• Title/Summary/Keyword: Br

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Study of Inorganic CsPbI2Br Perovskite Solar Cell Using Hot-air Process (Hot-air 공정을 이용한 무기 CsPbl2Br 페로브스카이트 태양전진 제작 연구)

  • RINA, KIM;Dong-Gun, Lee;Dong-Won, Kang;Eundo, Kim;Jeha, Kim
    • Current Photovoltaic Research
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    • v.10 no.4
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    • pp.101-106
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    • 2022
  • We prepared a CsPbI2Br solution using Cesium iodide (CsI), Lead (II) bromide (PbBr2) and Lead (II) iodide (PbI2) materials into a polar solvent mixture of N,N-dimethylformamide (DMF) and Dimethyl sulfoxide (DMSO). A simple spin coating technique was used for the fabrication of CsPbI2Br absorber layer in the solution process. In order to prepare uniform coating of absorber film we adopted a hot-air process in assocation with the spin coating. It was confirmed that the thin film manufactured by the hot-air process had a higher absorption rate than that without it, and the optical band gap was measured 1.93 eV. The thin film of absorber was uniformly prepared and revealed the Black α-Cubic crystal phase as proved through X-ray diffraction analysis. Finally, a perovskite solar cell having an n-i-p structure was manufactured with a CsPbI2Br perovskite absorption layer. From the solar cell, we obtained a power conversion efficiency (PCE) of 5.97% in a forward measurement.

Study on self-diffusion transport phenomena during mercurous bromide (Hg2Br2) vapor processes (브로민화수은(I)(Hg2Br2) 증착공정에서 자체확산 연구)

  • Nam Il Kim;Geug Tae Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.2
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    • pp.48-54
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    • 2024
  • During the Hg2Br2 physical vapor transport process with self-diffusion, it is concluded that for 10-3g0≤ g ≤ 1g0 the thermal buoyancy driven convection is dominant in the vapor phase; at the gravitational level of g = 10-4g0, the transition region from the convection to diffusion occurs; for 10-6g0 ≤ g ≤ 10-5g0, the diffusion mode is predominant. The total molar flux of Hg2Br2 decays exponentially with the decreasing of one tenth of gravitational magnitude. For 10℃ ≤ ΔT ≤ 50℃, the total molar flux increases linearly and directly with the temperature difference between the source and crystal regions.

Coat Color Patterns and Genotypes of Extension and Agouti in Hanwoo and Jeju Black Cattle (제주흑우와 한우에서 Extension, Agouti 유전자형과 모색 출현 양상)

  • Han, Sang-Hyun;Cho, In-Cheol;Kim, Jae-Hwan;Ko, Moon-Suck;Kim, Young-Hoon;Kim, Eun-Young;Park, Se-Pill;Lee, Sung-Soo
    • Journal of Life Science
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    • v.21 no.4
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    • pp.494-501
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    • 2011
  • To understand the relationship between coat color inheritance patterns and genotypes of Extension (E) and Agouti (A) loci in cattle, the genotypes for melanocortin-1 receptor (MC1R) and agouti signaling protein (ASIP) were analyzed in Hanwoo, Jeju black cattle (JBC), and their crossbred progeny. Three MC1R alleles ($E^D$, $E^+$, and e) were found in the black-colored JBC population. JBC had no recessive homozygotes (e/e), but this genotype was predominant in the Hanwoo breed. However, MC1R $E^+$/e Hanwoo did not produce a black coat color as they appeared either as brown or solid red. For ASIP, three genotypes (A/A, A/$A^{Br}$, and $A^{Br}/A^{Br}$) were determined by insertion/deletion of an L1-BT element in Hanwoo. The ASIP $A^{Br}$ allele was rarely observed, and no ASIP $A^{Br}/A^{Br}$ homozygotes were detected in the JBC population. Cattle carrying ASIP $A^{Br}$ did not show any agouti-like brindle pigmentation patterns in either breed or their progeny. The coat colors of the crossbred progeny were discriminated by two colors, yellowish-brown versus dark-brown or black, and their coat colors were directly related to the genotypes of the Extension locus, yellowish-brown (e/e) and dark-brown or black ($E^+$/e), but not to the Agouti locus. ASIP genotypes probably did not affect coat color development in the Hanwoo or crossbred progeny. Our results suggest that the ASIP genotypes do not play key roles in coat color variation, but the MC1R genotypes do direct the phenotypes of Hanwoo, JBC, and their progeny.

