• Journal of the Mineralogical Society of Korea
• /
• v.23 no.2
• /
• pp.161-170
• /
• 2010

Many microbes, including both bacteria and fungi, produce manganese (Mn) oxides by oxidizing soluble Mn(II) to form insoluble Mn(IV) oxide minerals, a kinetically much faster process than abiotic oxidation. These biogenic Mn oxides drive the Mn cycle, coupling it with diverse biogeochemical cycles and determining the bioavailability of environmental contaminants, mainly through strong adsorption and redox reactions. This mini review introduces recent findings based on quantum mechanical density functional theory that reveal the detailed mechanisms of toxic metal adsorption at Mn oxide surfaces and the remarkable role of Mn vacancies in the photochemistry of these minerals.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.7 no.1
• /
• pp.66-77
• /
• 2005

We have investigated microclimatic controls on the spatiotemporal variations of net primary production (NPP) of a rugged forested watershed using the process-based biogeochemical model (BIOME-BGC). To validate the model simulation of water and carbon cycles at the plot scale, we have conducted field survey over deciduous broadleaf forest (DBF) and evergreen needleleaf forest (ENF) since 2000. The modeled values of soil temperature, soil moisture and soil respiration showed high correlation with those from the field measurements. The modeled seasonal changes of NPP showed high correlation with air temperature but no significant correlation with water related parameters. The precipitation frequency turned out to be the best climatic factor to explain the annual variation of NPP. Furthermore, NPP of ENF was more sensitive to precipitation frequency than that of DBF. With changes in vegetation cover and topography, the spatial distribution of NPP was of great heterogeneity, which was negatively correlated with the magnitude of NPP. Despite the annual precipitation of 1,400mm, NPP at the study site was constrained by the amount of water available for the vegetation. Such a modeling result should be verified by the field measurements.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.8 no.2
• /
• pp.210-224
• /
• 2003

Sulfate reduction is a microbiological process which occurs ubiquitously in anaerobic marine environment. Sulfate reducing bacteria play a significant role in anaerobic decomposition of organic matter and regeneration of inorganic nutrients which supports the primary production in the water column (i.e., benthic-pelagic coupling) and, in special case, could be responsible for the harmful algal bloom in the coastal marine environment. Summary of the sulfate reduction rates reported in various marine sedimentary environments revealed that supply of organic substrates and presence of various electron acceptors (i.e., $O_2$, NO$_{3}$$^{[-10]}$ , Fe(III) and Mn(IV), etc.) for other aerobic and anaerobic respiration directly affect the sulfate reduction rate and relative significance of sulfate reduction in organic matter mineralization. Significance of temperature, macrophytes and bioturbation is discussed as factors controlling supply of organic substrates and distribution of electron acceptors. Finally, we suggest studies on the anaerobic microbiological processes associated with biogeochemical element cycles in the coastal environments of Korea where massive operation of organic enriched fish cage farm, frequent occurrence of toxic algal bloom and hypoxia and conservation of tidal flat are of major environmental issues.

• Journal of Korean Society on Water Environment
• /
• v.36 no.6
• /
• pp.611-620
• /
• 2020

Although process-based models have been a preferred approach for modeling freshwater aquatic systems over extended time intervals, the increasing utility of data-driven models in a big data environment has made the data-driven models increasingly popular in recent decades. In this study, international peer-reviewed journals for the relevant fields were searched in the Web of Science Core Collection, and an extensive literature review, which included total 2,984 articles published during the last two decades (2000-2020), was performed. The review results indicated that the rate of increase in the number of published studies using data-driven models exceeded those using process-based models since 2010. The increase in the use of data-driven models was partly attributable to the increasing availability of data from new data sources, e.g., remotely sensed hyperspectral or multispectral data. Consistently throughout the past two decades, South Korea has been one of the top ten countries in which the greatest number of studies using the data-driven models were published. Among the major data-driven approaches, i.e., artificial neural network, decision tree, and Bayesian model, were illustrated with case studies. Based on the review, this study aimed to inform the current state of knowledge regarding the biogeochemical water quality and ecological models using data-driven approaches, and provide the remaining challenges and future prospects.

