• Title/Summary/Keyword: Bond 식

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Properties of $CaO-P_2O_5-SiO_2$ Glasses ($CaO-P_2O_5-SiO_2$계 유리의 물성)

  • 조정식;김철영
    • Journal of the Korean Ceramic Society
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    • v.30 no.4
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    • pp.289-298
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    • 1993
  • Properties in terms of the variation of the glass compositions, which were density (p), molar volume(Vm), atom/ion packing density (Dp), refractive index (nD), transformation temperature (Tg), dilatometric softening point (Td), thermal expansion coefficient (α), Young's modulus (E), and knoop hardness (KHN) were investigated in CaO-SiO2 glasses and CaO-P2O5-SiO2 glasses containing less than 10mole% of P2O5. Those properties were measured by density measurement kit, Abbe refractometer, dilatometer, ultrasonic pulse echo equipment, and micro hardness tester. When CaO content was increased in CaO-SiO2 glasses, p, Dp, nD, Tg, Td, α, E and KHN were increased, while Vm was decreased. When P2O5 was added to the CaO-SiO2 glasses with constant CaO/SiO2 ratio as 1.07, p, Dp, nD, Tg, Td, α, E and KHN were decreased, while Vm was increased. When the amount of P2O5 in glasses was kept constant, the changes of the properties with variation of CaO content in the CaO-P2O5-SiO2 glasses were very similar to those of CaO-SiO2 glasses. These phenomena could be explained by the structural role of P2O5 in the CaO-P2O5-SiO2 glasses, which was polymerization of siicate structures and resulted in [PO4] monomer structure in glasses. Due to this structural characteristics, the bond strength and packing density were changed with compositions. Proportional relationships between 1) np and Dp, 2) Tg, Td, α and CaO content, 3) E and Vm-1, and 4) KHN and P2O5 content were evaluated in this investigation.

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A Microfluidic Chip-Based Creatinine Filtration Device (마이크로 플루이딕 칩을 기반으로 한 크레아티닌 여과장치)

  • Lee, Sack;Shin, Dong-Gyu;Nguyen, Thanh Qua;Park, Woo-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.12
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    • pp.921-925
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    • 2015
  • The number of people suffering from renal disease increases every year. One of the most common treatments (clinical care options) for renal diseases is hemodialysis. However it takes a long time and has a high cost. Therefore, the importance of artificial kidney research has risen. Filtering creatinine from blood is one of the prime renal functions. Thus, we designed a novel two channel microfluidic chip focused on that function. In order to bond the individual polydimethylsiloxane layers, we have developed a housing system using acrylic plastic frame. This method has significant advantages in changing filter membranes. We use anodic aluminum oxide for the filter membrane. We analyzed the difference in the absorbance values for various creatinine concentrations using the Jaffe reaction. For the purpose of acquiring a standard equation to quantify the creatinine concentration, we interpolated the measured data and confirmed the concentration of the filtered solution. Through this experiment, we determined how the filtration efficiency depended on the flow rate and creatinine concentration.

Relationship Marketing Factors, Relationship Quality, and Store Loyalty in Retail Specialty Stores (소매전문점에서의 관계마케팅요인과 관계품질 그리고 점포충성도와의 관계)

  • Park, Myung-Ho;Jung, Jung-Il
    • Journal of Distribution Research
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    • v.11 no.4
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    • pp.97-124
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    • 2006
  • This study investigates the relationship between the relationship marketing factors, relationship quality and store loyalty in retail specialty stores. The customization of a retail specialty store was found to be having a larger effect on relationship quality than other factors such as expertise, bonding and communication and the moderating effects of customer characteristic was found be having a larger effect on relationship quality all factors except to communication. The result of this study has some practical implications. First of all, the customization strategy for individual customers is needed because customers trusted employees who provide a customized service more. Second, the employees' expertise is important to obtain the trust of customers. Third, the findings of the study showed that the communication with employees did not affect the trust. Rather, customers more often want price discounts, useful information, other benefits related to transactions. The communication is also necessary to bond a strong relationship with customers, as well as to respond customer's requests immediately Fourth, the marketing managers of the store have to effectively manage the customer relationship with the special consideration to the customer's gender, transaction experience, and variety seeking disposition.

