• Title/Summary/Keyword: Boron based

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Reliable charge retention in nonvolatile memories with van der Waals heterostructures

  • Qiu, Dongri;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.282.1-282.1
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    • 2016
  • The remarkable physical properties of two-dimensional (2D) semiconducting materials such as molybdenum disulfide ($MoS_2$) and tungsten disulfide ($WS_2$) etc. have attracted considerable attentions for future high-performance electronic and optoelectronic devices. The ongoing studies of $MoS_2$ based nonvolatile memories have been demonstrated by worldwide researchers. The opening hysteresis in transfer characteristics have been revealed by different charge confining layer, for instance, few-layer graphene, $MoS_2$, metallic nanocrystal, hafnium oxide, and guanine. However, limited works built their nonvolatile memories using entirely of assembled 2D crystals. This is important in aspect view of large-scale manufacture and vertical integration for future memory device engineering. We report $WS_2$ based nonvolatile memories utilizing functional van der Waals heterostructure in which multi-layered graphene is encapsulated between $SiO_2$ and hexagonal boron nitride (hBN). We experimentally observed that, large memory window (20 V) allows to reveal high on-/off-state ratio (>$10^3$). Moreover, the devices manifest perfect retention of 13% charge loss after 10 years due to large graphene/hBN barrier height. Interestingly, the performance of our memories is drastically better than ever published work related to $MoS_2$ and black phosphorus flash memory technology.

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Prediction of Hardness of Hot Stamped Parts Using the Quench Factor Analysis (핫스템핑 공정에서 Quench Factor Analysis를 이용한 제품의 경도 예측)

  • Choi, J.Y.;Ko, D.H.;Seo, P.K.;Cha, S.H.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.23 no.6
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    • pp.357-362
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    • 2014
  • The purpose of the current study is to predict the hardness distribution in steel products after hot stamping using a quench factor analysis(QFA) coupled with FE-simulations. QFA is a method to predict properties such as hardness and tensile strength based on time-temperature-property(TTP) curves and can determine properties based on the temperature histories. The constants($K_1{\sim}K_5$) of QFA were determined using hardness data obtained after various cooling rates. In the current study, a rear side member was selected for evaluation and FE-simulations were performed to obtain the temperature histories during hot stamping. The predicted temperature data were imported into the QFA to calculate the hardness distribution of the hot stamped parts. A hot stamping experiment of the rear side member was conducted to verify the predicted hardness. The simulation results show good agreement with the experimental measurements.

A Study on the Development of Fouling Analysis Technique for Shell-and-Tube Heat Exchangers (다관원통형 열교환기의 파울링 해석기법 개발 연구)

  • Hwang, Kyeong-Mo;Jin, Tae-Eun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.2
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    • pp.167-173
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    • 2004
  • Fouling of heat exchangers is generated by water-borne deposits, commonly known as foulants including particulate matter from the air, migrated corrosion produces; silt, clays, and sand suspended in water; organic contaminants; and boron based deposits in plants. The fouling is known to interfere with normal flow characteristics and reduce thermal efficiencies of heat exchangers. This paper describes the fouling analysis technique developed in this study which can analyze the thermal performance for heat exchangers and estimate the future fouling variations. To develop the fouling analysis technique fur heat exchangers, fouling factor was introduced based on the ASME O&M codes and TEMA standards. For the purpose or verifying the fouling analysis technique, the routing analyses were performed for four heat exchangers in several nuclear power plants; two residual heat removal heat exchangers of the residual heat removal system and two component cooling water heat exchangers of the component cooling water system.

