• Journal of the korean academy of Pediatric Dentistry
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• v.34 no.1
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• pp.106-121
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• 2007

The purpose of this study was to examine the effects of suggested etching method on the performance of pits and fissures sealant. In the first part, seventy extracted sound human permanent third molars and premolars were used. The teeth were randomly divided and performed in three different groups as follows : conventional etching, enameloplasty, and testing group. Non-pumicing, dye-guidance vigorous brushing-start etching technique was applied on the occlusal of testing group. Then the pit and fissure sealant was applied on all of the specimens. After the thermocycling and immersing in 1% methylene blue, the resin embedded sections were made. The microleakage data on the section were then recorded under the stereoscope and statistic analysis was done. Additional experiments were also performed : direct fissure surface etched pattern experiment, replica study, and micro-shear bond strength testing observation. The second part included two groups. A paired study was designed to evaluate the influence the environment has on the performance of the sealant. After etching, half of each occlusal surface received one of the two following treatments in succession: sealing in laboratory and intraoral condition (group 1), sealing in intraoral condition with and without a single-bonding agent (group 2). The results of present study can be summarized as follows: - The microleakage of testing group was significant different with conventional method (P<.05) and was not different with the enameloplasty group (P>.05). - The quality and quantity of etched enamel were improved. - Microshear bond strength of testing group was higher than control group (p<.05). - The environmental condition was influenced on the performance of the sealant. The testing etching method modified the capacity of the etching agent to penetrate into the pits and fissures, and simultaneous enhance their efficiency in vitro condition.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.859-862
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• 2008

The objective of this study offer the equation of the development length for GFRP reinforcement. Pullout test carried out to propose the development length for GFRP reinforcement. Test variables included embedment length (L=15, 30 and 45d$_b$ ), pure cover thickness(C=0.5, 1.0, 1.5, and 2.0d$_b$ ), diameter of reforcement(D10, D13 and D16), and three types, (domestic : K2KR, K3KR, foreign : AsUS) of GFRP reinforcement. The method of test were introduced pure pullout and tests lasted until the GFRP reinforcements were reached final failure. Based on the results through the pullout test, the bond characteristics and average bond stress for GFRP reinforcement were investigated. The equation of development length was proposed based on the regression analysis selected specimens having splitting failure. The equation gained from this study compared with the design equation provided by ACI committee 440.1R-06. The results through this study are capable of the flexural member design with GFRP reinforcement having lab spliced.

• Journal of the Korea Institute of Building Construction
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• v.9 no.6
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• pp.141-149
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• 2009

The objective of this study was to propose a development length equation for bottom and top GFRP bars. Including the bottom and top GRPP bars, a total of 104 modified pullout tests were completed. The test variables were embedment length (15, 30, 45db), net cover thickness (0.5~2.0db), different GFRP bar types, and bar diameters (10, 13, 16mm). The average bond stresses were determined based on the modified pullout test results. Two variable linear regression analyses were performed on the results of the average bond stresses. Utilizing the 5% fractile concept, a conservative development length design equation was derived. The design equation of the development length for bottom and top GFRP bars was proposed and the design equation derived in this study was compared to the ACI 440.1R-06 committee equation.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.225-228
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• 2008

This paper presents out-of-plane shear strength models for composite wall with steel plates based on limit theorem in the framework of the plasticity theory. The formulas proposed by JEAG 4618 need to be reconsidered with a couple of limitations; ignoring the effect of bond stress generated by studs in the process of calculating arch action, illogically discriminating between concrete shear cracking strength and arch strength by algebraic relation in short shear span ratio(0-2.0). In most cases, reinforcement ratio is not sufficient to yield, as a result, arch strength is determined by accounting equilibrium including both bond strength and concrete compressive strength. We conducted experimental research assuming that SC wall is a continuous beam under the simplified loading patterns, changing main valuables involving the number of studs, stirrups. The results show good agreements with the formula and we quoted the test results of JEAG.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.397-400
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• 2006

