• Title/Summary/Keyword: Bet A

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Effects of Temperature on A Synthesized Birnessite (온도 변화에 따른 합성 버네사이트 특성 변화 연구)

  • Park, Soo Oh;Kim, Young Jae;Lee, Young Jae
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.81-86
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    • 2013
  • A series of birnessite was synthesized at 25, 40, 60, and $80^{\circ}C$, respectively. Intensities of XRD and the ratio of signal to noise of the peaks for samples increases with increasing temperature up to $60^{\circ}C$, whereas the intensity and ratio for a sample synthesized at $80^{\circ}C$ decrease, showing that crystallinity of the birnessite synthesized at $60^{\circ}C$ is better than that of the synthesized at $80^{\circ}C$. However, BET surface areas for these two samples show that the surface area increases 39.4 to 89.7 $m^2/g$ with increasing synthesizing temperature from 60 up to $80^{\circ}C$, indicating that a small surface area is shown in a well-crystallized birnessite rather than that of a poorly crystallized birnessite. SEM images show that morphologies for samples are seriously influenced by temperature. The morphology of the synthesized at 25 shows a round-shape, while a plate-like morphology is shown in the synthesized birnessite at $80^{\circ}C$. In addition, a porous layered structure is also shown in the synthesized birnessite at $80^{\circ}C$. These results suggest that physicochemical properties of the synthesized birnessite are sensitively affected by mechanical changes of parameters such as temperature during the synthesization.

Studies on Correlation Among Sperm Characteristics, Farrowing Rates by AI and Chromatin Structure in Boars (돼지에서 정액 성상 및 인공수정 분만율과 염색질 구조 분석(SCSA)과의 상관관계에 관한 연구)

  • 유재원;김인철;이장희;조규호;지달영;이주형;김일;이종완;윤희진;방명걸;류범용;정영채;김창근
    • Journal of Animal Science and Technology
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    • v.48 no.6
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    • pp.777-784
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    • 2006
  • This study was designed to investigate between the semen characteristics and sperm chromatin structure in boar with different farrowing rates and relationship between fertility by AI and results of sperm chromatin structure assay (SCSA). The CASA (computer-aided sperm analysis) and SCSA were performed with liquid semen in boars. The all SCSA parameters based on the farrowing rates by AI were significantly differ (P<0.05). The significant negative correlations (P<0.05) were observed between all SCSA parameters and farrowing rate obtained by AI in the field. In conclusion, these results suggest that the sperm parameters evaluated in these studies may be useful indicators to predict the fertility by AI.

The Protective Effects of Scutellaria baicalensis Georgi Water Extracts on the Immunomodulatory Effects on Liver Damage Induced by Carbon Tetrachloride in Rats (사염화탄소로 간 손상이 유발된 흰쥐에서 황금(黃芩) 열수 추출물이 면역작용에 미치는 효과)

  • An, Chi-Sun;Jin, Hai-Lan;Jeon, Yun-Hui;Lim, Beong-Ou
    • Korean Journal of Medicinal Crop Science
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    • v.17 no.4
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    • pp.273-279
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    • 2009
  • GATA-binding protein-3 (GATA-3) and T-box expressed in T-cells (T-bet) are now considered as master transcription factors involving Th cell differentiation, but the roles of these factors are still uncertain in vivo. This study was conducted to investigate the expression of these transcription factors in the liver damage induced by carbon tetrachloride ($CCl_4$) in rats. In this study, liver damage were induced with Scutellaria baicalensis Georgi water extracts (SBW) and followed for 4 weeks. The expression of GATA-3 and T-bet protein in liver damage induced by $CCl_4$ and the serum levels of immunoglobulin A (IgA), IgE were studied after 4 weeks of treatment. We found that effect of SBW on IFN-$\gamma$, STAT1, pSTAT1 and T-bet was decreased in vivo. Several genes were demonstrated to be IL-4 inducible prior to the discovery of STAT6. $CCl_4$+SBW group was significantly lower than $CCl_4$ group in IL-4, STAT6, pSTAT6 and GATA-3. Our data indicate that cytokine protein production were increased in $CCl_4$ group and $CCl_4$+SBW group. From these results, water extracts obtained from Scutellaria baicalensis Georgi may have an immunoregulatory effect in the liver induced by $CCl_4$ of rats.

A Study on the Development of Activated Carbons from Sewage Sludge (하수슬러지를 이용한 활성탄 개발에 관한 연구)

  • Lee, Taek-Ryong;Chung, Chan-Kyo;Joe, Young-Cheon
    • Clean Technology
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    • v.15 no.1
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    • pp.31-37
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    • 2009
  • This study deals with the production process of activated carbons from the sewage sludge char by chemical activation reaction. KOH and NaOH were used as activating agents, which react well with carbon. From the experiments, it was found that activated carbons made with KOH treatment had better physicochemical properties in terms of iodine number and BET value than those made with NaOH treatment. It was also found that the optimal deposition ratio of an activating agent to the sewage sludge char was 75 wt% of KOH and 50 wt% of NaOH. Activated carbons were washed out by distilled water after neutralization with 5 M hydrochloric acid solution. The activated carbons that were produced from a sewage sludge char at this optimal conditions have BET surface areas of approximately $600m^2/g$.

