• Title/Summary/Keyword: Bio films

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Development of Oxo-biodegradable Bio-plastics Film Using Agricultural By-product such as Corn Husk, Soybean Husk, Rice Husk and Wheat Husk (농산부산물인 옥피, 대두피, 왕겨, 소맥피를 이용한 산화생분해 바이오플라스틱 필름 개발)

  • You, Young-Sun;Kim, Mi-Kyung;Park, Myung-Jong;Choi, Sung-Wook
    • Clean Technology
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    • v.20 no.3
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    • pp.205-211
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    • 2014
  • Biomass-based plastics containing the biomass content higher than 25 wt% have been considered as environment-friendly materials due to their effects on the reduction in the $CO_2$ emission and petroleum consumption as well as biodegradability after use. This article described the effect of the additions of oxo-biodegradable additive, 4 kinds of plant biomass, unsaturated fatty acid, citric acid in the properties of polyethylene films. Bio films were prepared using a variety of biomasses and tested for feasibility as a food packaging film. Mechanical properties such as tensile strength and percent elongation at break were evaluated. Husk biomasses from such as corn, soybean, rice, and wheat were pulverized using air classifying mill (ACM) and four different types of packaging films with thickness of $50{\mu}m$ were prepared using the pulverized biomass and low density polyethylene/linear low density polyethylene. The packaging film with wheat husk biomass was found to have greater mechanical properties of elongation and tensile strength than the other samples. Biodegradability of bio film was measured to be 51.5% compared to cellulose.

Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/Graphene Oxide Nanocomposite Films: Thermomechanical Properties, Oxygen Transmission Rates, and Hydrolytic Degradation

  • You, Eun Jung;Ha, Chang-Sik;Kim, Gue-Hyun;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.26 no.1
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    • pp.1-10
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    • 2017
  • In this study, poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/graphene oxide (GO) nanocomposite films containing various content of GO were prepared using solution casting method. The effect of GO content on Young's modulus and dispersion of GO in PHBV matrix was investigated. Also, the thermomechanical properties, oxygen transmission rates and hydrolytic degradation of PHBV/GO nanocomposite films were studied. The addition of GO into PHBV improves the Young's modulus and decreases thermal expansion coefficient. The improvement can be mainly attributed to good dispersion of GO and interfacial interactions between PHBV and GO. Furthermore, PHBV/GO nanocomposite films show good oxygen barrier properties. PHBV/GO nanocomposites show lower hydrolytic degradation rates with increasing content of GO.

Preparation and Mechanical Properties of Wheat Protein Isolate Films Cross-linked with Resorcinol

  • Chandrasekhar, M.;Prabhakar, M.N.;Song, Jung-Il
    • Composites Research
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    • v.28 no.2
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    • pp.40-45
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    • 2015
  • The purpose of the present work was to preparation and study of full biodegradable Eco-friendly bio-composites by using renewable resources. In this study, wheat protein isolate (WPI) films were formed by cross linking with resorcinol through solution casting method for packaging applications. By varying the resorcinol content (10, 20, 30, 40, and 50 wt %), its effect on mechanical properties of the wheat protein isolate film was measured. The addition of 20% resorcinol led to an overall increase in the tensile strength from 5.2 to 18.6 MPa and modulus increase from 780 to 1132 MPa than WPI films. The % elongation was increased from 2.8 to 9.05 when compared to unmodified WPI film. A thermal phase transition of the prepared WPI was assessed by means of DSC. FTIR is evident that the characteristic WPI spectral IR bands shifted on cross-linking with resorcinol.

Feasibility Study of Diffusion Film for the Light Guide of Gamma Ray Imaging System

  • Cha, Hyemi;Min, Eungi;Lee, Kisung;Jung, Young-Jun;Lee, Hakjae
    • IEIE Transactions on Smart Processing and Computing
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    • v.6 no.2
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    • pp.124-128
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    • 2017
  • A light guide improves the spatial resolution of a gamma ray imaging system by diffusing the scintillation light. Similarly, light diffusion film, which has been applied to flat-panel-display engineering, spreads the light from the light guide panel. In this study, we adopted light diffusion film for the light guide of a gamma ray imaging system, and evaluated its diffusion characteristics. We compared the light diffusion performance of the film to an ordinary acrylic plate. As a result, the diffusion film widely spreads scintillation light. As for the thickness of the light guide, we acquired more distinct images with three films overlapped than with an acrylic plate. We expect light diffusion film to be a promising candidate for light guides in gamma ray imaging systems.

