• 전기화학회지
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• 제8권4호
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• pp.168-171
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• 2005

The electrochemical properties of $LiFePO_4$ as a cathode for Li-ion batteries were improved by incorporating conductive carbon into the $LiFePO_4$. X-ray diffraction analysis and SEM observations revealed that the carbon-coated $LiFePO_4$ consisted of fine single crystalline particles, which were smaller than the bare $LiFePO_4$. The electrochemical performance of the carbon-coated $LiFePO_4$ was tested under various conditions. The carbon-coated $LiFePO_4$ showed much better performance in terms of the discharge capacity and cycling stability than the bare $LiFePO_4$. The improved electrochemical performances were found to be attributed to the reduced particle size and enhanced electrical conductivity of the $LiFePO_4$ by the carbon.

• 한국재료학회지
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• 제28권6호
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• pp.337-342
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• 2018

Using a high pressure homonizer, we report on the electrochemical performance of $Li_4Ti_5O_{12}(LTO)$ particles manufactured as anode active material for lithium ion battery. High-pressure synthesis processing is performed under conditions in which the mole fraction of Li/Ti is 0.9, the synthesis pressure is 2,000 bar and the numbers of passings-through are 5, 7 and 10. The observed X-ray diffraction patterns show that pure LTO is manufactured when the number of passings-through is 10. It is found from scanning electron microscopy analysis that the average size of synthesized particles decreases as the number of passings-through increases. $LiCoO_2-based$ active cathode materials are used to fabricate several coin half/full cells and their battery characteristics such as lifetime, rate capability and charge transfer resistance are then estimated, revealing quite good electrochemical performance of the LTO particles as an effective anode active material for lithium secondary batteries.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2015년도 제46회 하계학술대회
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• pp.652-654
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• 2015

Integrated switched reluctance motor drive as an electric vehicle battery charger is presented in this paper. The SRM, which is used as the traction power in the driving mode, is used in the charge circuit to improve the power factor of charging system. The charging circuit can share the power switches of the asymmetric converter and phase windings of SRM to charge the battery, and can reduce the size and cost of the system in the plug-in system. To keep the rotor at standstill, zero torque control method is proposed. Since the inductances of the SRM windings are not same at any stop position, the charger controller controls the reference current to satisfy the total charging current with PFC and zero torque condition. A novel cubic equation method is proposed as a current reference distributor of the charging controller. Simulations are performed by MATLAB software and results satisfy the Effectiveness of proposed battery charging system.

• Journal of Electrochemical Science and Technology
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• 제5권3호
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• pp.87-93
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• 2014

The fluorine-substituted $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode materials were synthesized by using the transition metal precursor, $LiOH{\cdot}H_2O$ and LiF. This was to facilitate the movement of lithium ions by forming more compact SEI layer and to reduce the dissolution of transition metals. The $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode material was sphere-shaped and each secondary particle had $10{\sim}15{\mu}m$ in size. The fluorine-substituted cathodes initially delivered low discharge capacity, but it gradually increased until 50th charge-discharge cycles. These results indicated that fluorine substitution gave positive effects on the structural stabilization and resistance reduction in materials.

• 전력전자학회논문지
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• 제17권1호
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• pp.77-84
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• 2012

This paper describes the process of optimal resonant frequency design with full-bridge series-loaded resonant dc-dc converter in a high efficiency 3.3 kW on-board battery charger application for Electric Vehicles and Plug-in Hybrid Electric Vehicles. The optimal range of resonant frequency and switching frequency used for ZVS are determined by considering trade-off between loss of switching devices and resonant network with size of passive/magnetic devices. In addition, it is defined charging region of battery, the load of on-board charger, as the area of load by deliberating the characteristic of resonant. It is verified the designed frequency band by reflecting the defined area on resonant frequency.

