• 제목/요약/키워드: Boron free

검색결과 66건 처리시간 0.024초

Nuclear Design Characteristics of SMART

  • Lee, Chungchan;Park, Sang-Yoon;Lee, Ki-Bog;Zee, Sung-Quun;Chang, Moon-Hee
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(1)
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    • pp.19-26
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    • 1998
  • Nuclear design bases for System-Integrated Modular Advanced ReacTor(SMART) core are presented. Based on the proposed design bases, a SMART core loading pattern is constructed and its nuclear characteristics are studied. The proposed core loading pattern satisfies 3-year cycle length and soluble boron-free operation requirements at any time during the cycle

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필러 네트워크 형성 및 배향이 복합소재 열전도도와 산소투과도에 미치는 영향 고찰 (Impact of Filler Aspect Ratio on Oxygen Transmission and Thermal Conductivity using Hexagonal Boron Nitride-Polymer Composites)

  • 신하은;김채빈
    • Composites Research
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    • 제34권1호
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    • pp.63-69
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    • 2021
  • 일체형 방열 및 기체 차단 재료 개발을 위하여 신규 고분자를 합성하고 판상형 육방정 질화 붕소(hBN) 필러를 포함하는 복합소재를 제조하였다. 복합소재는 필러의 크기 및 함량에 따라 열전도도 및 산소투과도 조절이 가능하였다. 복합소재는 최대 28.0 W·m-1·K-1의 높은 열전도도를 지녔으며 필러 미포함 샘플 대비 산소투과도는 62% 감소하였다. 열전도도 및 기체투과도 실험 측정값과 모델 예측값 비교를 통해 복합소재 내 필러의 종횡비를 계산하였다. 이러한 결과를 토대로 높은 열전도도 및 낮은 기체투과도는 필러 간 효과적인 네트워크 형성 때문이며 이는 복합소재 제조 시 전단 응력 극대화가 가능한 신규 수지의 특성으로부터 유래된것으로 사료된다. 또한, 열전도도로부터 계산된 필러 종횡비와 산소 투과도로부터 계산된 필러 종횡비 값이 서로 다름을 확인하였고 이에 관련하여 복합소재에서 열 전달 및 기체 투과 메커니즘에 대하여 고찰하였다. 본 연구에서 개발된 높은 열전도도 및 낮은 산소투과도를 갖는 고분자 복합소재는 전자 제품의 일체형 방열 및 산화 방지 재료로 사용 될 수 있다.

Buckling and vibration analyses of MGSGT double-bonded micro composite sandwich SSDT plates reinforced by CNTs and BNNTs with isotropic foam & flexible transversely orthotropic cores

  • Mohammadimehr, M.;Nejad, E. Shabani;Mehrabi, M.
    • Structural Engineering and Mechanics
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    • 제65권4호
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    • pp.491-504
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    • 2018
  • Because of sandwich structures with low weight and high stiffness have much usage in various industries such as civil and aerospace engineering, in this article, buckling and free vibration analyses of coupled micro composite sandwich plates are investigated based on sinusoidal shear deformation (SSDT) and most general strain gradient theories (MGSGT). It is assumed that the sandwich structure rested on an orthotropic elastic foundation and make of four composite face sheets with temperature-dependent material properties that they reinforced by carbon and boron nitride nanotubes and two flexible transversely orthotropic cores. Mathematical formulation is presented using Hamilton's principle and governing equations of motions are derived based on energy approach and applying variation method for simply supported edges under electro-magneto-thermo-mechanical, axial buckling and pre-stresses loadings. In order to predict the effects of various parameters such as material length scale parameter, length to width ratio, length to thickness ratio, thickness of face sheets to core thickness ratio, nanotubes volume fraction, pre-stress load and orthotropic elastic medium on the natural frequencies and critical buckling load of double-bonded micro composite sandwich plates. It is found that orthotropic elastic medium has a special role on the system stability and increasing Winkler and Pasternak constants lead to enhance the natural frequency and critical buckling load of micro plates, while decrease natural frequency and critical buckling load with increasing temperature changes. Also, it is showed that pre-stresses due to help the axial buckling load causes that delay the buckling phenomenon. Moreover, it is concluded that the sandwich structures with orthotropic cores have high stiffness, but because they are not economical, thus it is necessary the sandwich plates reinforce by carbon or boron nitride nanotubes specially, because these nanotubes have important thermal and mechanical properties in comparison of the other reinforcement.