• Journal of Korea Water Resources Association
• /
• v.54 no.10
• /
• pp.779-793
• /
• 2021

Water stress and environmental drivers are important factors to explain the variance of gross primary production (GPP). Environmental drivers are used to generate GPP in Moderate Resolution Imaging Spectroradiometer (MODIS) algorithm and process-based model. However, MODIS algorithm only consider the vapor pressure deficit (VPD) data while the process-based biogeochemical model also uses limited data to express water stress. We compared the relationship between environmental drivers and GPP from eddy covariance method, MODIS algorithm, and Community Land Model 4 (CLM 4) simulation in normal years and drought years. To consider water stress specifically, we used VPD and evaporative fraction (EF). We evaluated the effects from environmental drivers and EF towards GPP products using the structural equation modeling (SEM) in South Korea. We found that GPP products from MODIS algorithm and model simulation results were not restricted from VPD data if VPD was underestimated. We also found that in the cropland area, irrigation effects can relieve VPD effects to GPP. However, GPP products derived from MODIS and CLM 4 had limitation to explain the irrigation effects to GPP. Overall, these results will enhance the understanding of GPP products derived from MODIS and CLM 4.

• Ocean and Polar Research
• /
• v.35 no.3
• /
• pp.259-272
• /
• 2013

One of the factors influencing the climate around Korea is the oceanic-atmospheric variability in the tropical region between the eastern Indian and the western Pacific Oceans. Lack of knowledge about the air-sea interaction in the tropical Indo-Pacific region continues to make it problematic forecasting the ocean climate in the East Asia. The 'Tropical Indo-Pacific water transport and ecosystem monitoring EXperiment (TIPEX)' is a program for monitoring the ocean circulation variability between Pacific and Indian Oceans and for improving the accuracy of future climate forecasting. The main goal of the TIPEX program is to quantify the climate and ocean circulation change between the Indian and the Pacific Oceans. The contents of the program are 1) to observe the mixing process of different water masses and water transport in the eastern Indian and the western Pacific, 2) to understand the large-scale oceanic-climatic variation including El Nino-Southern Oscillation (ENSO)/Warm Pool/Pacific Decadal Oscillation (PDO)/Indian Ocean Dipole (IOD), and 3) to monitor the biogeochemical processes, material flux, and biological changes due to the climate change. In order to effectively carry out the monitoring program, close international cooperation and the proper co-work sharing of tasks between China, Japan, Indonesia, and India as well as USA is required.

• Ocean and Polar Research
• /
• v.25 no.1
• /
• pp.21-30
• /
• 2003

Seasonal fluctuations of physico-chemical and biological aspects of the environment were studied in Vladivostok harbour (Golden Horn Bay, the East Sea/Sea of Japan). The benthic community structure was described with a focus on size-spectra (bacteria, meio- and macrofauna) related with the chemical environment and chemical fluxes in sediment and to reveal their possible ecological role in the process of bioremediation of the environment. Samples from two sites with different concentrations of heavy metals (Fe, Zn, Cu, Pb, Mn, Cr, Ni Cd, Co) and petroleum hydrocarbon were assessed by a number of methods. These included plate counts of culturable bacteria, observation through a scanning electron (SEM) and transmission electron microscope (TEM). These approaches were complemented with microscopic assessments of the diversity of the benthic community. The specific communities had a limited number of species, tolerant to abnormally high levels of toxic compounds. The dominant species were presented by several sho.1-lived small polychaetes (Capitella capitata) and nematodes (Oncholaimium ramosum). The highest population density was recorded in microbenthos, in various diatoms, various physiological groups of bacteria which participate in biomineralization: marine heterotrophic bacteria, which oxidized oil, black oil in addition to groups resistant to heavy metals. They have the entire set of mechanisms for neutralizing the negative effect of those compounds, forming the detrital food web and biogeochemical circulation of material in sediments, which results in the biological self-recycling of sea basins. Macro- and meiobenthic organisms were more sensitive to a greater extent of $H_2S$ and petroleum hydrocarbons than to metal content, but the within-site rankings were the same as those achieved for microbiological analyses.

