• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1191-1198
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• 2023

Bentonite buffer material is a critical component in an engineered barrier system (EBS) for disposing high-level radioactive waste (HLW). The bentonite buffer material protects the disposal canister from groundwater penetration and releases decay heat to the surrounding rock mass; thus, it should possess high thermal conductivity, low hydraulic conductivity, and moderate swelling pressure to safely dispose the HLWs. Bentonite clay is a suitable buffer material because it satisfies the safety criteria. Several additives have been suggested as mixtures with bentonite to increase the thermal-hydraulic-mechanical-chemical (THMC) properties of bentonite buffer materials. Therefore, this study investigated the geotechnical, mineralogical, and THMC properties of several candidate additives such as sand, graphite, granite, and SiC powders. Datasets obtained in this study can be used to select adequate additives to improve the THMC properties of the buffer material.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2002.04a
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• pp.19-26
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• 2002

In this paper, the nonlinear structural analysis for the composite structure of the spent nuclear fuel disposal container and the 50cm thick bentonite buffer is carried out to predict the collapse of the container while the sudden rock movement of 10cm is applied on the composite structure. This sudden rock movement is anticipated by the earthquake etc. at a deep underground. Horizontal symmetric rock movement is assumed in this structural analysis. Elastoplastic material model is adopted. Drucker-Prager yield criterion is used for the material yield prediction of the bentonite buffer and von-Mises yield criterion is used for the material yield prediction of the container(cast iron insert, copper outer shell and lid and bottom). Analysis results show that even though very large deformations occur beyond the yield point in the bentonite buffer, the container structure still endures elastic small strains and stresses below the yield strength. Hence, the 50cm thick bentonite buffer can protect the container safely against the 10cm sudden rock movement by earthquake etc.. Analysis results also show that bending deformations occur in the container structure due to the shear deformation of the bentonite buffer. The elastoplastic nonlinear structural analysis for the composite structure of the container and the bentonite buffer is performed using the finite element analysis code, NISA.

• Transactions of Materials Processing
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• v.12 no.5
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• pp.479-486
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• 2003

This paper presents an elastoplastic analysis for spent nuclear fuel disposal container and its 50 cm thick bentonite buffer to predict the collapse of the container while the horizontal asymmetric sudden rock movement of 10 cm is applied on the composite structure. This sudden rock movement is anticipated by the earthquake etc. at a deep underground. Elastoplastic material model is adopted. Drucker-Prager yield criterion is used for the material yield prediction of the bentonite buffer and von-Mises yield criterion is used for the material yield prediction of the container. Analysis results show that even though very large deformations occur beyond the yield point in the bentonite buffer, the container structure still endures elastic small strains and stresses below the yield strength. Hence, the asymmetric 50 cm thick bentonite buffer can protect the container safely against the 10 cm sudden rock movement by earthquake etc.. Analysis results also show that bending deformations occur in the container structure due to the shear deformation of the bentonite buffer. The finite element analysis code, NISA, is used for the analysis.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.2
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• pp.185-192
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• 2022

A compacted bentonite buffer is a major component of engineered barrier systems, which are designed for the disposal of high-level radioactive waste. In most countries, the target temperature required to maintain safe functioning is below 100℃. If the target temperature of the compacted bentonite buffer can be increased above 100℃, the disposal area can be dramatically reduced. To increase the target temperature of the buffer, it is necessary to investigate its properties at temperatures above 100℃. Although some studies have investigated thermal-hydraulic properties above 100℃, few have evaluated the water suction of compacted bentonite. This study addresses that knowledge gap by evaluating the water suction variation for compacted Korean bentonite in the 25-150℃ range, with initial saturations of 0 and 0.22 under constant saturation conditions. We found that water suction decreased by 5-20% for a temperature increase of 100-150℃.

• Tunnel and Underground Space
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• v.21 no.4
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• pp.264-273
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• 2011

Bentonite buffer is one of the major components of an engineered barrier for an HLW (High-Level Waste) repository. The bentonite buffer is significantly exposed to the decay heat from radioactive wastes, the inflow of groundwater from the surrounding rock of the repository, and the high swelling pressure of densely-compacted bentonite that comes in contact with the groundwater. Therefore, it is essential to understand the THM (Thermal-Hydro-Mechanical) behavior of the bentonite buffer and to acquire the input data of its related constitutive models for the performance and safety assessment of an HLW repository. This paper analyzed the THM properties which have been obtained by conducting laboratory tests with a candidate buffer material for a Korean HLW repository. Moreover the formulation recipe of the reference bentonite buffer was defined on the basis of functional criteria, thus suggesting the THM properties which correspond to the formulation recipe of the reference bentonite buffer.

