• Bulletin of the Korean Chemical Society
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• 제20권8호
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• pp.869-874
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• 1999

In this paper, electrochemical techniques are used to investigate hydrothermal-electrochemically formation of barium titanate (BT) ceramic films. For comparison, the electrochemical behaviors of anodic titanium oxide films formed in alkaline solution were also investigated both at room temperature and in hydrothermal condition at 150.0 ℃. Film structure and morphology were identified by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Titanium oxide films produced at different potentials exhibit different film morphology. The breakdown of titanium oxide films anodic growth on Ti electrode plays an important roles in the formation of BT films. BT films can grow on anodic oxide/metal substrate interface by short-circuit path, and the dissolution-precipitation processes on the ceramic film/solution interface control the film structure and morphology. Based upon the current experimental results and our previous work, extensively schematic proce-dures are proposed to model the mechanism of ceramic film formation by hydrothermal-electrochemical method.

• Bulletin of the Korean Chemical Society
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• 제15권11호
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• pp.985-990
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• 1994

Cross-interaction constants, ${\rho}^e_{XY}$, ${\rho}_{YZ}$ and ${\rho}_{XZ}$ are defined using observed rate constant, k_N=(k_1/k_{-1})k_2=Kk_2$, for the stepwise carbonyl addition reactions involving the rate-limiting breakdown of a tetrahedral intermediate $(T^{\pm})$. Abundant experimental evidence in the literature enables us to determine signs for the three constants for such mechanism, ${\rho}^e_{XY}$>0, ${\rho}_{YZ}$<0 and ${\rho}_{XZ}$0. These are in contrast to those for the concerted $S_N2$ mechanism, ${\rho}_{XY}$<0, ${\rho}_{YZ}$>0 and ${\rho}_{XZ}$, and provide useful mechanistic criteria. In the light of these criteria, mechanisms of some nucleophilic reactions of carbonyl compounds are re-examined.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.53-58
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• 2002

Electrical insulation and mechanical properties of the plasma sprayed oxide ceramic coatings were studied before and after the sealing treatment of the ceramic coatings. Plasma sprayed A1$_2$O$_3$-TiO$_2$ coating as the reference coating was sealed using three commercial sealants based on polymer. Penetration depth of the sealants to the ceramic coating was evaluated directly from the optical microscope using a fluorescent dye. It is estimated that the penetration depth of the sealants to the ceramic coating is from 0.2 to 0.5 mm depending on the sealants used. The preliminary test results with a DC puncture tester imply that the dielectric breakdown voltage mechanism of plasma sprayed ceramic coatings has been determined to be a corona mechanism. Dielectric breakdown voltage of the as-sprayed and as-ground samples have shown a linear trend with regard to the thickness showing an average dielectric strength of 20 kV/mm for the thickness scale studied. It is also shown that grinding the coating before sealing and adding fluorescent dye do not agent the penetration depth of sealants. All of the microhardness, two-body abrasive wear resistance, bond strength, and surface roughness of the ceramic coating after the sealing treatment are improved. The extent of improvement is different from the sealants used. However, three-point bending stress of the ceramic coating after the sealing treatment is decreased. This is attributed to the reduced micro-crack toughening effect since the cracks propagate easily through the lamellar of the coating without crack deflection and/or branching after the sealing treatment.

• 조명전기설비학회논문지
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• 제14권1호
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• pp.22-29
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• 2000

본 논문은 가스절연개폐장치내에 바늘모양의 금속입자가 존재하는 경우 $\pm1.2/44[{\mu}s]$ 비진동성 임펄스와 $\pm0.4[{\mu}s]/1.14[MHz]$ 진동성 임펄스전압이 인가되었을 때 $SF_6$가스의 절연특성에 관한 것으로 절연파괴전압-시간 특성 (V-t 특성) 및 절연파괴전압-압력 특성(V-p 특성)을 측정하고 검토하였다. 실험은 길이 10[mml, 반경 0.5[mm]인 바늘모양의 돌기물에 의해 형성된 불평등 전계이며, 가스압력이 0.1~0.5[MPa]인 범위에서 수행하였다. 그 결과 절연 파괴는 정.부극성 모두 계단상 펄스에 의해 진전하는 리더메커니즘으로 발생하였다. 정극성의 진동성 임펼스전압이 인가되었을 때 절연파괴전압이 가장 낮았으며, 짧은 시간범위에서 V-t곡선의 감쇠가 현저하고 가스압력의 의존성이 적게 나타났다. 이에 반해 부극성의 경우 V-t 특성과 V-p 특성은 인가전압의 파형에 대한 의존성이 현저하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 하계학술대회 논문집 C
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• pp.1808-1810
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• 2004

This paper describes the discharge characteristics of liquid $SF_6$ (-41$[^{\circ}]$, 1.7[atm]) and $LN_2$ for plane to plane, needle to plane, plane to needle and sphere to plane electrode with gap variations from 1[mm] to 12[mm]. From this result, the breakdown voltage was increased with increasing gap length. Especially, the formation of bubbles by evaporation was observed in spite of non-applying voltage source. A corona is created of the applying voltage from the bubbles on the electrodes applied voltage. We consider it equal mechanism of corona as void exists in solid insulator. The results of liquid $SF_6$ and $LN_2$ discharge characteristics were caused by bubble formed evaporation and applied electric field voltage. Corona was happened to weak bubble and was proceed to new bubble breakdown.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권2호
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• pp.69-75
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• 2005

