• Bulletin of the Korean Chemical Society
• /
• v.19 no.9
• /
• pp.962-967
• /
• 1998

Block copolymers consisting of poly(rbenzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) as the hydrophilic part were synthesized and characterized. Polymeric micelles of the block copolymers (abbreviated GEG) were prepared by a dialysis method. The GEG block copolymers were associated in water to form polymeric micelles, and the critical micelle concentration (CMC) values of the block copolymers decreased with increasing PBLG chain length in the block copolymers. Transmission electron microscopy (TEM) observations revealed polymeric micelles of spherical shapes. From dynamic light scattering (DLS) study, sizes of polymeric micelles of GEG-1, GEG-2, and GEG-3 copolymer were 106.5±59.2 nm, 79.4±46.0 nm, and 37.9±13.3 nm, respectively. The drug loading contents of GEG-1, GEG-2 and GEG-3 polymeric micelles were 12.6, 11.9, and 11.0 wt %, respectively. These results indicated that the drugloading contents were dependent on PBLG chain length in the copolymer; the longer the PBLG chain length, the more the drug-loading contents. Release of norfloxacin (NFX) from the nanoparticles was slower in higher loading contents of NFX than in lower loading contents due to the hydrophobic interaction between PBLG core and NFX.

• Journal of Welding and Joining
• /
• v.26 no.2
• /
• pp.92-97
• /
• 2008

In welding of thin plate, some defects such as melt through and unmelted zone occur easily at welding start, however there is a limited study on those problems. Therefore the effects of start block and arc length on melt through and unmelted zone at start were investigated in this study. When start block height was lower than base metal, there was melt through at start. And when the height was even with base metal, no unmelted zone existed. Unmelted zone was increased as start block height increased from 0mm to 0.5mm. However unmelted zone was not much changed as the height increasing from 0.5mm to 1.0mm. When gap existed between start block and base metal, melt through occurred. However, unmelted zone was increased as the contact force of start block on base metal was increased from 0kgf to 7.5kgf. And when arc length was decreased from 3.8mm to 3.0mm, unmelted zone was decreased. It was concluded that the optimum condition to prevent melt through and to minimize unmelted zone would be with start block height 0.25mm, contact force 3.0kgf, and arc length 3.4mm. This optimum condition was applied to the mass production line and resulted in satisfied outcome.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.05a
• /
• pp.99-104
• /
• 2002

In this paper the influence or specimen length on flexural compressive strength and parameter or equivalent rectangular stress block of polymer concrete was evaluated. For this purpose, a series of C-shaped specimens subjected to eccentric compression were tested using four different length-to-depth ratios(from 1.0, 2.0, 3.0 and 4.0) of specimens with compressive strength of 1,020kgf/cm$^2$. Results indicate that for the region of h/c$\leq$3.0 the reduction in equivalent rectangular stress block depth and flexural compressive strength with increase of length-to-depth ratios was apparent but for the region of h/c$\geq$3.0 they were nearly constant. It means that for the region of h/c$\geq$3.0 effect of specimen length on equivalent rectangular stress block depth and flexural compressive strength was negligible. It was also founded that the effect of specimen length on v, a coefficient of strength, that was from 0.84 to 0.86 regardless of h/c was petty. Finally, predictive equation is, suggested by using modified law of effect of specimen length and results.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 1996.04a
• /
• pp.281-285
• /
• 1996

In this paper, I made visual inspection system using Vision Board and it is consist of an illuminator (a fluorescent lamp), image input device(CCD(Charge)Coupled Device) camera), image processing system(Vision Board(FARAMVB-02), image output device(videomonitor, printer), a measuring instrument(TELMN1000). Length measurement by visual inspection system is used 100mm gauge block instead of calculating distance between camera and object, it measured horizontal and vertical length factor from 400mm to 650mm by increasing 50mm. In this place, measured horizontal and vertical length factor made use of length measurement of a injection. A measuring instrument used to compare a measured length of a injection visual inspection system with it. In conclusion, length measurement of a injection compared a measuring instrument withvisual inspecion system using length factor of 100mm guage block. Maximum error of length compared two devices a measuring instrument with visual inspection system is 0.55mm. And operation program is made up Borland C++ 3.1. By changing, it is applied to various uses.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.5
• /
• pp.467-475
• /
• 2001

A triblock copolymer based on $poly(\varepsilon-caprolactone)$ (PCL) as the hydrophobic part and poly(ethylene glycol) (PEG) as the hydrophilic portion was synthesized by a ring-opening mechanism of ${\varepsilon}-caprolactone$ with PEG containing a hydroxyl group at bot h ends as an initiator. The synthesized block copolymers of PCL/PEG/PCL (CEC) were confirmed and characterized using various analysis equipment such as 1H NMR, DSC, FT-IR, and WAXD. Core-shell type nanoparticles of CEC triblock copolymers were prepared using a dialysis technique to estimate their potential as a colloidal drug carrier using a hydrophobic drug. From the results of particle size analysis and transmission electron microscopy, the particle size of CEC core-shell type nanoparticles was determined to be about 20-60 nm with a spherical shape. Since CEC block copolymer nanoparticles have a core-shell type micellar structure and small particle size similar to polymeric micelles, CEC block copolymer can self-associate at certain concentrations and the critical association concentration (CAC) was able to be determined by fluorescence probe techniques. The CAC values of the CEC block copolymers were dependent on the PCL block length. In addition, drug loading contents were dependent on the PCL block length: the larger the PCL block length, the higher the drug loading content. Drug release from CEC core-shell type nanoparticles showed an initial burst release for the first 12 hrs followed by pseudo-zero order release kinetics for 2 or 3 days. CEC-2 block copolymer core-shell type nanoparticles were degraded very slowly, suggesting that the drug release kinetics were governed by a diffusion mechanism rather than a degradation mechanism irrelevant to the CEC block copolymer composition.

