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Catalytic Performance for the Production of Synthetic Natural Gas (SNG) on the Commercial Catalyst in Low Hydrogen Concentration; Influence of Steam and CO2 (낮은 수소농도에서 합성천연가스 생산을 위한 상업용 촉매의 반응특성; 스팀과 CO2에 대한 영향)

  • Kang, Suk-Hwan;Kim, Jin-Ho;Kim, Hyo-Sik;Ryu, Jae-Hong;Jeong, Ki-Jin;Yoo, Young-Don;Kim, Kwang-Jun
    • Clean Technology
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    • v.20 no.1
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    • pp.57-63
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    • 2014
  • In this work, we performed the methanation with steam and synthesis gas of a low $H_2/CO$ ratio to develop a process for producing SNG (synthetic natural gas). In this experiment conditions, the water gas shift reaction and the methanation reaction take place at the same time, and insufficient supply of steam might cause the deactivation of the catalyst. Therefore, the reaction characteristics with the amount of steam was performed, and the methanation on syngas containing $CO_2$ of the high concentration were studied. As a result, the temperature in the catalyst bed decreased by the supply of steam, and the methanation and the water gas shift reaction occurred at the same time. Although methane yield slightly decreased at the methanation using syngas containing $CO_2$ of the high concentration, the long-term operation (1,000 h) in the experimental conditions of this study indicates that this condition is suitable for the new commercial scale SNG process.

An Experimental Study on the Devolatilization Kinetics of Ashless coal in Fixed and Entrained Conditions (초청정 석탄의 탈휘발 반응률에 관한 실험적 연구)

  • Yu, Da-Yeon;Lee, Byoung-Hwa;Song, Ju-Hun;Lee, Si-Hyun;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.10
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    • pp.997-1003
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    • 2011
  • In order to investigate devolatilization characteristics for ashless coal with relatively low ash content and high heating value, an experiment was performed in different bed configurations of TGA and DTF(Drop Tube Furnace) at atmospheric pressure condition. The heating rate was $10^{\circ}C$/min up to $950^{\circ}C$ in TGA, while the temperatures of DTF varied from 500 to $1300^{\circ}C$ in step of $200^{\circ}C$. A weight loss and particle temperature were obtained to determine devolatilization kinetics. The kinetic parameters including an activation energy and pre-exponential factor for ashless coal were obtained using Coats-Redfern method in TGA and single step method in DTF. Furthermore, the devolatilization kinetics of the ashless coal were compared with the results of different kinds of conventional coal such as sub-bituminous and bituminous. The results show that the activation energy of devolatilazation for ashless coal is lower than those of others in fixed and entrained conditions.

Study on Pyrolysis Characteristics for Upgrading of Bitumen-Like Heavy Oil Contained in Indonesian Resources (인도네시아산 자원 내에 포함된 역청성 오일의 경질화를 위한 열분해 특성에 관한 연구)

  • Jang, Jung Hee;Han, Gi Bo;Park, Cheon-kyu;Jeon, Cheol-Hwan;Kim, Jae-Kon;Kwak, Hyun
    • Clean Technology
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    • v.22 no.4
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    • pp.292-298
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    • 2016
  • In this study, the pyrolysis process was carried out in order to upgrade of heavy oil contained in the resources from Indonesia. In order to investigate the composition and basic properties of the heavy oil contained in the resources, the various analytical methods was used and then the TGA (thermogravimetric) method was especially used for the thermal degradation characteristics of heavy oil in the pyrolysis. From the results obtained from the various analytical methods, the reaction conditions such as the reaction temperature was collected for the pyrolysis process and the pyrolysis using the resources containing the heavy oil was conducted using the fixed-bed reactor under the various reaction conditions. Consequently, We found that the content of heavy oil contained in the resources was about 35% and the conversion of heavy oil and the recovery efficiency of thermal degradation oil were about 21 and 80%, respectively.