Most of the civil structures in Korea and abroad have many kinds of damages when they are facing over-loaded traffics, long-term serviceability, and severe environmental conditions. Repair, rehabilitation, and retrofit are important for maintaining the serviceability of structures. In recent year, VES-LMC has been widely used as repair material for bridge deck repair and rehabilitation, because the VES-LMC has a various benefits such as traffic opening after 3 hours of curing, higher durability and bond strength. In case of any structure repaired or rehabilitated with VES-LMC, those were influenced capacity of bond between the base layer of slab and VES-LMC as well as physical properties of each other materials. The capacity of bond depended on purity of interface, micro cracks, curing of VES-LMC and so like. A kind of popular concrete repair technique, High pressure water jetting equipment is extremely efficient at removing damaged concrete. Removing damaged or poor quality concrete from sensitive structures such as bridge, tunnels, multi-story car parking decks and runways, using the high pressure water jetting could remove damaged or poor quality concrete remaining healthy and sound concrete. Accordingly, the purpose of this study is that it was to evaluate effect of hydrodemolition on the bond strength of VES-LMC overlay compared with effects of other method such as breaker, untreated. Also, it was evaluated the effect of surface moisture.

• Journal of the Korea Concrete Institute
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• v.24 no.3
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• pp.259-266
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• 2012

A general earthquake resistant design philosophy of ductile frame buildings allows beams to form plastic hinges adjacent to beam-column connections. In order to carry out this design philosophy, the ultimate bond or shear strength of the beam should be greater than the flexural yielding force and should not degrade before reaching its required ductility. The behavior of RC members dominated by bond or shear action reveals a dramatic reduction of energy dissipation in the hysteretic response due to the severe pinching effects. In this study, a method was proposed to predict the deformability of reinforced concrete members with short-span-to-depth-ratios, which would result in bond failure after flexural yielding. Repeated or cyclic loading produces a progressive deterioration of bond that may lead to failure at lower cyclic bond stress levels. Accumulation of bond damage is caused by the propagation of micro-cracks and progressive crushing of concrete in front of the lugs. The proposed method takes into account bond deterioration due to the degradation of concrete in the post yield range. In order to verify bond deformability of the proposed method, the predicted results were compared with the experimental results of RC members reported in the technical literature. Comparisons between the observed and calculated bond deformability of the tested RC members showed reasonably good agreement.

• Restorative Dentistry and Endodontics
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• v.35 no.2
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• pp.134-142
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• 2010

The purpose of this study was to evaluate the effect of Er,Cr:YSGG laser irradiation with hypersensitivity mode on microtensile bond strength of composite resin. Twenty extracted permanent molars were randomly assigned to six groups, according to the irradiation of Er,Cr:YSGG laser, adhesive system (Optibond FL or Clearfil SE bond) and application time of etchant (15 sec or 20 sec). Then composite resin was build up on each conditioned surface. The restored teeth were stored in distilled water at room temperature for 24 h and twelve specimens for each group were prepared. All specimens were subjected to microtensile bond strength and the fracture modes were evaluated. Also, the prepared dentin surface and laser irradiated dentin surface were examined under SEM. The results were as follows: 1. The microtensile bond strength of laser irradiated group was lower than that of no laser irradiated group. 2. Regardless of laser irradiation, the microtensile bond strength of Optibond FL was higher than that of Clearfil SE bond. And the microtensile bond strength of 20 sec etching group was higher than that of 15 sec etching group when using Optibond FL. 3. The SEM image of laser irradiated dentin surface showed prominent peritubular dentin, opened dentinal tubules and no smear layer.

