• Applied Chemistry for Engineering
• /
• v.26 no.6
• /
• pp.674-680
• /
• 2015

A solvent-soluble polyimide (PI) polymeric binder was synthesized by a two-step reaction for silicon (Si) anodes for lithium-ion batteries. Polyamic acid was first prepared through ring opening between two monomers, bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA) and 4,4-oxydianiline (ODA), followed by condensation reaction. Using the synthesized PI polymeric binder (molecular weight = ~10,945), the coating slurry was then prepared and Si anode was fabricated. For the control system, Si anode based on polyvinylidene fluoride (PVDF, molecular weight = ~350,000) having the same constituent ratio was prepared. During precycling, PI polymeric binder revealed much improved discharge capacity ($2,167mAh\;g^{-1}$) compared to that of using PVDF polymeric binder ($1,740mAh\;g^{-1}$), while the Coulombic efficiency of two systems were similar. PI polymeric binder improved the cycle retention ability during cycles compared to that of using PVDF, which is attributed to an improved adhesion property inside Si anode diminishing the dimensional stress during Si volume changes. The adhesion property of each polymeric binder in Si anode was confirmed by surface and interfacial cutting analysis system (SAICAS) (Si anode based on PI polymeric binder = $0.217kN\;m^{-1}$ and Si anode based on PVDF polymeric binder = $0.185kN\;m^{-1}$).

• Applied Chemistry for Engineering
• /
• v.22 no.5
• /
• pp.501-507
• /
• 2011

To develop environmental-friendly insulating composite materials, natural cellulose and porous ceramic balls were used as core materials and activated Hwangtoh was used as a binder. Various specimens were prepared with different water/binder ratios and core material/binder ratios. The physical properties of these specimens were then investigated through compressive strengths, flexural strengths, absorption test, hot water resistance test, pore analysis, thermal conductivity, and observation of micro-structures using scanning electron microscope. Results showed that the maximum compressive strength varied appreciably with the water/binder ratios and core material/binder ratios, but the flexural strength increased with the core material/binder ratios regardless of water/binder ratios. The compressive strength and the flexural strength measured after the hot water resistance test decreased remarkably compared to those measured before test. The pore analysis measured after the hot water resistance test showed that total pore volume, porosity and average pore diameter decreased, while bulk density increased by the acceleration of hydration reaction of binder in the hot water. The thermal conductivity decreased gradually with an increase of core material/binder ratios. It can be evaluated that the composite insulation materials having good insulating properties and mechanical strengths can be used in the field.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.21 no.5
• /
• pp.141-147
• /
• 2017

Recently, lots of researches on concrete with high volume mineral admixtures such as ground granulated blast-furnace slag(GGBS) have been carried out to reduce greenhouse gas. The high volume GGBS concrete has advantages such as low heat, high durability, but it has a limitation in practical field application, especially low strength development in early ages. This study investigated the compressive strength and hydration characteristics of high performanc and volume GGBS cement pastes with low water to binder ratio. The effects of fineness($4,330cm^2/g$, $5,320cm^2/g$, $6,450cm^2/g$, $7650cm^2/g$) and replacement(35%, 50%, 65%, 80%) of GGBS on the compressive strength, setting and heat of hydration were analyzed. Experimental results show that the combination of high volume slag cement paste with low water to binder ratio and high fineness GGBS powder can improve the compressive strength at early ages.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.14 no.4
• /
• pp.28-33
• /
• 2015

In this study, the optimal design for the support and the binding device for the protection of crops for the maximum allowable stress of the shape necessary to minimize volume has been proposed. Optimization of the support and the binding device for the crops should be designed to support businesses in terms of profit, in part to reduce the material, and to profit from the ease and speed of working that part of the farmers. We used CATIA for the mechanical design and the ANSYS program for the structural analysis. Additionally, the optimization was performed by PIAnO with seven design variables for the binding device and three parameters for the support. The weight method using a multi-objective function was also determined by the Pareto optimal solution. The volume of the binding device in the optimum design result was found to be reduced by 16%, from $2.278e-005m^3to1.912e-005m^3$. From the result, we confirmed the effectiveness of the design method proposed as a multi-objective function optimization problem.

• Advances in concrete construction
• /
• v.6 no.1
• /
• pp.29-45
• /
• 2018

This paper investigates the effect of inclusion of glass fibers on mechanical and fracture properties of binary blend geopolymer concrete produced by using fly ash and ground granulated blast furnace slag. To study the effect of glass fibers, the mix design parameters like binder content, alkaline solution/binder ratio, sodium hydroxide concentration and aggregate grading were kept constant. Four different volume fractions (0.1%, 0.2%, 0.3% and 0.4%) and two different lengths (6 mm, 13 mm) of glass fibers were considered in the present study. Three different notch-depth ratios (0.1, 0.2, and 0.3) were considered for determining the fracture properties. The test results indicated that the addition of glass fibers improved the flexural strength, split tensile strength, fracture energy, critical stress intensity factor and critical crack mouth opening displacement of geopolymer concrete. 13 mm fibers are found to be more effective than 6 mm fibers and the optimum dosage of glass fibers was found to be 0.3% (by volume of concrete). The study shows the enormous potential of glass fiber reinforced geopolymer concrete in structural applications.