• Physical Therapy Rehabilitation Science
• /
• v.6 no.3
• /
• pp.140-145
• /
• 2017

Objective: The purpose of this study was to investigate the effect of visual block with ankle joint fatigue on gait and dynamic balance ability. Design: Cross-sectional study. Methods: Thirty healthy young adults (men=15, women=15) between 22 to 25 years of age voluntarily participated in this study. All subjects performed the gait and dynamic balance test successively in two conditions: the visual block and the open eyes condition. Before the gait and dynamic balance test, muscle fatigue on the ankle joint was induced to all subjects by doing ankle dorsiflexion and plantarflexion alternately, and then gait parameters (step length, stride length, cadence, velocity, single limb support, and double limb support) were assessed by walking on the GAITRite system (CIR Systems Inc., USA). Subjects also performed the functional reach test (FRT) for assessment of dynamic balance. This study examined gait parameters and FRT scores in each visual block and open eyes condition. Results: The results showed that FRT scores with the visual block condition significantly decreased compared to without visual blocking (p<0.01). Step length, stride length, cadence, and velocity of gait parameters decreased significantly in the visual block condition (p<0.01) while there was no significant difference for single limb support. However, double limb support increased significantly in the visual block system (p<0.01). Conclusions: Therefore, blocking of visual information with muscle fatigue of the ankle joint can affect gait and balance ability of young adults and increase the risk of falls.

• 제어로봇시스템학회:학술대회논문집
• /
• 2000.10a
• /
• pp.240-240
• /
• 2000

This paper presents two algorithms based on the concept of the frequency domain adaptive filter(FDAF). First the frequency domain recursive least squares(FRLS) algorithm with the overlap-save filtering technique is introduced. This minimizes the sum of exponentially weighted square errors in the frequency domain. To eliminate discrepancies between the linear convolution and the circular convolution, the overlap-save method is utilized. Second, the sliding method of data blocks is studied Co overcome processing delays and complexity roads of the FRLS algorithm. The size of the extended data block is twice as long as the filter tap length. It is possible to slide the data block variously by the adjustable hopping index. By selecting the hopping index appropriately, we can take a trade-off between the convergence rate and the computational complexity. When the input signal is highly correlated and the length of the target FIR filter is huge, the FRLS algorithm based on the block processing technique has good performances in the convergence rate and the computational complexity.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.28 no.4C
• /
• pp.365-373
• /
• 2003

In this paper, we design a versatle RS decoder which can decode RS codes of any block length n as well as any message length k, based on a modified Euclid's algorithm (MEA). This unique feature is favorable for a shortened RS code of any block length it eliminates the need to insert zeros before decoding a shortened RS code. Furthermore, the value of error correcting capability t can be changed in real time at every codeword block. Thus, when a return channel is available, the error correcting capability can be adaptiverly altered according to channel state. The decoder permits 4-step pipelined processing : (1) syndrome calculation (2) MEA block (3) error magnitude calculation (4) decoder failure check. Each step is designed to form a structure suitable for decoding a RS code with varying block length. A new architecture is proposed for a MEA block in step (2) and an architecture of outputting in reversed order is employed for a polynomial evaluation in step (3). To maintain to throughput rate with less circuitry, the MEA block uses not only a multiplexing and recursive technique but also an overclocking technique. The adaptive RS decoder over GF($2^8$) with the maximal error correcting capability of 10 has been designed in VHDL, and successfully synthesized in a FPGA.

• Macromolecular Research
• /
• v.13 no.5
• /
• pp.435-440
• /
• 2005

This study describes a method where the match of two different length scales, i.e., the patterns from self-assembled block copolymer (<50 nm) and electron beam writing (>50 nm), allow the nanometer scale pattern mask. The method is based on using block copolymers containing a poly(methyl methacrylate) (PMMA) block, which is subject to be decomposed under an electron beam, as a pattern resist for electron beam lithography. Electron beam on self assembled block copolymer thin film selectively etches PMMA microdomains, giving rise to a polymeric nano-pattern mask on which subsequent evaporation of chromium produces the arrays of Cr nanoparticles followed by lifting off the mask. Furthermore, electron beam lithography was performed on the micropatterned block copolymer film fabricated by micro-imprinting, leading to a hierarchical self assembled pattern where a broad range of length scales was effectively assembled, ranging from several tens of nanometers, through submicrons, to a few microns.

• Proceedings of the IEEK Conference
• /
• 2003.07a
• /
• pp.549-552
• /
• 2003

In this paper, an efficient architecture of a versatile Reed-Solomon (RS) decoder is designed, where the message length k as well as the block length n can be variable. The decoder permits 3-step pipelined processing based on the modified Euclid's algorithm(MEA). A new architecture for the MEA is designed for variable values of error correcting capability t. To maintain the throughput rate with less circuitry, the MEA block uses both the recursive and the overclocking technique. The decoder can decode a codeword received not only in a burst mode, but also in a continuous mode. It can be used in a wide range of applications due to its versatility. A versatile RS decoder over GF(2$^{8}$ ) having the error-correcting capability of up to 10 has been designed in VHDL, and successfully synthesized in an FPGA chip.