• Restorative Dentistry and Endodontics
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• v.30 no.6
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• pp.435-441
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• 2005

The purpose of this study was to evaluate the effect of increasing application time of single bottle adhesives (SBA) to microtensile bond strength (MTBS) of dried dentin. To expose the superficial dentin surfaces, human molars were sectioned perpendicular to the long axis of tooth. $32\%$ phosphoric acid gels were applied for 15s and rinsed. The teeth were randomly assigned to 3 groups ; S group (Single Bond), O group (One-Step), P group (Prime & Bond NT). Each group was divided to 3 subgroups (W: dentin wipe with wet gauge and light cured immediately, D, dentin dried for 30s and light cured immediately, 30: dentin dried for 30s and light cured after applying SBA for 30s). Composite resin was built up on the dentin surface and sectioned to obtain 20 specimens with $1mm^2$ cross sectional area and the MTBS was measured. For Single Bond, the mean MTBS of S-W and S-30 group were higher than that of S-D group statistically (P<0.05). For One-Step, the mean MTBS of O-D group was statistically lower than that of O-W group (P<0.05). For Prime & Bond NT, the mean MTBS of P-30 group was statistically lower than that of P-D group (P<0.05).

• The korean journal of orthodontics
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• v.31 no.1 s.84
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• pp.137-147
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• 2001

Acidic primer is the bonding agent which combines the conditioning and priming agent into the single solution and was originally developed for the dentin bonding system. It is less harmful to the tooth structure and more convenient to manipulate than the traditional etching procedure. The Purpose of this study is to evaluate the shear bond strength of various bonding materials when the enamel is treated with acidic primer for the bracket bonding procedure. Fifty recently extracted human premolars were randomly separated into five groups -Group I using Clearfil Liner Bond 2 adhesive system to the enamel treated with acidic primer, Group II using Transbond XT adhesive system to the enamel treated with acidic primer, Group III using panavia 21 adhesive system to the enamel treated with acidic primer, Group IV using Fuji-Ortho LC adhesive system to the enamel treated with acidic primer, Group V using Transbond XT adhesive system to the enamel treated with 37$\%$ phosphoric acid. The shear bond strength was measured with Instron universal testing machine after storing in $37^{\circ}C$ water bath for 48 hours. After debonding, the teeth and brackets were examined under scanning electron microscope (SEM) and assessed with the adhesive remnant index (ARI). The results were as follows : 1. There were no significant differences in shear bond strength between group III ($8.69{\pm}2.72MPa$), group IV (9.7 ± 3.16 MPa), and group V ($10.48{\pm}2.60MPa$) (p>0.05). 2. The shear bond strength of group III and group IV was significantly higher than that of group I ($1.09{\pm}0.53MPa$), and Group II ($2.70{\pm}1.46MPa$) (p<0.05). 3. The ARI of group IV ($2.1{\pm}1.1$) and group V ($2.9{\pm}0.3$) was significantly higher than that of group I ($0.2{\pm}0.4$), group II ($0.3{\pm}0.9$) and group III ($0.2{\pm}0.4$) (p<0.05). 4. There were no significant difference between the ARI of group IV and group V (p>0.05). This result suggests that the combination of acidic primer and some bonding adhesive can provide sufficient shear bond strength for clinical orthodontics.

• Journal of the Korean Chemical Society
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• v.32 no.4
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• pp.301-310
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• 1988

Reaction rates for mononuclear heterocyclic rearrangement of N-(5-phenyl-1,2,4-oxadiazol-3-yl)-N'-arylformamidines into 3-acylamino-1-aryl-1,2,4-triazoles were determined spectrophotometrically in dioxane/water (50 : 50, v/v). There are two different reaction paths according to pH. One is pH-independent path, the other is pH-dependent one. In pH-independent path, the result of substituent effect by IYT equation show that N-H bond breaking as well as new N-N bond formation controls the reaction rate. In pH-dependent path, concave-upward Hammett plot was observed. It can be concluded that new N-N bond formation is more advanced than N-H bond breaking in transition state for electron-donating substituents, but N-H bond breaking is more advanced than new N-N bond formation for electron-withdrawing substituents.