Effect of Red or Blue Resin Added to Greenhouse Covering Films on Growth of Tomato and Pepper (적색 및 청색 수지 첨가 피복재가 토마토와 고추의 생육에 미치는 영향)

  • Kwon, Joon-Kook;Cho, Myeomg-Whan;Kang, Yun-Im;Park, Kyoung-Sub;Woo, J.G.
    • Journal of Bio-Environment Control
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    • v.19 no.4
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    • pp.284-289
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    • 2010
  • Spectral irradiance of greenhouse covering films that three resins (red, blue, red plus blue) were added to get higher utilization efficiency of sunlight were compared to the normal film in this study. Growth and yield of tomato and pepper grown under the films were also investigated. Transmittance of PAR (photosynthetically active radiation, 400~700 nm) and sunlight (300~1,100 nm) of red or blue resin-added films increased by 5 to 6% and 0.5 to 1.0%, respectively. As compared to the normal film, fruit yield and soluble solid content of tomato and pepper grown under red plus blue resin-added film increased by 15 to 20% and by $0.5^{\circ}Bx$.

Photoelectrochemical and Hydrogen Production Characteristics of CdS-TiO2 Nanocomposite Photocatalysts Synthesized in Organic Solvent (유기용매상에서 제조된 수소제조용 CdS-TiO2 나노복합 광촉매의 특성 연구)

  • Jang, Jum-Suk;So, Won-Wook;Kim, Kwang-Je;Moon, Sang-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.3
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    • pp.224-232
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    • 2002
  • CdS-$TiO_2$ nano-composite sol was prepared by the sol-gel method in organic solvents at room temperature and further hydrothermal treatment at various temperatures to control the physical properties of the primary particles. Again, CdS-$TiO_2$ composite particulate films were made by casting CdS-$TiO_2$ sols onto $F:SnO_2$ conducting glass and then heat-treatment at $400^{\circ}C$. Physical properties of these 61ms were further controlled by the surface treatment with $TiCl_4$, aqueous solution. The photo currents and hydrogen production rates measured under the experimental conditions varied according to the $CdS/[CdS+TiO_2]$ mole ratio and the mixed-sol preparation method. For $CdS-TiO_2$ composite sols prepared in IPA, CdS particles were homogeneously surrounded by $TiO_2$ particles. Also, the surface treatment with $TiCl_4$ aqueous solution caused a considerable improvement in the photocatalytic activity, probably as a result of close contacts between the primary particles by the etching effect of $TiCl_4$. It was found that the photoelectrochemical performance of these particulate films could be effectively enhanced by this approach.

Effects of High Performance Greenhouse Films on Growth and Fruit Quality of Tomato (기능성 피복재가 토마토 생육 및 품질에 미치는 영향)

  • Kwon, Joon-Kook;Cho, Myeomg-Whan;Kang, Nam-Jun;Kang, Yun-Im;Park, Kyoung-Sub;Lee, Jae-Han
    • Journal of Bio-Environment Control
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    • v.18 no.3
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    • pp.232-237
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    • 2009
  • This study was performed to investigate the effect of high performance greenhouse films on growth and fruit quality of tomato. For this purpose, polyolefin (PO), fluoric, antidrop, antifog and thermal films were compared to normal film, ethylene vinyl acetate (EVA). In spectral irradiance of the films, UV ($300{\sim}400nm$) transmittance was highest in fluoric film and lowest in PO film. PAR (photosynthetically active radiation, $400{\sim}700nm$) transmittance was higher in fluoric, thermal and PO film, and near infrared ray (NIR, $700{\sim}1,100nm$) transmittance was higher in high performance films, compared to the EVA film. Total light transmittance was higher in order of fluoric, antifog, anti drop, PO, thermal, and EVA film. Day air temperature in greenhouse was highest under fluoric film and lowest under EVA film due to the light transmittance, while night air temperature was highest under PO and anti drop film due to the thickness of film. Tomato fruits grown under the high performance films had 0.2 to $0.5^{\circ}Bx$ higher soluble solids and 15 to 30% higher lycopene content, compared to those grown under the EVA film. The results showed that tomato fruit quality such as soluble solids and lycopene content can be heightened in terms of much irradiation and better light quality of high performance films, compared to the nomal film, EVA film.

