• The Journal of the Korean dental association
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• v.58 no.7
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• pp.435-442
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• 2020

Porcelain is the first ceramic material to be introduced into dentistry. Porcelain jacket crown was introduced by Dr. Charles H Land in 1886, which was an excellent aesthetic dental restoration but has not been widely used due to high firing shrinkage and low tensile strength. Then metal-ceramic system, which combines the esthetic properties of ceramics and the mechanical properties of metals, was introduced and nowadays it is still used in dental clinical field. However, the metal-ceramic system has shown some problems, such as increased lightness by reflection of light at opaque layer, shadow beneath the gingival line due to the block-out of light by metal coping, exposure of metal in margin part, bond failure between metal and porcelain, oxidation of metal coping during firing the porcelain, etc. Recently, along with the advance of fabrication methods of dental ceramics, the all-ceramic restorations with high esthetic and mechanical properties has increased and gradually replaced metal-ceramic restorations. Especially, CAD/CAM technology has opened a new era in fabricating the dental ceramic restorations. This overview will take a look at the past, present and future possibility of the dental ceramic materials.

• Korean Journal of Materials Research
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• v.11 no.1
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• pp.3-7
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• 2001

$M\"{o}ssbauer$ spectra of the $Ni_{1+x}Ti_xFe_{2-2x}O_4$ systems ($0{\leqq}x{\leqq}0.7$), which appear as single phase spinel structure, were examined at RT. The $M\"{o}ssbauer$ spectra reveal two sextet for $0{\leqq}x{\leqq}0.3$, two sextet and a doublet for $0.4{\leqq}x{\leqq}0.6$, and a doublet for x=0.7 As x increases, the area ratio of B-site and A-site($A_B/A_A$) of the sextet decreases, and the area ratio of the doublet and the total areas($A_{doublet}/A_{tot.}$) increases. The isomer shift(I.S.) of A-site slightly increases and magnetic hyperfine fields($H_{hf}$) of two sites decrease as the increasing x. From these results, we have obtained the cation distributions of the samples and concluded that the increasing x leads to the decrease of covalency of $Fe^{3+}-O^{2-}$ bond in A-sites and A-B superexchange interactions.eractions.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.10
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• pp.4359-4368
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• 2011

Among several macroeconomic missteps blamed for the recent global financial crisis including the social problems of income distribution and the lack of proper financial remedies, two of them have received particular attention: the global BOP(Balance of Payment) imbalance and the misguided monetary policy. Such BOP imbalance was blamed for massive foreign exchange investment flows from Asia into the U.S., triggering the financial and real estate bubble in America. The latter refers to the excessively loose monetary policy of the U.S. Federal Reserve, which pushed financial institutions and households into reckless investment behavior in search of higher returns. Given the abuse of certain innovative financial techniques and new investment instruments that have been created in recent decades, both collateralized debt obligations (CDOs) and credit default swaps (CDS) enjoyed a symbiotic and toxic relationship prior to the financial crisis This paper is organized as follows: The first section analyzes the real causes of the recent financial crisis. The second details the role of CDOs and CDS. Then, to identify key determinants of the CDS spreads in an emerging capital market, the sample data of major Korean firms' CDS spreads are used to estimate the risk premium by utilizing the multiple regression analysis. The empirical test result indicates that Korean 3-year treasury bond rate(TYIELD), market to book value ratio(MV/BV), and assets size(INASSETS) are shown to demonstrate statistically significant influences on the changes of the CDS premium for sample firms.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.3
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• pp.221-229
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• 1992

A series of experiments on the resuspension of deposited fine-grained sediments were carried out in a recirculating straight flume to investigate the influence of the sediment type, water content and bed shear stress (${\tau}_b$) on the resuspension characteristics of the sediments. The sediments were sampled from Youngkwang coast and Youngdo coast which are located in the western sea and southeastern sea of Korea, respectively. Critical bed shear stress (${\tau}_c$) for resuspension was deduced for each experimental series. For the same sediment, critical bed shear stress for resuspension decreased but suspension mass or rate increased with increasing water content. The resuspension of deposited fine-grained sediments depended strongly on the water content, and the sediment type characterizing the inter-particle bond strength. It has been found that critical bed shear stress for resuspension in the unidirection flow is about 4 times higher than that in the combined wave-current flow, In case of lower bed shear stress, after an initially high suspension, suspension mass approaches a constant value due to the bed hardening with increasing time, but in case of higher bed shear stress, suspension mass increased successively due to the bed softening with time. Initial suspension rate, $E={\alpha}_3({\tau}_b/{\tau}_c-1)^{\beta}$ (where ${\alpha}_3$ and ${\beta}$=empirical constants), was estimated for each experimental series, ${\alpha}_3$ and ${\beta}$ values for the same sediment increased with water content.