In order to improve the reliability of high voltage rotating machines and mold transformers, it is necessary to understand the breakdown mechanism and life assessment of the high voltage winding parts. Especially the on-line PD test provides the ability to monitor effects, such as slot discharge, internal discharge, and end-winding discharge without interrupting the electrical machines, this method has been proven the major testing technology. Capacitive couplers have been the most widely used sensors for the on-line partial discharge detection in rotating machines nowadays. This paper deals with the electrical characteristics and long-term reliability of a ceramic coupler(CC), which can be easily mounted into high voltage input terminal part, has been developed and tested to continuously measure PD activity during operating condition. This paper presents electrical characteristics (dielectric loss angle, capacitance, PD inception level, breakdown voltage, and frequency response bandwidth) and long-term life test result of the developed 6.6 kV class on-line ceramic coupling sensor. It was found that this sensor had good electrical characteristics to detect PD activity during the operating condition with its detection frequency band is between several and several tens MHz. Also, the voltage life of the 6.6kV class ceramic coupler was calculated over 60 years.

• E2M - 전기 전자와 첨단 소재
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• 제7권2호
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• pp.145-151
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• 1994

The multi-dielectric layer SiOz/Si3N4/SiO2(ONO) is used to scale down the memory device. In this paper, the change of composition in ONO layer due to the process condition and the conduction mechanism are observed. The composition of the oxide film grown through the oxidation of nitride film is analyzed using auger electron spectroscopy(AES). AES results show that oxygen concentration increases at the interface between oxide and nitride layers as the thickness -of the top oxide layer increases. Results of I-V measurement show that the insulating properties improve as the thickness of the top oxide layer increases. But when the thickness of the nitride layer decreases below 63.angs, insulating peoperties of film 28.angs. of top oxide and film 35.angs. turn over showing that insulating property of film 28.angs. of top oxide is better than that of film 35.angs. of top oxide. This phenomenon of turn over is thought as the result of generation of surface state due to oxygen flow into nitride during oxidation process. As the thickness of the top oxide and nitride increases, the electrical breakdown field increases, but when the thickness of top oxide reaches 35.angs, the same phenomenon of turn over occurs. Optimum film thickness for scaled multi-layer dielectric of memory device SONOS is estimated to be 63.angs. of nitride layer and 28.angs. of top oxide layer. In this case, maximum electrical breakdown field and leakage current are 18.5[MV/cm] and $8{\times}{10^-12}$[A], respectively.

• BMB Reports
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• 제48권8호
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• pp.467-472
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• 2015

Heat shock increases skin temperature during sun exposure and some evidence indicates that it may be involved in skin aging. The antioxidant response mediated by the transcription factor NF-E2-related factor 2 (Nrf2) is a critically important cellular defense mechanism that serves to limit skin aging. We investigated the effects of heat shock on collagenase expression when the antioxidant defense system was downregulated by knockdown of Nrf2. GSH and collagenases were analyzed, and the expression of inducible Nrf2, HO-1, and NQO1 was measured. HS68 cells were transfected with small interfering RNA against Nrf2. Heat shock induced the downregulation of Nrf2 in both the cytosol and nucleus and reduced the expression of HO-1, GSH, and NQO1. In addition, heat-exposed Nrf2-knockdown cells showed significantly increased levels of collagenase protein and decreased levels of procollagen. Our data suggest that Nrf2 plays an important role in protection against heat shock-induced collagen breakdown in skin. [BMB Reports 2015; 48(8): 467-472]

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권5호
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• pp.204-212
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• 2002

In order to improve the reliability of high voltage rotating machines, it is necessary to understand the breakdown mechanism of stator windings. Especially partial discharge(PD) inception and growth are important in stator winding insulation. Recently, many research on the diagnosis of stator winding insulation for large rotating machines have been developed since the 1970s. Capacitive couplers have been the most widely used sensor for on-line partial discharge detection in rotating machines. This paper deals with the electrical on-line monitor characteristics of ceramic coupler(CC) which has been developed to continuously measure the PD activity in operating high voltage motor stator windings on site. We investigated the electrical characteristics(PD quantity, breakdown voltage and frequency response) to develop CC. This paper presents frequency characteristics and laboratory test result to compare conventional 80([F] epoxy-mica coupler(EMC) and 105[pF] CC for PD measurement with 6.6㎸ model stator windings.

• 조명전기설비학회논문지
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• 제12권1호
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• pp.3-11
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• 1998

스페이서 표면 파티클에 의한 오염의 영향은 SF6GIS의 절연내력을 현저히 감소시킨다. 이와 관련해서 우리는 평행평판전극 구성으로 SF6가스중에서 금속 및 비금속 파티클의 위치 및 형태를 변화시키면서 교류전압에서 섬락전압 특성과 파괴 기구에 대해서 연구했다. 주된 결과는 $\circled1$파티클 위치에 대한 섬락전압 감소의 영향은 갭중간에서 가장 적고 전극에서 미소간극 분리된 경우의 영향이 가장 커다. $\circled2$ 섬락전압 감소가 크게 되는 금속 파티클 일수록 FOV 포화 현상은 낮은 압력 영역으로 이동된다. $\circled3$0.6[mm]이하의 비금속 파타클은 섬락전압에 그의 영향을 미치지 않는다.