• Journal of Electrochemical Science and Technology
• /
• v.12 no.1
• /
• pp.74-81
• /
• 2021

Silicon (Si) is recognized as a promising anode material for high-energy-density lithium-ion batteries. However, under a condition of electrode comparable to commercial graphite anodes with low binder content and a high electrode density, the practical use of Si is limited due to the huge volume change associated with Si-Li alloying/de-alloying. Here, we report a novel core-shell composite, having a reversible capacity of ~ 500 mAh g-1, by forming a shell composed of a mixture of nano-Si, graphite nanosheets and a pitch carbon on a spherical natural graphite particle. The electrochemical measurements are performed using electrodes with 2 wt % styrene butadiene rubber (SBR) and 2 wt.% carboxymethyl cellulose (CMC) binder in an electrode density of ~ 1.6 g cm-3. The core-shell composites having the reversible capacity of 478 mAh g-1 shows the outstanding capacity retention of 99% after 100 cycles with the initial coulombic efficiency of 90%. The heterostructure of core-shell composites appears to be very effective in buffering the volume change of Si during cycling.

• Composites Research
• /
• v.35 no.2
• /
• pp.69-74
• /
• 2022

In this study, the conductive paste used in a wide range such as wiring in the electronic packaging field, the automobile industry, and electronic products is manufactured under various process conditions due to the simplicity of the process, and then the thermal, mechanical, and electrical characteristics are analyzed and simulation studies are conducted to optimize the process. to establish the conditions of the conductive paste manufacturing process. First, a conductive paste was prepared by setting various types of binder resin, an essential component of the conductive paste, and characteristics such as thermal conductivity, tensile strength, and elongation were analyzed. Among the binder resins, the conductive paste applied with a flexible epoxy material had the best physical properties, and a simulation study was conducted based on the physical property data base of the conductive face. As a result of the simulation, the best physical properties were exhibited when the Ag flake volume fraction was 60%.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.6 no.1
• /
• pp.1-7
• /
• 2018

This study examined the effect of binder-to-soil ratio(B/S) and water-to-binder ratio(W/B) on the flow and compressive strength development of soil concrete using high-volume supplementary cementitious materials. As a partial replacement of ordinary portland cement, 10% by-pass dust, 40% ground granulated blast-furnace slag, and 25% circulating fluidized bed combustion fly ash were determined in the preliminary tests. Using the low-cement binder incorporated with clay soil or sandy soil, a total of 18 soil concrete mixtures was prepared. The flow of the soil concrete tended to increase with the increase in W/B and B/S, regardless of the type of soils. The compressive strength was commonly higher in sandy soil concrete than in clay soil concrete with the same mixture condition. Considering the high-workability and compressive strength development, it could be recommended for low-cement soil concrete to be mixed under the following condition: B/S of 0.35 and W/B of 175%.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.12 no.2
• /
• pp.135-142
• /
• 2024

The purpose of this study is to experimentally investigate the effect of water-binder ratio and fiber type on the compressive strength and tensile performance of fiber reinforced highly ductile composites. To achieve this, four different mixtures were prepared by varying the water-binder ratio and fiber type, and compression and tension tests were conducted. The test results showed that the influence of fiber type on compressive strength was minimal, however, the WB50 series mixture exhibited a 29 % lower strength compared to the WB40 series mixture, indicating a significant effect of the water-binder ratio. On the other hand, the effect of fiber type on tensile properties was found to be more significant than that of the water-binder ratio. Tensile strain capacity ranged from 2.9 % to 6.2 %, with PE series mixtures showing 1.63 to 2.14 times higher performance compared to PVA series mixtures. Additionally, the crack patterns of the PE series mixtures were superior than those of the PVA series mixtures.

• Advances in concrete construction
• /
• v.12 no.5
• /
• pp.367-375
• /
• 2021

This study experimentally investigated the improvement of bond strength and durability of concrete containing high volume fly ash. Concrete mixtures made with 0%, 25% and 60% replacement of cement with class F fly ash were prepared. Water-binder ratios ranged from 0.28 to 0.72. The compressive, flexural and pullout bond strength, the resistance to chloride-ion penetration, and the water permeability of concrete were measured and presented. Test results indicate that except for the concretes at early ages, the mechanical properties, bond strength, and the durability-related chloride-ion permeability and water permeability of concrete containing high volume (60% cement replacement) fly ash were obviously superior to the concrete without fly ash at later ages of beyond 56 days. The enhanced bond strength for the high volume fly-ash concrete either with or without steel confinement is a significant finding which might be valuable for the structural application.