• Journal of the Korea Concrete Institute
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• v.22 no.5
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• pp.675-684
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• 2010

The reinforced concrete members are designed to fail in flexural to lead ductile fracture. In the building structures, the failure is typically imposed on beams to prevent damages in columns. However, progression of plastic collapse mechanism may ultimately develop, a plastic hinge at the bottem end of the first floor column, which then can be subjected to shear or bond finally due to large axial force and small shear span-to-depth ratio. In this study, 10 RC column specimens failed in shear after flexural yielding was investigated to determine the factors affecting the plastic hinge length. The findings of this study showed that the most effective factor affecting the plastic hinge length was an axial force. As an axial force increase, an axial strain and a ductility ratio were decreased obviously. The test also shows the observed plastic hinge length was about 0.8~1.2d and the this result has difference compared with forward research.

• International Journal of Highway Engineering
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• v.17 no.3
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• pp.85-95
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• 2015

PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

• Journal of the Korean Geosynthetics Society
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• v.11 no.2
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• pp.39-47
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• 2012

This paper describes large-scale pullout test results of geosynthetic strip, which can be applied in reinforced earth wall with block-type wall facing. The pullout tests are conducted to evaluate the strain distribution, the induced pullout force and the pullout strength. The maximum pullout force is appeared regardless of reinforcement width and normal stress when end displacement is less than 15 mm. The pullout behavior based on horizontal spacing of reinforcement was similar in relationship between pullout force and end displacement. The strain distribution and pullout force distribution of the geosynthetic strip are concentrated in the front part of reinforcement, and it appeared clearly in higher normal stress condition This means that the pullout behavior of geosynthetic strip is affected by the bond between soil and friction resistance reinforcement according normal stress. Therefore, the pullout resistance design is reasonable when pullout behavior of geosynthetic strip should be evaluated by effective length considering tensile characteristic.

• Journal of the Korean Chemical Society
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• v.25 no.6
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• pp.376-382
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• 1981

The rates and the activation parameters for the reaction of phenacyl bromide with substituted anilines in methanol and dimethylformamide were measured. The effects of substituted anilines were discussed. The rate of the reaction was increased with the electron donating power of substituent and showed larger value in DMF than in MeOH. The isokinetic relationship was shown between ${\delta}H^{\neq}$ and ${\delta}S^{\neq}$, isokinetic temperature was 539 and $400^{\circ}C$ in MeOH and DMF respectively, but p-nitro aniline was deviated from linearity in both solvents caused by solvent effects. The excellent linear relationship between log k and p$K_a$ of substituted anilines was observed by following equation. log k = 0.57p$K_a$-1.28 (r = 0.996) in MeOH at $45^{\circ}C$, log k = 0.65p$K_a$-0.88 (r = 0.970) in DMF at $45^{\circ}C$. From the Hammett plot, this reaction was a nucleophilic displacement of aniline to phenacyl bromide and the following equation was obtained at $45^{\circ}C$. log k/$k_0$ = -2.00${\sigma}$ + 0.06 (r = 0.985) in MeOH; log k/$k_0$ = -2.22${\sigma}$ + 0.08 (r = 0.995) in DMF. Large deviation of p-nitro aniline in DMF is resulted from solvent effects too. From above results, the substituent effect of this reaction can be described as $S_N2$ mechanism and bond formation more proceeds in DMF relative to MeOH.

• Journal of the Earthquake Engineering Society of Korea
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• v.16 no.5
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• pp.41-53
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• 2012

The objective of this study is to evaluate the seismic capacity of RC piers with small aspect ratios. Test specimens were selected from the prototype piers among existing national roadway bridges which are expected to fail in shear and/or complex shear-flexural mode. Two groups of full scale RC pier models were constructed with aspect ratios of 2.25 and 2.67. Quasi-static tests have been implemented to investigate the failure behavior of the RC piers in terms of the lap-spliced longitudinal reinforcing steel and the aspect ratio. It is confirmed that regarding its shear-flexural behavior, the pier is very sensitive to the aspect ratio or details. In the case of a test pier with highly lap-spliced longitudinal bars, the bond failure of lap-splice steels was the dominant cause of failure before the occurrence of flexure or shear-flexural failure, despite a slight change in the aspect ratio. Finally, based on the test results and analysis, this paper proposes formulas for the yielding and ultimate displacements of circular reinforced concrete bridge piers without seismic details. These formulas will be useful for the investigation and upgrade of the seismic capacity of bridge piers without seismic details.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.187-194
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• 2013

Fiber reinforced polymer (FRP) has been gathering interest from designers and engineers for its possible usage as a replacement reinforcement of a steel reinforcing bar due to its advantageous characteristics such as high tensile strength, non-corrosive material, etc. Since it is manufactured with various contents ratios, fiber types, and shapes without any general specification, test results for concrete members reinforced with these FRP reinforcing bars could not be systematically used. Moreover, since investigations for FRP reinforced members have mainly focused on short-term behavior, the purpose of this study is to evaluate long-term behaviors of glass FRP (GFRP) reinforcing bar and concrete beams reinforced with GFRP. In this paper, test results of tensile and bond performance of GFRP reinforcing bar and creep behavior are presented. In the creep tests, results showed that 100 years of service time can be secured when sustained load level is below 55% of tensile strength of GFRP reinforcing bar. A modification factor of 0.73 used to calculate long-term deflection of GFRP reinforced beams was acquired from the creep tests for GFRP reinforced concrete beams. It is expected that these test results would give more useful information for design of FRP reinforced members.