Characteristics of Reflective Light over Red and Black Plastic Mulch, and Effect on the Quality and Yield of the Oriental Melon and Tomato (적색 비닐멀칭과 흑색 비닐멀칭의 반사광 특성과 참외와 토마토의 품질과 수량에 미치는 영향)

  • Hong, Seung-Chang;Heo, Jeong-Wook;Lee, Jeong-Taek;Kang, Kee-Kyung
    • Korean Journal of Environmental Agriculture
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    • v.30 no.4
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    • pp.414-418
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    • 2011
  • BACKGROUND: Plastic mulches widely used in raised-bed culture mainly to conserve water, control weeds and raise soil temperature. The most widely used plastic mulch colour is black. Reflective red and far-red light can affect on growth and yield of various vegetable crops. Objectives of this study were to investigate the characteristics of reflective light of black and red plastic mulches, and to evaluate the reflective red and far-red light on the quality characteristics and yield of the Oriental melon (Cucumis. Melo L.) and tomato (Lycopersicon esculentum L.). METHODS AND RESULTS: Oriental melon and tomato were cultivated over the reflective red and black plastic mulches in plastic house. Reflected red and far-red light over the red plastic mulch were 2.6 times higher than those of black plastic mulch. Red to F-Red ratio of black plastic mulch, red plastic mulch and sunlight were 1.14, 0.93 and 1.16 respectively. Intensity of reflected red and far-red light over red plastic mulch were highest at surface height of 30 cm. The higher the height of the surface decrease the intensity of far-red light. Accordingly, Red to F-Red ratio were increased. Reflective red plastic mulch increased the weight of fruit and content of sugar in Oriental melon and tomato. CONCLUSION(s): Yield of Oriental melon over reflective red plastic mulch was higher than that of black plastic mulch. These results suggested that reflected red and far-red light over the red plastic mulch affected allocation of photosynthate in growing Oriental melon.

An Experimental Study for Longitudinal Resistance of Ballast Track on Bridge (교량 상 자갈궤도의 종저항력 측정을 위한 실험 연구)

  • Min, Kyung-Hwan;Yun, Kyung-Min
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.5
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    • pp.173-178
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    • 2016
  • When a ballast track of a high-speed train is constructed on a bridge, the displacement of the bridge decks can occur because they are not fixed to the rails. Moreover, relative displacements occur between the bridge and rails caused by temperature changes and external loads. The current longitudinal resistance criteria (UIC Code 774-3, KR C-08080) on ballast tracks with continuous welded rails (CWRs) do not take into account the longitudinal movement of the bridge and the frictional force between the ballast and slabs. In addition, the magnitude of the longitudinal resistance, k, is calculated somewhat conservatively and, (therefore?) it acts as an unfavorable element in the design of long span and continuous railway bridges. Thus, in order to replicate the actual behavior more effectively, the longitudinal resistance of CWRs should take into account the additional rigidity between the slab and track. In this study, the longitudinal resistances of the ballasted track on the bridge were analyzed by carrying out an experimental study with a test setup designed to simulate the deck and bed track. In the test results, the maximum longitudinal resistances of the tests were similar to the resistances of the current codes, however, the measured longitudinal stiffness designed to limit the displacement of the tests were much smaller in comparison with the longitudinal stiffness on the codes.

Stratigraphy, Lithology and Diagenetic Mineral Facies of the Tertiary Yeonil Group (제 3기 연일층군의 층서, 암상 및 속성 광물상)