Additional Effect of Zeolite Based on Bactericidal Activated Carbon Spheres with Enhanced Adsorption Effect and Higher Ignition Temperature

  • Zhu, Lei;Ye, Shu;Asghar, Ali;Bang, Seong-Ho;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.68-74
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    • 2016
  • In this study, the fabrication of zeolite combined activated carbon spherical samples was carried out as follows. Briefly, ZSM-5 zeolite and activated carbon were composed as main absorbent materials; by controlling the weight percentage of zeolite and binder materials, a series of spherical samples (AZP 4, 6, 8) were prepared. These spherical samples were characterized by BET, XRD, SEM, EDX, and pressure drop; benzene and iodine adsorption tests, bactericidal effect test, and ignition temperature test were also performed. The adsorption capability was found to depend on the BET surface area; the spherical samples AZP6 with high BET surface area of $1011m^2/g$ not only exhibited excellent removal effects for benzene (24.9%) and iodine (920mg/g) but also a good bactericidal effect. The enhanced ignition temperature may be attributed to the homogeneous dispersion conditions and the proper weight percentage ratio between zeolite and activated carbon.

Characterization of the Functional Domains of Human Foamy Virus Integrase Using Chimeric Integrases

  • Lee, Hak Sung;Kang, Seung Yi;Shin, Cha-Gyun
    • Molecules and Cells
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    • v.19 no.2
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    • pp.246-255
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    • 2005
  • Retroviral integrases insert viral DNA into target DNA. In this process they recognize their own DNA specifically via functional domains. In order to analyze these functional domains, we constructed six chimeric integrases by swapping domains between HIV-1 and HFV integrases, and two point mutants of HFV integrase. Chimeric integrases with the central domain of HIV-1 integrase had strand transfer and disintegration activities, in agreement with the idea that the central domain determines viral DNA specificity and has catalytic activity. On the other hand, chimeric integrases with the central domain of HFV integrase did not have any enzymatic activity apart from FFH that had weak disintegration activity, suggesting that the central domain of HFV integrase was defective catalytically or structurally. However, these inactive chimeras were efficiently complemented by the point mutants (D164A and E200A) of HFV integrase, indicating that the central domain of HFV integrase possesses potential enzymatic activity but is not able to recognize viral or target DNA without the help of its homologous N-terminal and C-terminal domains.

Preparation of Spherical Activated Carbon and Their Physicochemical Properties

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Zhang, Kan;Meng, Ze-Da
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.568-573
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    • 2009
  • In this study, we used coal based activated carbons as starting material and phenolic resin (PR) as a bonding agent to prepare spherical shaped activated carbons. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity and pressure drop. According to the results, the spherical activated carbon prepared with activated carbon and PR at a ratio of 60:40 was found to have the best formation of spherical shape, which was found in sample SAC40. After activation, SAC40 has high BET surface area, iodine adsorption capability and strength value, and lowest pressure drop.

A Study on the Water-Vapor Sorption of Resin Treated Viscose Rayon - Characterization by the GAB and BET Equations - (수지처리된 비스코스 레이온 섬유의 흡습성에 관한 연구 - BET, GAB식에 의한 해석 -)

  • Lee Mee Sik
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.1 s.33
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    • pp.13-19
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    • 1990
  • The water-vapor sorption isotherms of viscose rayon and of modified viscose rayon were studied to elucidate the change of sorptivity by the DMDHEU resin finish. To determine the sorption isotherms, moisture regains of the samples were measured at various humidities. The sorption isotherms were determined by the BET and GAB multilayer adsorption theories. The adsorption isotherm of the starting rayon was Brunauer Type II while with increasing resin content those of the DMDHEU-treated rayon became progressively more like Type IV. The DMDHEU-treated samples appeared to be hydrophilic due to the hydrophilicity of DMDHEU although moisture regains at higher humidities markedly decreased because of an impediment in swelling by crosslinkings. The $W_{m}$ value and surface area of crosslinked samples increased with increasing resin content. VR-R-6 which was the most heavily crosslinked viscose rayon had the highest $W_{m}$ and surface area values among all the samples. Relative sorption hysteresis was decreased as humidity increased for all samples. The untreated viscose rayon appeared to have a higher value than the DMDHEU-treated rayon.

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Adsorption of $N_2$ and Ar Gases on the Non-porous Perovskite Surfaces (무공성 Perovskite 표면에서의 $N_2$와 Ar 기체의 흡착)

  • Hyun-Woo Cho;Jung-Soo Kim;Kwang-Soon Lee;Woon-Sun Ahn
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.204-210
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    • 1991
  • Multilayer adsorption isotherms of nitrogen and argon on the perovskite-type mixed oxides, synthesized by a citrate coprecipitation method, are determined at the liquid nitrogen temperature using a gravimetric adsorption apparatus. The volume of the adsorbed gas are plotted against the statistical thickness of the adsorbed layer, calculated from several universal adsorption isotherms one after another. The t-method area obtained from this plot is compared with the BET area and finally the appropriateness of universal adsorption isotherms is then discussed on the basis of the plot.

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A Study on Characterization of Surface and Pore for Ag-impregnated Activated Carbon (은이 침착된 활성탄의 표면과 세공특성에 관한 연구)

  • Kim, Jong-Gyu;Oh, Won-Chun;Kim, Myoung-Kun
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.729-733
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    • 1998
  • The surface structure and the pore size distribution of the activated carbon impregnated with silver have been investigated. It has been confirmed that the impregnants had an effect only on the external surface, not on the internal surface and that adsorption isotherms of both impregnated and non-impregnated activated carbons were classified as a typical BET type-I. As the amount of the impregnants increased, the amounts of adsorption, the specific surface area, and the micropore volume decreased and the window blocking was observed. The average pore diameter of the activated carbon impregnated with silver was observed to show the constant values regardless of the amount of the impregnants.

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