Temperature-dependent Photoluminescence of Boron-doped ZnO Nanorods

  • Kim, Soaram;Park, Hyunggil;Nam, Giwoong;Yoon, Hyunsik;Kim, Jong Su;Kim, Jin Soo;Son, Jeong-Sik;Lee, Sang-Heon;Leem, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3335-3339
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    • 2013
  • Boron-doped ZnO (BZO) nanorods were grown on quartz substrates using hydrothermal synthesis, and the temperature-dependence of their photoluminescence (PL) was measured in order to investigate the origins of their PL properties. In the UV range, near-band-edge emission (NBE) was observed from 3.1 to 3.4 eV; this was attributed to various transitions including recombination of free excitons and their longitudinal optical (LO) phonon replicas, and donor-acceptor pair (DAP) recombination, depending on the local lattice configuration and the presence of defects. At a temperature of 12 K, the NBE produces seven peaks at 3.386, 3.368, 3.337, 3.296, 3.258, 3.184, and 3.106 eV. These peaks are, respectively, assigned to free excitons (FX), neutral-donor bound excitons ($D^{\circ}X$), and the first LO phonon replicas of $D^{\circ}X$, DAP, DAP-1LO, DAP-2LO, and DAP-3LO. The peak position of the FX and DAP were also fitted to Varshni's empirical formula for the variation in the band gap energy with temperature. The activation energy of FX was about ~70 meV, while that of DAP was about ~38 meV. We also discuss the low temperature PL near 2.251 eV, related to structural defects.

Calcium-Boron Interaction in Exopolysaccharide Production by the Cyanobacterium, Nostoc spongiaeforme

  • Singh;Netu;Asthana, R.K.;Singh, S.P.
    • Journal of Microbiology and Biotechnology
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    • 제10권3호
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    • pp.381-385
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    • 2000
  • The effect and interaction of Ca and B on exopolysaccharide (EPS) synthesis in the diazotrophically growing cyanobacterium. Nostoc spongiaeforme, was investigated. The absence of B inhibited EPS synthesis 1.56-fold ($16\mu\textrm{g}$ glucose equivalent/mg dry weight, 16 d) over the control cells ($25\mu\textrm{g}$ glucose equivalent) grown in medium containing 0.5 mM Ca and $8{\mu}{\textrm}{m}$ B. When B concentration was raised to $40{\mu}{\textrm}{m}$, EPS production was stimulated 1.8-fold. Reduction of Ca concentraion to one-half (0.25 mM) resulted in increased B demand (16$\muM$) by the cells for EPS production at par with the normal sets. However, without Ca, EPS production also increased as B increased. Addition of B to a Ca-free medium stimulated cyanobacterial diazotrophic growth as well as synthesis of Chl a and phycocyanin (0-8 d). The data suggest B-dependent diazotrophic growth during Ca-deficiency and point to and important interactive role of Ca and B in regulation of cyanobacterial EPS synthesis.

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A comprehensive review on the modeling of smart piezoelectric nanostructures

  • Ebrahimi, Farzad;Hosseini, S.H.S.;Singhal, Abhinav
    • Structural Engineering and Mechanics
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    • 제74권5호
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    • pp.611-633
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    • 2020
  • In this paper, a comprehensive review of nanostructures that exhibit piezoelectric behavior on all mechanical, buckling, vibrational, thermal and electrical properties is presented. It is firstly explained vast application of materials with their piezoelectric property and also introduction of other properties. Initially, more application of material which have piezoelectric property is introduced. Zinc oxide (ZnO), boron nitride (BN) and gallium nitride (GaN) respectively, are more application of piezoelectric materials. The nonlocal elasticity theory and piezoelectric constitutive relations are demonstrated to evaluate problems and analyses. Three different approaches consisting of atomistic modeling, continuum modeling and nano-scale continuum modeling in the investigation atomistic simulation of piezoelectric nanostructures are explained. Focusing on piezoelectric behavior, investigation of analyses is performed on fields of surface and small scale effects, buckling, vibration and wave propagation. Different investigations are available in literature focusing on the synthesis, applications and mechanical behaviors of piezoelectric nanostructures. In the study of vibration behavior, researches are studied on fields of linear and nonlinear, longitudinal and transverse, free and forced vibrations. This paper is intended to provide an introduction of the development of the piezoelectric nanostructures. The key issue is a very good understanding of mechanical and electrical behaviors and characteristics of piezoelectric structures to employ in electromechanical systems.