  • Noh Jin Hwan
    • The Korean Journal of Petroleum Geology
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    • v.2 no.2 s.3
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    • pp.91-99
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    • 1994
  • In the Heunghae area, genetic relationships among sedimentary facies, lithology, stratigraphy and diagenetic mineral facies of the Yeonil Group, are discussed. Conglomerate and sandstone of lower to middle parts of the Yeonil Group contain considerable amounts of volcaniclastic sediments, which were derived from the Tertiary volcanics exposed in the western margins of the sedimentary basin. A new stratigraphic division of the Yeonil Group into the Chunbuk and Pohang Formations is proposed on the basis of sedimentary facies, lithologic characteristics including volcaniclastic feature, and the presence of a key bed of siliceous mudstone overlying the Chunbuk Formation. Diagenetic mineral facies largely depend on the lithology and composition of sediments. Heulandite, smectite, calcite, and opal-CT are commonly found as diagenetic minerals in the Yeonil Group. Among these authigenic minerals, heulandite occurs as the coarse- grained main cement in conglomerates and sandstones of the Chunbuk Formation. Formation of the zeolite cement is favored by partial volcaniclastic lithology of the Chunbuk Formation. Smectite composition and diagenetic mineral facies such as heulandite and opal-CT may reflect that the Yeoil Group has undergone a shallow rial temperature ranging $40{\~}60^{\circ}C$.

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Nutrients and Suspended Organic Particulates in the Estuary of NakDong River (낙동강 하구수역의 영양염류와 유기현탁물질)

  • Choe, Sang;Chung Tai Wha
    • 한국해양학회지
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    • v.7 no.1
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    • pp.1-14
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    • 1972
  • Seasonal changes in nutrients and suspended organic particulates were measured in the estuary of Nak-dong River in relation to the black laver bed. Monthly measurements of water temperature, pH, dissolved oxygen, nutrients ( $NH_4$-N, $NO_2$-N, $NO_3$\-N, $PO_4$-P and $SiO_2$-Si) and organic suspended particulates (organic carbon and nitrogen) were determined at five stations from February through December, 1970. PH varied 7.6-8.4 with an average of 8.0, and percent saturation of dissolved oxygen were 71-147% with an average of 100.8%. Studies gave evidence that Nak-dong River estuary is strongly enriched with nutrients. Concentrations of nutrients were: 0.13-12.54 ${\mu}g$-atoms/${\iota}$ (averaging 1.63 ${\mu}g$-atoms/${\iota}$) for $NH_4-N$, 0.12-2.09 ${\mu}g$-atoms/${\iota}$ (averaging 0.71 ${\mu}g$-atoms/${\iota}$) for $NO_2-N$, 3.46-56.79 ${\mu}g$-atoms/${\iota}$ (averaging 21.54 ${\mu}g$-atoms/${\iota}$) for $NO_3$-N, 4.04-57.90 ${\mu}g$-atoms/${\iota}$ (averaging 23.79 ${\mu}g$-atoms/${\iota}$) for total soluble nitrogen, 0.18-5.05 ${\mu}g$-atoms/${\iota}$ (averaging 0.96 ${\mu}g$-atoms/${\iota}$) for $PO_4$-P, and 18.33-133.29 ${\mu}g$-atoms/${\iota}$ (averaging 71.57 ${\mu}g$-atoms/${\iota}$) for $SiO_2$-Si, respectively. These nutrient levels were considerably higher compare with other productive laver beds of Wan do and Pyung-il Do in Korea or Ise Bay in Japan. Concentrations of suspended organic particulates varied 55-648 ${\mu}g/{\iota}$ (averaging 392 ${\mu}g/{\iota}$) with organic carbon, 30-155 ${\mu}g/{\iota}$ (averaging 92 ${\mu}g/{\iota}$) with organic nitrogen, and its carbon-nitrogen ratios were varied within 1.5-8.4 with an average of 4.6.

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Production of Bio-Carbon from Unused Biomass through CO2 Activation: Removal Characteristics of Formaldehyde and Acetaldehyde (미이용 바이오매스의 이산화탄소 활성화를 통한 바이오카본 생산: 포름알데하이드 및 아세트알데하이드 제거 특성)