• Proceedings of the KSRS Conference
• /
• v.1
• /
• pp.90-93
• /
• 2006

The first Geostationary Ocean Color Imager (GOCI) onboard its Communication Ocean and Meteorological Satellite (COMS) is scheduled for launch in 2008. GOCI includes the eight visible-to-near-infrared (NIR) bands, 0.5km pixel resolution, and a coverage region of 2500 ${\times}$ 2500km centered at 36N and 130E. GOCI has had the scope of its objectives broadened to understand the role of the oceans and ocean productivity in the climate system, biogeochemical variables, geological and biological response to physical dynamics and to detect and monitor toxic algal blooms of notable extension through observations of ocean color. The special feature with GOCI is that like MODIS, MERIS and GLI, it will include the band triplets 660-680-745 for the measurements of sun-induced chlorophyll-a fluorescence signal from the ocean. The GOCI will provide SeaWiFS quality observations with frequencies of image acquisition 8 times during daytime and 2 times during nighttime. With all the above features, GOCI is considered to be a remote sensing tool with great potential to contribute to better understanding of coastal oceanic ecosystem dynamics and processes by addressing environmental features in a multidisciplinary way. To achieve the objectives of the GOCI mission, we develop the GOCI Data Processing System (GDPS) which integrates all necessary basic and advanced techniques to process the GOCI data and deliver the desired biological and geophysical products to its user community. Several useful ocean parameters estimated by in-water and other optical algorithms included in the GDPS will be used for monitoring the ocean environment of Korea and neighbouring countries and input into the models for climate change prediction.

• Journal of Korean Society for Atmospheric Environment
• /
• v.33 no.1
• /
• pp.54-63
• /
• 2017

Atmospheric nitrogen containing organic compounds(e.g. amino acids) has attracted considerable attention from the viewpoint of the oceanic biogeochemical cycle of nitrogen as well as the long range transfer. However, only a few measurements of organic nitrogen compounds have been conducted due to analytical difficulties. In this study, total of nine amino acids such as Glutamic acid, Histidine, Arginine, Tyrosine, Cystine, Valine, Methionine, Phenylalanine, Lysine have been analytically determined by Liquid Chromatography - Mass Spectrometry Mass Spectrometry (LC-MSMS). As results, Fragmentor Voltage (FV), Precursor Ion, Collision Energy, Product Ion related to individual amino acid compounds are shown. Based on the operational conditions, Lysine, Glutamine Acid, Tyrosine were analyzed during the China Oriented Smog Period. High concentrations of Lysine, Glutamine Acid, and Tyrosine are discussed with organic carbon (OC), elemental carbon (EC), and water soluble ions. The results can provide to understand the sources with aging process related to amino acids influenced by the long-range transport from the Yellow Sea area.

• Asian Journal of Turfgrass Science
• /
• v.20 no.2
• /
• pp.253-264
• /
• 2006

It is a general trend that golf courses have been developed on mountain areas or in valleys due to economical or legal reasons in Korea. Therefore, most of golf courses have special landscape characteristics of brooks and ridge lines as well as peaks. Development of golf courses in the regions of intermediate valley significantly influences ecological factors such as biodiversity, hydrology, and biogeochemical cycles due to changes in original ecosystems of valleys, ridges, and peaks. This study developed a comprehensive framework to incorporate ecological principles and examples into the landscape planning and design process. The restoration system fur water environment may significantly minimize the ecological impacts from developing golf courses. Biotops and artificial damps have been applied to a golf course construction site in southern part of Korea, requiring a restoration of existing water ecosystem by the local EPA. The detailed drawings and water restoration plans were presented in this paper.