Influence of Brazing Temperature on Strength and Structure of SUS304 Stainless Steel Brazed System with BNi-2 Filler Metal : Fundamental Study on Brazeability with Ni-Based Filler Metal(II) (BNi-2계 삽입금속에 의한 SUS304 스테인리스강 접합체의 강도와 조직에 미치는 브레이징 온도의 영향 : Ni기 삽입금속에 의한 브레이징 접합성의 기초적 검토(II))

  • Lee, Yong-Won;Kim, Jong-Hoon
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.179-183
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    • 2007
  • A plate heat exchanger (PHE) normally uses vacuum brazing technology for connecting plates and fins. However, the reliability of high temperature brazing, especially with nickel-based filler metals containing boron the formation of brittle intermetallic compounds (IMCs) in brazed joints is of major concern. since they considerably degrade the mechanical properties. This research was examined the vacuum brazing of commercially SUS304 stainless steel with BNi-2 (Ni-Cr-B-Si) filler metal, and discussed to determine the influence of brazing temperatures on the microstructure and mechanical strength of brazed joints. In the metallographic analysis it is observed that considerable large area of Cr-B intermetallic compound phases at the brazing layer and the brazing tensile strength is related to removal of this brittle phase greatly. The mechanical properties of brazing layer could be stabilized through increasing the brazing temperature over $100^{\circ}C$ more than melting temperature of filler metals, and diffusing enough the brittle intermetallic compound formed in the brazing layer to the base metal.

Brazing Property of SUS304 Stainless Steel and BNi-2 Filler Metal with Vacuum Brazing : Fundamental Study on Brazeability with Ni-Based Filler Metal(I) (진공브레이징에 의한 SUS304 스테인리스강과 BNi-2계 삽입금속의 접합특성 : Ni기 삽입금속에 의한 브레이징 접합성의 기초적 검토(I))

  • Lee, Yong-Won;Kim, Jong-Hoon
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.142-146
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    • 2007
  • Vacuum brazing method has been coming to an important process as one of the new fabricating techniques of metals and alloys. In this study, a vacuum brazing of SUS304 stainless steel with BNi-2 filler metal was carried out in $1{\times}10^{4}$ Torr of vacuum atmosphere. The formation of brittle intermetallic compounds in brazed joints between SUS304 stainless steel and BNi-2 filler metal is a major concern, since they considerably degrade the mechanical properties of joints. To obtain enough stable joining strength, it is necessary to understand the unique properties of brazing process with Ni-based filler metals containing boron. So, in this research we investigated the performance of SUS304/BNi-2 brazed system and the brazed joint properties were evaluated at room temperature by using tensile test. Metallurgical and fractographic analysis were used to characterize the microstructure, the mechanisms of brazing, and joint failure modes.

Recent Research Progresses in 2D Nanomaterial-based Photodetectors (2D 나노소재기반 광 센서 소자의 최근 연구 동향)

  • Jang, Hye Yeon;Nam, Jae Hyeon;Cho, Byungjin
    • Ceramist
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    • v.22 no.1
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    • pp.36-55
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    • 2019
  • Atomically thin two-dimensional (2D) nanomaterials, including transition metal dichalcogenides (TMDs), graphene, boron nitride, and black phosphorus, have opened up new opportunities for the next generation optoelectronics owing to their unique properties such as high absorbance coefficient, high carrier mobility, tunable band gap, strong light-matter interaction, and flexibility. In this review, photodetectors based on 2D nanomaterials are classified with respect to critical element technology (e.g., active channel, contact, interface, and passivation). We discuss key ideas for improving the performance of the 2D photodetectors. In addition, figure-of-merits (responsivity, detectivity, response speed, and wavelength spectrum range) are compared to evaluate the performance of diverse 2D photodetectors. In order to achieve highly reliable 2D photodetectors, in-depth studies on material synthesis, device structure, and integration process are still essential. We hope that this review article is able to render the inspiration for the breakthrough of the 2D photodetector research field.

PARTICLE SIZE-DEPENDENT PULVERIZATION OF B4C AND GENERATION OF B4C/STS NANOPARTICLES USED FOR NEUTRON ABSORBING COMPOSITES

  • Kim, Jaewoo;Jun, Jiheon;Lee, Min-Ku
    • Nuclear Engineering and Technology
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    • v.46 no.5
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    • pp.675-680
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    • 2014
  • Pulverization of two different sized micro-$B_4C$ particles (${\sim}10{\mu}m$ and ${\sim}150{\mu}m$) was investigated using a STS based high energy ball milling system. Shapes, generation of the impurities, and reduction of the particle size dependent on milling time and initial particle size were investigated using various analytic tools including SEM-EDX, XRD, and ICP-MS. Most of impurity was produced during the early stage of milling, and impurity content became independent on the milling time after the saturation. The degree of particle size reduction was also dependent on the initial $B_4C$ size. It was found that the STS nanoparticles produced from milling is strongly bounded with the $B_4C$ particles forming the $B_4C$/STS composite particles that can be used as a neutron absorbing nanocomposite. Based on the morphological evolution of the milled particles, a schematic pulverization model for the $B_4C$ particles was constructed.