• Tunnel and Underground Space
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• v.33 no.4
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• pp.228-243
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• 2023

Bentonite is widely recognized and utilized as a buffer material in high-level radioactive waste repositories, mainly due to its favorable characteristics such as swelling capability and low permeability. Bentonite buffers play an important role in ensuring the safe disposal of radioactive waste by providing a low permeability barrier and effectively preventing the migration of radionuclides into the surrounding rock. However, the long-term performance of bentonite buffers still remains a subject of ongoing research, and one of the main concerns is the erosion of the buffer induced by swelling and groundwater flow. The erosion of the bentonite buffer can significantly impact repository safety by compromising the integrity of buffer and leading to the formation of colloids that may facilitate the transport of radionuclides through groundwater, consequently elevating the risk of radionuclide migration. Therefore, it is very important to numerically quantify the erosion of bentonite buffer to evaluate the long-term performance of bentonite buffer, which is crucial for the safety assessment of high-level radioactive waste disposal. In this technical note, Two-region model is introduced, a proposed model to simulate the erosion behavior of bentonite based on a dynamic bentonite diffusion model, and quantitative evaluation is conducted for the bentonite buffer erosion with this model.

• Nuclear Engineering and Technology
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• v.31 no.6
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• pp.39-50
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• 1999

The physicochemical, mineralogical, hydraulic, swelling and mechanical properties of a domestic bentonite for use as the buffer material in a high-level waste repository have been measured. The bentonite is identified to be a Ca-bentonite, and the hydraulic conductivity of the compacted bentonite with the dry density higher than 1.4 Mg/㎥ is lower than 10$^{-11}$ m/s When the dry densities are 1.4 to 1.8 Mg/㎥, the swelling pressures are in the range of 6.6 to 143.5 kg/$\textrm{cm}^2$. The unconfined compressive strength is about 94 kg/$\textrm{cm}^2$, and the coefficient of volume change and the coefficient of consolidation are in the range of 0.O0249 to 0.02142 $m^2$/MN and 0.018 to 0.115$m^2$/year, respectively.

• Nuclear Engineering and Technology
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• v.55 no.4
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• pp.1495-1506
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• 2023

For the safe disposal of high-level radioactive waste using Engineered Barrier Systems (EBS), bentonite buffer is used by its high swelling capability and low hydraulic conductivity. When the bentonite buffer is contacted to heated pore water containing ions by radioactive decay, chemical alterations of minerals such as illitization reaction occur. Illitization of bentonite indicates the alteration of expandable smectite into non-expandable illite, which threatens the stability and integrity of EBS. This study intends to provide a thorough review on the information underlying in the illitization of bentonite, by covering basic clay mineralogy, smectite expansion, mechanisms and observation of illitization, and illitization in EBS. Since understanding of smectite illitization is crucial for securing the safety and integrity of nuclear waste disposal systems using bentonite buffer, this thorough review study is expected to provide essential and concise information for the preventive EBS design.

• Tunnel and Underground Space
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• v.20 no.4
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• pp.284-291
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• 2010

In the present design concept of a high-level waste repository, the bentonite and bentonite-sand mixture are considered as the buffer and backfill material. For the Kyungju bentonite which is a candidate material, the thermal conductivities of compacted bentonite and bentonite-sand mixture were measured. A correlation has been proposed to predict the thermal conductivity of the Kyungju bentonite and the bentonite-sand mixture as a function of the dry density, the water content and the sand fraction. The proposed correlation can predict the thermal conductivity with a difference less than 10% under the experimental conditions.

• Nuclear Engineering and Technology
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• v.31 no.2
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• pp.139-150
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• 1999

The swelling pressure of a potential buffer material was measured and the effect of dry density, bentonite content and initial water content on the swelling pressure was investigated to provide the information for the selection of buffer material in a high-level waste repository. Swelling tests were carried out according to Box-Behnken's experimental design. Measured swelling pressures were in the wide range of 0.7 Kg/$\textrm{cm}^2$ to 190.2 Kg/$\textrm{cm}^2$ under given experimental conditions. Based upon the experimental data, a 3-factor polynomial swelling model was suggested to analyze the effect of dry density, bentonite content and initial water content on the swelling pressure The swelling pressure increased with an increase in the dry density and bentonite content, while it decreased with increasing the initial water content and, beyond about 12 wt.% of the initial water content, levelled off to nearly constant value.