Studies on the Physical and Thermal Properties of the Chitosan/Gelatin Blend (키토산/젤라틴 블랜드 폴리머의 물리적 및 열적 특성에 대한 연구)

  • Kim, Byung-Ho;Park, Jang-Woo
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.30-37
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    • 2005
  • To mass-produce useful biopolymer films, chitosan/gelatin blend films were prepared by solution casting method. Effects of mixing ratio, tensile strength (TS), elongation (E) at break, total color difference (${\Dalta}E$), opacity, water vapor permeability (WVP), oxygen permeability (OP), and thermal properties on chitosan/gelatin blend films properties were investigated. TS, E, ${\Dalta}E$, opacity, WVP, and OP values were 58.24-22.01 MPa, 13.11-24.67%, 1.86-17.45, 0.3104-1.2161 nmO.D./${\mu}m$, $1.6875-1.7225ng{\cdot}m/m^{2}{\cdot}s{\cdot}Pa$, and $2.2380{\times}10^{-7}-2.2975{\times}10^{-7}\;mL{\cdot}{\mu}m/m^{2}{\cdot}s{\cdot}Pa$, respectively. TS of blend films decreased, while E, ${\Dalta}E$, and opacity increased with increasing chitosan content. WVP of blend films did not show any significant relationship with mixing ratio and thickness of blend films. Miscibility of films was examined over entire composition range by thermogravimetric analyzer (TGA) and dynamic mechanical analyzer (DMA). TGA results showed gelatin is more thermally stable than chitosan and some interactions among functional groups of two biopolymers. Glass transition temperature $(T_{2})$ of films as determined by DMA decreased with increasing content of chitosan in the blend. Results of thermal analysis indicate high miscibility among polymer components in the blend.

Film-Forming Properties of Proteinaceous Fibrous Material Produced from Soybean Fermented by Bacillus natto

  • Park Sang-Kyu;Bae Dong-Ho
    • Journal of Microbiology and Biotechnology
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    • v.16 no.7
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    • pp.1053-1059
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    • 2006
  • The effectiveness of a proteinaceous fibrous material formed during commercial fermentation of soy protein (PFSP) and cysteine addition were evaluated in order to improve on the properties of soy protein-based films. Nine types of films were prepared at pH 7, 9, and 11, with heat treatments at $70^{\circ}C\;and\;90^{\circ}C$ for 30 min, by casting 5% (w/w) PFSP aqueous solution, containing 2.25% (w/w) glycerol, on to polystyrene plates. The tensile strength (TS) of films ranged from 3.88 to 6.87 MPa. The highest puncture strength (PS) was observed with pH 7.0 films prepared from PFSP solution heated at $70^{\circ}C$ (P<0.05). Alkaline pH and temperature caused a decrease in both the TS and PS of the films. The thickness of films ranged from $58\;to\;74{\mu}m$. Water vapor permeabilities of the films decreased with increasing pH and temperature. To produce films from PFSP, pH value of 7.0 to 9.0 and heat treatment of $70^{\circ}C\;to\;90^{\circ}C$ were needed. A soluble nature of PFSP films in water might be useful for preparation of hot water-soluble pouches. Cysteine addition could be necessary to produce films with increased TS and enhanced barrier properties. The combination treatment that provided the best combination of barrier and mechanical properties was the PFSP film prepared at pH 7.0 with addition of 1% cysteine. The films were good oxygen barriers.