Comparative and Feasibility Evaluation of Detection Ability of Relative Dosimeters using CsPbI2Br and CsPbIBr2 Materials in Brachytherapy QA (근접방사선치료 QA에서 CsPbI2Br과 CsPbIBr2를 이용한 상대 선량계들의 검출 능력 비교 및 적용가능성 평가)

  • Seung-Woo Yang;Sung-Kwang Park
    • Journal of the Korean Society of Radiology
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    • v.17 no.3
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    • pp.433-440
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    • 2023
  • High dose rate brachytherapy is a cancer treatment that intensively irradiates radiation to tumors by inserting isotopes with high dose rates into the body. For such a treatment, it is necessary to deliver an accurate dose to the tumor tissue through an accurate treatment plan while delivering only a minimum dose to the normal tissue. Therefore, it is very important to check the location accuracy of the source through accurate Quality Assurance (QA) in clinical practice. However, since the source position is determined using a ruler, automatic radiographer, video monitor, etc. in clinical practice, it yields inaccurate results. In this study, a semiconductor dosimeter using CsPbI2Br and CsPbIBr2 was fabricated. And, in order to analyze whether it is more suitable for the relative QA dosimeter for brachytherapy device among the two materials, the radiation detection ability of each was compared and evaluated. In order to evaluate the radiation detection ability in brachytherapy, the reproducibility and linearity of the two materials were evaluated in 192IR. In the reproducibility evaluation, CsPbI2Br presented a Relative Standard Deviatio(RSD) of 0.98% and CsPbIBr2 presented an RSD of 3.45%. In the linearity evaluation, the coefficient of determination (R2) of CsPbI2Br was presented as 0.9998, and the R2 of CsPbIBr2 was presented as 0.9994. As a result of the evaluation, it was found that CsPbI2Br was more stable in radiation detection while satisfying the evaluation criteria in the dosimeter manufactured in this experiment. Therefore, CsPbI2Br material is suitable for application as a relative dosimeter for radiation detection in brachytherapy devices.

Analysis of Selenium in Grain with ORC Collision-Removal of Br Interference using Mathematical Calibration (ORC ICPMS에서의 곡류중의 셀레늄 분석-수학적 보정을 이용한 Br의 간섭제거)

  • Cho, Heon-Hong;Pak, Yong-Nam
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.472-477
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    • 2011
  • The concentration of selenium in grain samples was determined using isotope dilution method in ORC-ICPMS. The experimental conditions were optimized to $H_2$ mode and the flow rate was $4.0\;mL\;min^{-1}$. ORC in $H_2$ mode proved to eliminate most of polyatomic interferences except $BrH^+$ when Br is present in sample matrix. Chemical removal of Br was very difficult and the mathematical correction was successfully employed. The fraction of $BrH^+$ generated from Br at the current experimental condition was 14.1%. The signal on m/z 82 was corrected and calculated for isotope dilution. The analytical reliability of the propose method was successfully evaluated by analyzing the certified standard reference material NIST SRM 1566 and 1567. The method was applied to real samples and the results are $0.034{\pm}0.001\;{\mu}g\;g^{-1}$ for white rice, $0.059{\pm}0.002_5\;{\mu}g\;g^{-1}$ for brown rice, $0.029{\pm}0.001_4\;{\mu}g\;g^{-1}$ for black rice, and $0.034{\pm}0.002\;{\mu}g \;g^{-1}$ for barley. The detection limits ($3\sigma$) for Se was $0.012\;ng\;g^{-1}$.