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The Crystal and Molecular Structure of Z-3-P-Tolylthio-4-Nitro-3-Hexene (Z-3-파라-톨릴치오-4-니트로-3-헥센의 결정 및 분자구조)

  • An, Jung Tae;Gene B. Carpenter
    • Journal of the Korean Chemical Society
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    • v.34 no.2
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    • pp.130-135
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    • 1990
  • The title compound (C13H17NO2S) is monoclinic, space group P21/a, with a = 13.756 (3), b = 9.310(4), c = 21.305(3) $\AA$, $\beta$ = 95.0。, Z = 8, V = 2718.11 $\AA$3, Dc = 1.23$g·{\cdot}cm-3$, (Mo k$\alpha$) = 0.71069$\AA$,$\mu$ = 2.18 cm-1, F(000) = 1071.86, T = 298, R = 0.085 for 2935 unique observed reflections with I >2.0$\sigma$(I). The structure was solved by direct methods. The C-H bond lengths and the methyl groups are fixed and refined as their ideal geometry by allowing to ride on the parent atoms. Both molecules A and B have almost same structures except for two terminal ethyl groups. The ethylene-like skeleton including the nitro group in one molecule is nearly perpendicular to the plane of the methylbenzene group and two ethyl groups form a cis-type structure which has the dfferent orientations between two molecules; in the molecule A, two terminal methyl groups being the opposite directional arrangement against the plane of its skeleton, while in the B, with the same directional structure from its plane. The molecules in the crystal are packed together by non-bonded van der Waals forces.

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Formation of Optical Fiber Preform Using Octamethylcyclotetrasiloxane (Octamethylcyclotetrasiloxane를 이용한 광섬유 클래드 프리폼 형성)

  • Choi, Jinseok;Lee, Tae Kyun;Park, Seong Gyu;Lee, Ga Hyoung;Jun, Gu Sik;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.6-11
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    • 2018
  • There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

Production Condition and Characterization of Extracellular Protease from Micrococcus sp. HJ-19 (Micrococcus sp. HJ19에서 체외분비 단백질 분해효소의 생산조건과 효소특성)

  • Cha, In-Tae;Oh, Yong-Sik;Cho, Woon-Dong;Lim, Chae-Sung;Lee, Je-Kwan;Lee, Oh-Seuk;Roh, Dong-Hyun
    • Korean Journal of Microbiology
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    • v.45 no.1
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    • pp.69-73
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    • 2009
  • Proteases are degradative enzymes which hydrolyze a peptide bond between amino acids and they are abundantly applied to commercial field. In order to investigate optimal medium compositions of carbon and nitrogen source for enzyme production, modified STY medium containing 0.15% yeast extract were used as basal medium. When galactose was used as carbon source, enzyme activity showed 1.3 higher than that of glucose. For nitrogen source addition of casamino acids to basal medium in place of tryptone showed lowest activity, whereas addition of malt extract showed maximal activity. The optimum temperature and pH of extracellular protease were found to be $35^{\circ}C$ an pH 8.5.

An Experimental Study on the Fatigue Flexural Bonding Characteristic of Concrete Beam Reinforced with GFRP Rebar (GFRP Rebar로 보강된 콘크리트보의 피로 휨·부착성능에 관한 실험적 연구)

  • Oh, Hong Seob;Sim, Jong Sung;Kang, Tae-Sung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.1
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    • pp.101-108
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    • 2008
  • This study is to examine bond strength of beam reinforced with GFRP rebar under 4-point fatigue bending test by adopting BRITISH STANDARD. The variables were made to have bonding length of 5times(5db), and 15times(15db) of the nominal diameter of GFRP rebar and were done to analyze the relationship between the bonding strength and the slip. In the result of the test, pull-out failure was dominant in the 5db specimen, patterns of the pull-out failure and concrete shear failure appeared in the 15db specimen showed only concrete shear failure at the end of bonding length. Therefore, The strain development consist of three different stage : A rapid increases form 0 to about 10% of total fatigue life. A uniform increases form 10% to about 70%~90%. Then a rapid increases until failure, if failure takes place. It seems that stress level has not influence on the secant modules of elasticity. And also according to the outcome the existing strengthening method came out to be the most superiority in S-N graphs.