Selective Reduction of Organic Compounds with Non-Free Hydride Reducing Agents

  • Cha, Jin Soon
    • 통합자연과학논문집
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    • 제1권3호
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    • pp.192-194
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    • 2008
  • A series of non-free hydride reducing systems containing boron or aluminum atom, which possess no metal-hydride bond but an available hydrogen at a branched ${\beta}$-position, has been applied to the selective reduction (chemo--, regio-, and stereoselective reduction) of organic compounds. The systems, comprised of diisopinocampheylborane and diisobutylalane derivatives, exhibited almost perfect selectivities in the reduction of aldehydes and ketones. The characteristics features of this systems leading to a perfect transformation have been depicted in this report, especially in the 1) Reduction of ${\alpha}$,${\beta}$-Unsaturated Carbonyl Compounds to Allylic Alcohols via 1,2-Reduction, 2) Chemoselective Reduction between Structurally Different Carbonyl Compounds, and 3) Stereoselective Reduction of Cyclic Ketones.

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Effects of Molding Pressure and Sintering Temperature on Properties of Foamed Glass without Blowing Agent

  • Kim, EunSeok;Kim, Kwangbae;Lee, Hyeryeong;Kim, Ikgyu;Song, Ohsung
    • 한국세라믹학회지
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    • 제56권2호
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    • pp.178-183
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    • 2019
  • A process of fabricating the foamed glass that has closed pores with 8 ~ 580 ㎛ sizes without a blowing agent by sintering 10 ㎛ boron-free glass powder composed of CaO, MgO, SO3, Al2O3-83 wt% SiO2 at a molding pressure of 0 ~ 120 MPa and a sintering temperature of 750 ~ 1000℃ was investigated. To analyze the glass transition temperature of glass powder, thermogravimetric analysis-differential thermal analysis (TGA-DTA) method were used. The microstructure and pore size of foamed glass were examined using the optical microscopy and field emission scanning electron microscopy (FE-SEM). For the thermal diffusivity and color of the fabricated samples, a heat flow meter and ultraviolet-visible-near-infrared (UV-VIS-NIR)-colormetry were used, respectively. In the TGA-DTA result, the glass transition temperature of glass powder was confirmed to be 626℃. In the microstructure result, closed pores of 7 ~ 20 ㎛ were formed at 750 ~ 900℃, and they were not affected by the molding pressure and sintering temperature. However, at 1,000℃, when there was 0 MPa molding pressure, closed pores of 580 ㎛ were confirmed, and the pore size decreased as the molding pressure increased. Moreover, at a molding pressure of 30 MPa or higher, closed pores of approximately 400 ㎛ were formed. The porosity showed an increasing trend of smaller molding pressure and larger sintering temperature, and it was controllable in the range of 5.69 ~ 68.45%. In the thermal diffusivity result, there was no change according to the molding pressure, and, by increasing the sintering temperature, up to 0.115 W/m·K could be obtained. The Lab color index (CIE-Lab) results all showed a similar translucent white color regardless of molding pressure and sintering temperature. Therefore, based on the foamed glass without boron and blowing agent, it was confirmed that white foamed glass, which has closed pores of 8 ~ 580 ㎛ and a thermal diffusivity characteristic of 0.115 W/m·K, can be fabricated by changing the molding pressure and sintering temperature.

개간지 상전에 발생하는 발아불량 현상의 원인 및 방제에 관한 연구 (Studies on the Cause and Control for Non-sprouting Bud in the Utility Reclaimed Hill Side Mulberry Field.)