  • Kim, JongSu;Choi, SeukCheun;Lee, Uendo;Park, EunSeuk;Jeong, Soohwa
    • Clean Technology
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    • v.27 no.4
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    • pp.325-331
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    • 2021
  • In this study, bio-carbons were produced by activation process from unused biomass (Grade 3 wood pellet and spent coffee grounds) to determine the removal performance of formaldehyde and acetaldehyde. The activation experiments were conducted in a fixed bed reactor using CO2 as an activation agent. The temperature of the activation reactor and input of CO2 were 900 ℃ and 1 L min-1 for all the experiments. The maximum BET surface area of about 788 m2 g-1 was obtained for bio-carbon produced from Grade 1 wood pellet, whereas about 544 m2 g-1 was achieved with bio-carbon produced from spent coffee grounds. In all the experiments, the bio-carbons produced were mainly found to have micro-porous nature. A lower ash amount in raw material was favored for the high surface area of bio-carbons. In the removal test of formaldehyde and acetaldehyde, the bio-carbon produced from spent coffee grounds showed excellent adsorption performance compared with woody biomass (Grade 1 wood pellet and Grade 3 wood pellet). In addition, the comparative experiment of commercial impregnated activated carbon and bio-carbon produced from spent coffee grounds was conducted. In terms of formaldehyde removal performance, the commercial impregnated bio-carbon was excellent, while bio-carbon produced from spent coffee grounds was excellent in acetaldehyde removal.

Characteristics of RDF Char Combustion in a Bubbling Fluidized Bed (기포 유동층 내에서 RDF 촤의 연소 특성)

  • Kang, Seong-Wan;Kwak, Yeon-Ho;Cheon, Kyoung-Ho;Park, Sung Hoon;Jeon, Jong-Ki;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.429-432
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    • 2011
  • The feasibility of applications of the char obtained from a gasification process of municipal-waste refuse derived fuel (RDF) as an auxiliary fuel was evaluated by combustion experiments. The higher heating value of the RDF char was 3000~4000 kcal/kg and its chlorine content was below the standard requirement demonstrating its potential as an auxiliary fuel. In the combustion exhaust gas, the maximum $NO_x$ and $SO_2$ concentrations were 240 ppm and 223 ppm, respectively. If an aftertreatment is applied, it is possible to control their concentrations low enough to meet the air pollutant emission standard. The HCl concentration was relatively high indicating that a care should be taken for HCl emission from the combustion of RDF. Based on the temperature distribution within the reactor, the concentration change of $O_2$ and $CO_2$, and the amount and the loss on ignition of solid residue, it was inferred that the combustion reaction was the most reliable when the excess air ratio of 1.3 was used.

Analysis and Improvement Plan of Cultivation and Postharvest Management Status of Cut Chrysanthemum Farms in Korea (국내 절화국화 재배농가의 재배와 수확 후 관리현황 분석 및 개선 방안)

  • Roh, Yong Seung;Yoo, Yong Kweon
    • FLOWER RESEARCH JOURNAL
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    • v.26 no.4
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    • pp.187-194
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    • 2018
  • This study was conducted to investigate the facilities, cultivation, postharvest management, and distribution status of 27 cut chrysanthemum farms in Korea. The 60% of farms have cultivated the cut chrysanthemum using soil fertigation system in the PE plastic house. In Jeonnam and Busan provinces, Standard type of chrysanthemum was cultivated mainly than spray type of chrysanthemumJeoas. Most farms have been producing the rooted cuttings by plug system using cuttings self-propagated or purchased from the company, but farms in Jeonnam have been planting cuttings directly on cultivation bed. And the 66.6% of cut chrysanthemum farms have been pretreating with dipping in hot water or tap water after harvesting. Precooling was not performed on 70.4% of the farms, and precooling farms have been mainly conducted at temperature of $2-4^{\circ}C$. After harvesting, 70.4% of the farms stored the cut flowers at $2-4^{\circ}C$ for more than 48 hours to control the distribution volume. Cut chrysanthemum was graded mainly by individuals before distribution, and some export farmers have been conducting the cooperative grading. In distribution, all farms have distributed the cut flowers to the domestic markets, and 44.4% of these farms have been also exporting. The 63.0% of farms distributed to domestic market have been trading with flower auction sites.