Identification and Characterization of Glycosyl hydrolase family genes from the Earthworm (지렁이의 Gycosyl hydrolasse family 유전자들의 동정과 특성에 관한 연구)

  • Lee, Myung Sik;Tak, Eun Sik;Ahn, Chi Hyun;Park, Soon Cheol
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.4
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    • pp.48-58
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    • 2009
  • Glycosyl hydrolases (GH, EC 3.2.1.-) are key enzymes which can hydrolyze the glycosidic bonds between two or more carbohydrates, or between a carbohydrate and a non-carbohydrate moiety. The new enzyme nomenclature of glycoside hydrolases is based on their amino acid sequence similarity and structural features. Here, we examined the glycosyl hydrolase family(GHF) genes reported from earthworm species. Among overall 115 GHFs, 12 GHFs could be identified from earthworm species through CAZy database. Of 12 GHF group genes, five genes including GHF2, 5, 17, 18, 20 are thought to be potent for industrial applications. The alignment of these genes with same genes from other animal species exhibited high sequence homology and some important amino acid residues necessary for enzyme activity appeared to be conserved. These genes can be utilized as a pest control agent or applicable to the food industry, clinical therapeutics and organic wastes disposition.

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Rotary Bending Fatigue Characteristics According to Optimal Friction Welding of SF45 to SM45C Steel Bars (SF45와 SM45C의 마찰용접 최적화에 따른 회전굽힘피로 특성)

  • Kong, Yu Sik;Park, Young Whan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.3
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    • pp.219-224
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    • 2017
  • A study on dissimilar friction-welded joints was performed for cam shaft applications using solid bar samples, 20mm in diameter, of forging steel(SF45) and carbon steel(SM45C). The main parameters of friction welding such as tensile tests, Vickers hardness surveys of the bond of area, the heat affected zone (HAZ), and the observation of microstructure were investigated to ensure a good quality of friction welding through visual observations. The specimens were tested as-welded and post weld heat treatment(PWHT). This paper deals with optimizing the welding conditions and analyzing various rotary bending fatigue test(RBFT) properties about heat-treated base metal(BM), as-welded and PWHT. Consequently, two materials for friction welding are strongly mixed with a well-combined structure of micro-particles without any molten material, particle growth, or any defect. Moreover, the fatigue limit of BM(SF45) and PWHT for the RBFT were observed as 180MPa and 250MPa, respectively. It was confirmed that the PWHT causes approximately 40% improvement in the fatigue limit when compared to the BM(SF45).

Tensile Adhesive Chracteristics of Waterproofing System for Concrete Bridge Decks (교량 바닥판 조건에 따른 교면방수 시스템의 인장접착 특성)

  • Lee, Byung-Duck;Shim, Jae-Won;Park, Sung-Ki;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.4 no.3 s.13
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    • pp.15-23
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    • 2002
  • The waterproofing system's performance is known to show a determing by complex interaction of material factors, design details, and the quality of construction, and the waterproofing integrity of waterproofing membranes is determined by the bond to the deck and the amount of damage to the waterproofing membrane. In this research, the basic properties of waterproofing membranes on market and the tensile adhesive chracteristics of waterproofing systems of concrete bridge deck have also been investigated in the view of the damages frequently reported from job site. For the tensile adhesive strength of sheet waterproofing membranes, the results after asphalt concrete paving tends to increase more than before those. The results of the liquid waterproofing membranes are upside-down, and the more concrete has strength, the more strength of tensile adhesive increase. The ambient temperature of asphalt concrete when application of the waterproofing membrane has considerable influence on the performance of waterproofing system. As described above, waterproofing system can be influenced by several factors. If they are not considered under construction, the overlooking will cause the damages of pavement and waterproofing system after traffic opening.

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