  • 유근섭
    • 한국잠사곤충학회지
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    • 제16권1호
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    • pp.1-20
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    • 1974
  • 본 연구는 산지개간상전에 발생하는 발아불량현상의 원인을 구명하고 방제법을 대립코자 1971∼1974년까지 4개년간에 걸처 실시하였으며 그 결과는 다음과 같았다. 1. 피해증상은 춘기에는 지조의 선단부가 발아를 하지 않거나 발아도중 즉 탈포∼연구기까지 진행되다가 갑자기 말라 죽는다. 발아불량지조의 피층 및 인피부에는 Necrosis 현상이 일어나고 갈색으로 변한다. 추기에는 엽의 노화, 선단엽의 이상, 엽맥, 엽병이 양변한다. 2. 발아불량상전토양은 화강암모재에 점질의 비율이 매우 낮은 사양토로 되어 있으며 하층토가 치밀 견고하고 공극률이 너무 적어서 근군발달에 매우 불량한 토양구조로 되어 있었다. 특히 발아불량극심지의 심토는 건전지에 비하여 고상이 과대하여 한발시에는 수분부족현상이 일어나기 쉬운 조건을 갖추고 있었다. 3. 발아불량극심상전은 건전상전에 비하여 토양수분함량이 유의하게 적었으며 특히 심토의 수분함량은 건전지가 적당한 수분함량을 유지하고 있었는데 반하여 발아불량극심지는 거의 위조점에 가까운 수분함량이었다. 4. 유방토심은 발아불량상전이 건전상전에 비하여 얕았고, 발아불량정도가 기한곳일수록 유방토심은 얕아지는 경향을 나타냈다. 5. 토양수분함량의 경시적변화는 토양내 유방붕소함량에 영향을 미쳤으며 발아불량상전의 수분함량은 건전상전에 비하여 6월 5일부터 9월 5일까지 계속 적은 함량을 유지하고 있었고, 유방붕소함량도 수분함량의 증감과 같은 경향으로 변화되였다. 6. 토양의 pH(4.7-5.6)와 유방붕소함량간에는 상관관계가 없었으나 유기물함량과 유방붕소함량간에는 고도의 정상관관계가 있었다. 7. 토양중 유방붕소함량은 발아불량상전이 0.19∼0.28ppm, 건전상전이 0.34∼0.43ppm으로서 발아불량상전보다 유의하게 많았다. 8. 엽 및 피층내의 붕소함량은 발아불량수가 건전수보다 유의하게 적었다. 9. 사경시험의 붕소결제구에서는 발아불량현상이 유발되었으며 그 피해증상은 포장에서 발생되는 증상과 동일하였다. 10. 석회의 시용은 시용량이 증가할 수록 발아불량현상을 다소 높게하는 경향이 있었다. 이상의 결과를 종합하여 볼때 뽕나무의 발아불량현상은 붕소의 결핍에 기인되나 붕소의 결핍피해정도는 토양모재, 토양내 유기물함량 및 수분함량 그리고 석회시용등에 의해서도 좌우되는 것으로 인정된다. 11. 발아불량현상은 붕사를 10a 당 6∼9kg을 춘, 하2회분시하면 방제할 수 있으며, 10a당2,000kg의 퇴비를 수년간 계속시용하는 방법도 상당한 방제방과를 얻을 수 있다고 믿어진다.

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Integrated Thyristor Switch Structures for Capacitor Discharge Application

  • 김은동;장창리;김상철;백도현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 반도체재료
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    • pp.22-25
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    • 2001
  • A thyristor switch circuit for capacitor discharge application, of which the equivalent circuit includes a resistor between cathode and gate of a reverse-conducting thyristor and an avalanche diode anti-parallel between its anode and gate to set thyristor tum-on voltage, is monolithically integrated by planar process with AVE double-implantation method. To ensure a lower breakdown voltage of the avalanche diode for thyristor tum-on than the break-over voltage of the thyristor, $p^+$ wells on thyristor p base layer are made by boron implantation/drive-in for a steeper doping profile with higher concentrations while rest p layers of thyristor and free-wheeling diode parts are formed with Al implantation/drive-in for a doping profile of lower steepness. The free-wheeling diode part is isolated from the thyristor part by formation of separated p-well emitter for suppressing commutation between them, which is achieved during the formation of thyristor p-base layer.

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