Optical Characterizations of TlBr Single Crystals for Radiation Detection Applications

  • Oh, Joon-Ho;Kim, Dong Jin;Kim, Han Soo;Lee, Seung Hee;Ha, Jang Ho
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.167-171
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    • 2016
  • Background: TlBr is of considerable technological importance for radiation detection applications where detecting high-energy photons such as X-rays and ${\gamma}$-rays are of prime importance. However, there were few reports on investigating optical properties of TlBr itself for deeper understandings of this material and for making better radiation detection devices. Thus, in this paper, we report on the optical characterizations of TlBr single crystals. Spectroscopic ellipsometry (SE) and photoluminescence (PL) measurements at RT were performed for this work. Materials and Methods: A 2-inch TlBr single crystalline ingot was grown by using the vertical Bridgman furnace. SE measurements were performed at RT within the photon energy range from 1.1 to 6.5 eV. PL measurements were performed at RT by using a home-made PL system equipped with a 266 nm-laser and a spectrometer. Results and Discussion: Dielectric responses from SE analysis were shown to be slightly different among the different samples possibly due to the different structural/optical properties. Also from the PL measurements, it was observed that the peak intensities of the middle samples were significantly higher than those of the other two samples. With the given values for permittivity of free space (${\varepsilon}_0=8.854{\times}10^{-12}F{\cdot}m^{-1}$), thickness (d = 1 mm), and area ($A=10{\times}10mm^2$) of the TlBr sample, capacitances of TlBr were 6.9 pF (at $h{\nu}=3eV$) and 4.4 pF (at $h{\nu}=6eV$), respectively. Conclusion: SE and PL measurement and analysis were performed to characterize TlBr samples from the optical perspective. It was observed that dielectric responses of different TlBr samples were slightly different due to the different material properties. PL measurements showed that the middle sample exhibited much stronger PL emission peaks due to the better material quality. From the SE analysis, optical, dielectric constants were extracted, and calculated capacitances were in the few pF range.

An Experimental Study on the Effect of Low Fin Tube Geometry on Pool Boiling of a LiBr Solution (낮은 핀관의 형상이 LiBr 수용액의 풀 비등에 미치는 영향에 대한 실험적 연구)

  • Kim, Nae-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.7
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    • pp.591-598
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    • 2015
  • Pool boiling heat transfer coefficients of a LiBr solution were obtained for seven low fin tubes having different fin pitch and fin height. The test range covered saturation pressure from 7.38kPa to 101.3kPa, heat flux from $20kW/m^2$ to $40 kW/m^2$ and LiBr concentration from 0% to 50%. The optimum fin geometry for the present experimental range turned out to be 26 fpi with 0.18 mm fin height.The advantage of added heat transfer area and the disadvantage of slower bubble growth and departure appear to have yielded an optimum fin pitch. The heat transfer coefficient decreased as saturation pressure decreased and Libr concentration increased. The reason may be attributed to the low saturation pressure, which increased the bubble departure diameter and decreased the bubble departure frequency. As the LiBr concenreation increased, the saturation temperature increased and the mass diffusion rate decreased, which resulted in a reduced heat transfer coefficient. The heat transfer coefficients of the low fin tube were greater than those of the smooth tube. Correlations were developed based on the present data.

Study on the Possibility of Seawater Intrusion in the Ulsan Area Using Br : Cl Weight Ratios of Groundwater (지하수의 Br : Cl 함량비를 이용한 울산지역 해수침입 연구)

  • Cho, Byung-Wook;Lee, Byung-Dae;Yoon, Wook;Im, Hyun-Chul
    • Economic and Environmental Geology
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    • v.36 no.5
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    • pp.339-347
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    • 2003
  • Using 171 groundwater chemistry data, seawater intrusion in the Ulsan area was studied. The area near the downstream area of the Taehwa River shows the higher Cl concentrations(11,300 mg/L in maximum), whereas the Cl concentrations are generally low in the eastern coastal area maybe due to the geology of the area. When Cl concentrations are very low, groundwater shows Br:Cl weight ratios significantly deviating from the Br:Cl ratio of seawater($34.7{\times}10^{-4}$). However, Br:Cl ratios are very close to the value of seawater when Cl concentrations are higher than 100 mg/L. Eleven groundwater samples having very high Cl concentrations(>500 mg/L) show that ionic ratios for Ca, Mg, $SO_4$, $HCO_3$ and $SiO_2$ are considerably different from those of seawater. This indicates that the origin of the high Cl groundwaters occurring along the Taehwa River are likely to be the residual salines from the salterns previously located on the alluviums rather than the seawaters intruded recently. These waters seem to be accumulated in the sediments before the drastic expansion of the city. Considering the characteristics of the urban groundwater system where the inflow exceeds the outflow, it is anticipated that the high Cl concentration in the groundwater show a decreasing trend in the future.

