head (상존수두상태의 이중토양토주에서 질산태질소 이동에 대한 분쇄우분의 효과)

  • Chung, Doug-Young;Lee, K.S.;Baek, M.J.
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.1
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    • pp.26-32
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    • 2001
  • Influence of various rates of fractionated raw cow manure on hydraulic conductivity of the soil was observed. The fractionated raw cow manure(hereafter as FRCM) incorporated into soil. The hydraulic conductivity was measured for the double-layered soil while maintaining the water head by 5 cm over the soil surface. The influence on the mobility of $NO_3{^-}$-N transformed from the FRCM was analyzed. The upper layers (Wolgok series) were made with FRCM ranging from 0% to 10.4 % on weight basis for air-dried soil while the organic matter in the bottom layers (Chungwon series) was removed by combustion. The initial bulk densities for both layers were adjusted to $1.25g\;cm^{-3}$. In this experiment the $K_{sat}$ for the upper layer gradually decreased from $4.71{\times}10^{-3}cm\;min^{-1}$ to $1.2{\times}10^{-3}cm\;min^{-1}$ with increasing the rate of the FRCM from 0 % to 10.4%, while the Ksat of the bottom layer was maintained as $3.7cm\;min^{-1}$. For the double-layered soil columns, the $K_{sat}$ decreased with increasing rate of FRCM at the upper layer from $1.7{\times}10^{-3}cm\;min^{-1}$ to $8{\times}10^{-4}cm\;min^{-1}$ as the rate of organic matter increased from 0 % to 10.4 %, while it took almost 7 days to 64 days to obtain the steady state $K_{sat}$ The elution patterns of $NO_3{^-}$-N and $NH_4{^+}$-N showed that the amounts of both $NO_3{^-}$-N and $NH_4{^+}$-N rapidly approached to the maximum ranging from $14.8mmol_c\;kg^{-1}$ to $0.58mmol_c\;kg^{-1}$ as the rate of FRCM decreased from 10.7 % to 0 % which is equivalent to indigenous amount of $NO_3{^-}$-N and $NH_4{^+}$-N. And the amounts of $NO_3{^-}$-N were approximately three or four time than those of $NH_4{^+}$-N, indicating that the transformation rate of $NO_3{^-}$-N was improved by the higher FRCM rate. Thus, the ability of a soil to supply N can be predicted from its mineralization parameters and leaching potentials influenced by water flow regime in soil.

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