Detection of Volatile Alcohol Vapors Using Silicon Quantum Dots Based on Porous Silicon (다공성 실리콘을 근거한 실리콘 양자점을 이용한 휘발성 알콜 증기의 감지)

  • Cho, Bomin;Um, Sungyong;Jin, Sunghoon;Choi, Tae-Eun;Yang, Jinseok;Cho, Sungdong;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.3 no.2
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    • pp.117-121
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    • 2010
  • Silicon quantum dots base on photoluminescent porous silicon were prepared from an electrochemical etching of n-type silicon wafer (boron-dopped<100> orientation, resistivity of 1~10 ${\Omega}-cm$) and used as a alcohol sensor. Silicon quantum dots displayed an emission band at the wavelength of 675 nm with an excitation wavelength of 480 nm. Photoluminescence of silicon quantum dots was quenched in the presence of alcohol vapors such as methanol, ethanol, and isopropanol. Quenching efficiencies of 21.5, 32.5, and 45.8% were obtained for isopropanol, ethanol, and methanol, respectively. A linear relationship was obtained between quenching efficiencies and vapor pressure of analytes used. Quenching photoluminescence was recovered upon introducing of fresh air after the detection of alcohol. This provides easy fabrication of alcohol sensor based on porous silicon.

Current Status of Thin Film Silicon Solar Cells for High Efficiency

  • Shin, Chonghoon;Lee, Youn-Jung;Park, Jinjoo;Kim, Sunbo;Park, Hyeongsik;Kim, Sangho;Jung, Junhee;Yi, Junsin
    • Current Photovoltaic Research
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    • v.5 no.4
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    • pp.113-121
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    • 2017
  • The researches on the silicon-based thin films are being actively carried out. The silicon-based thin films can be made as amorphous, microcrystalline and mixed phase and it is known that the optical bandgap can be controlled accordingly. They are suitable materials for the fabrication of single junction, tandem and triple junction solar cells. It can be used as a doping layer through the bonding of boron and phosphorus. The carbon and oxygen can bond with silicon to form a wide range of optical gap. Also, The optical gap of hydrogenated amorphous silicon germanium can be lower than that of silicon. By controlling the optical gaps, it is possible to fabricate multi-junction thin film silicon solar cells with high efficiencies which can be promising photovoltaic devices.

Numerical Simulation of Mechanical Behavior of Composite Structures by Supercomputing Technology

  • Kim, Seung-Jo;Ji, Kuk-Hyun;Paik, Seung-Hoon
    • Advanced Composite Materials
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    • v.17 no.4
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    • pp.373-407
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    • 2008
  • This paper will examine the possibilities of the virtual tests of composite structures by simulating mechanical behaviors by using supercomputing technologies, which have now become easily available and powerful but relatively inexpensive. We will describe mainly the applications of large-scale finite element analysis using the direct numerical simulation (DNS), which describes composite material properties considering individual constituent properties. DNS approach is based on the full microscopic concepts, which can provide detailed information about the local interaction between the constituents and micro-failure mechanisms by separate modeling of each constituent. Various composite materials such as metal matrix composites (MMCs), active fiber composites (AFCs), boron/epoxy cross-ply laminates and 3-D orthogonal woven composites are selected as verification examples of DNS. The effective elastic moduli and impact structural characteristics of the composites are determined using the DNS models. These DNS models can also give the global and local information about deformations and influences of high local in-plane and interlaminar stresses induced by transverse impact loading at a microscopic level inside the materials. Furthermore, the multi-scale models based on DNS concepts considering microscopic and macroscopic structures simultaneously are also developed and a numerical low-velocity impact simulation is performed using these multi-scale DNS models. Through these various applications of DNS models, it can be shown that the DNS approach can provide insights of various structural behaviors of composite structures.