Evaluation of energy and amino acids of brown rice and its effects on laying performance and egg quality of layers

  • An, Byoung-Ki;An, Su Hyun;Jeong, Han-Seul;Kim, Kwan-Eung;Kim, Eun Jip;Lee, Sang-Rak;Kong, Changsu
    • Journal of Animal Science and Technology
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    • v.62 no.3
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    • pp.374-384
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    • 2020
  • Two experiments were conducted to determine apparent metabolizable energy (AME), nitrogen-corrected AME (AMEn), and ileal digestible amino acid (AA) content of brown rice (BR) and to investigate the effect of dietary supplementation of BR on laying performance and egg quality of laying hens. In Exp. 1, 72 Hy-line Brown layers (49-week-old) were allocated to two treatments using a completely randomized block design, and each treatment included six cages per treatment and six hens per cage. A semi-purified diet was formulated to include BR as the sole source of AA and energy and an N-free diet was used to determine basal endogenous loss of AA. The hens were fed a commercial layer diet for adaptation to the experimental environment and diet for 7 days from d 0, and then fed experimental diets for 5 days from d 7. Excreta were collected from d 10 to 11 and ileal digesta were collected on d 12. On a dry matter (DM) basis, the AME and AMEn of BR was determined at 3,773 and 3,729 kcal/kg, respectively. The apparent ileal digestibility (AID) of BR ranged from 32.7% for Thr to 73.7% for Arg. The range of the standardized ileal digestibility (SID) value was between 79.4% for Met and 96.6% for Lys. In Exp. 2, 252 Hy-line Brown layers (44-week-old) were divided into four groups, comprising seven replicates of nine birds each and assigned to four experimental diets containing 0 (Control), 5%, 10%, or 15% BR for 5 weeks. The BR-containing diets were formulated to be equal in the content of AMEn and digestible AA to those of the diet without BR. No significant differences were observed in laying performances. Egg quality and blood profiles were not linearly or quadratically affected by dietary treatments. These results suggest that up to 15% BR can be included into layer feed without any adverse effects on laying performance and egg quality, if its energy and digestible AA values are well evaluated.

Physicochemical Properties of Oxidized Rice Flour and Effects of Added Oxidized Rice Flour on the Textural Properties of Julpyun(Korean traditional rice cake) during Storage (TEMPO를 이용하여 산화시킨 쌀가루의 이화학적 특성 및 산화 쌀가루를 첨가한 절편의 저장 중 텍스처 특성)

  • Kim, Moon-Soo;Suh, Dong-Soon;Chang, Pahn-Shick;Kim, Kwang-Ok
    • Korean Journal of Food Science and Technology
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    • v.33 no.2
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    • pp.209-215
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    • 2001
  • This study was conducted to examine the effects of 2,2,6,6-tetramethyl-1-piperidine oxoammonium ion(TEMPO) and sodium bromide(NaBr) for the selective oxidation on primary alcohol groups of rice starch molecules in rice flour and to use oxidized rice flour in Julpyun to extend its shelf life. Reaction time decreased with higher levels of TEMPO and NaBr. Yield and selectivity decreased with increased NaBr levels. TEMPO increased yield until certain levels, but decreased thereafter. The levels of TEMPO and NaBr for the preparation of oxidized rice flour were determined as 0.9 and 44 mM/100 mM anhydroglucose unit, respectively. Water and oil binding capacities, and viscosity increased significantly by the oxidation of rice flour. The partial replacement of rice flour with oxidized rice flour increased peak viscosity and decreased setback. Oxidized rice flour with the increased amount of water showed positive effect on the textural properties of Julpyun during storage.

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