• International Journal of Automotive Technology
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• 제8권5호
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• pp.651-658
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• 2007

This paper presents a new type of fuzzy logic-based power control strategy for fuel cell hybrid electric vehicles designed to improve their fuel economy while maintaining the battery's state of charge. Since fuel cell systems have inherent limitations, such as a slow response time and low fuel efficiency, especially in the low power region, a battery system is typically used to assist them. To maximize the advantages of this hybrid type of configuration, a power distribution control strategy is required for the two power sources: the fuel cell system and the battery system. The required fuel cell power is procured using fuzzy rules based on the vehicle driving status and the battery status. In order to show the validity and effectiveness of the proposed power control strategy, simulations are performed using a mid-size vehicle for three types of standard drive cycle. First, the fuzzy logic-based power control strategy is shown to improves the fuel economy compared with the static power control strategy. Second, the robustness of the proposed power control strategy is verified against several variations in system parameters.

• Journal of Electrical Engineering and Technology
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• 제6권5호
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• pp.671-676
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• 2011

A multilayer square-type piezoelectric transformer with a hole at the center was investigated in this paper. Temperature distribution at the center was improved by using this construction, therefore increasing input voltage and output power. This model was simulated and investigated successfully by applying a finite element method (FEM) in ATILA software. An optimized structure was then fabricated, examined, and compared to the simulation results. Electrical characteristics, including output voltage and output power, were measured at different load resistances. The temperature distribution was also monitored using an infrared camera. The piezoelectric transformer operated at first radial vibration mode and a frequency area of 70 kHz. The 16 W output power was achieved in a three-layer transformer with 96% efficiency and $20^{\circ}C$ temperature rise from room temperature under 115 V driving voltage, 100 ${\Omega}$ matching load, $28{\times}28{\times}1.8mm$ size, and 2 mm hole diameter. With these square-type multilayer piezoelectric transformers, the temperature was concentrated around the hole and lower than in piezoelectric transformers without a hole.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2014년도 전력전자학술대회 논문집
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• pp.335-336
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• 2014

This paper investigates the design of coupled inductor for minimum inductor current ripple in rapid traction battery charger systems. Based on the general circuit model of coupled inductor together with the operating principles of dc-dc converter, the relationship between the ripple size of inductor current and the coupling factor is derived under the different duty ratio. The optimal coupling factor which corresponds to a minimum inductor ripple current becomes -1, i.e. a complete inverse coupling without leakage inductance, as the steady-state duty ratio operating point approaches 0.5. In an opposite manner, the optimal coupling factor value of zero, i.e. zero mutual inductance, is required when the steady-state duty ratio operating point approaches either zero or one. Coupled inductors having optimal coupling factor can minimize the ripple current of inductor and battery current resulting in a reliable and efficient operation of battery chargers.

• 한국수소및신에너지학회논문집
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• 제8권2호
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• pp.79-90
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• 1997

Extensive work has been done on investigating the inner cell pressure characteristics of sealed type Ni-MH battery in which Zr-Ti-Mn-V-Ni alloy is used as anode. The inner cell pressure of this type Ni-MH battery much more increases with the charge/discharge cycling than that of the other type Ni-MH battery where commercialized $AB_5$ type alloy is used as anode. The increase of inner cell pressure in the sealed type Ni/MH battery using Zr-Ti-Mn-V-Ni alloy system is mainly due to the accumulation of oxygen gas during charge/discharge cycling. The accumulation of oxygen gas arises mainly due to the low rate of oxygen recombination on the MH electrode surface during charge/discharge cycling. The difference of oxygen recombination rate between $AB_5$ type electrode and Zr-Ti-Mn-V-Ni electrode is caused by the difference of electrode reaction surface area resulting from different particle size after their activation and the difference of surface catalytic activity for oxygen recombination reaction, respectively. After EIS analysis, it is identified that the surface catalytic activity affects much more dominantly on the oxygen recombination reaction than the reaction surface area does. In order to suppress the inner cell pressure of Ni-MH battery where Zr-Ti-Mn-V-Ni is used as anode, it is suggested that the surface catalytic activity for oxygen recombination should be improved.

• 전기화학회지
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• 제5권2호
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• pp.74-78
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• 2002

아연공기전지는 공기중의 산소를 사용하므로 cathode의 재활용이 가능하다는 장점이 있으며 아연의 이론용량이 820(mAh/g)으로 상당히 높다. 그러나, 아연공기전지는 cathodf치 기공이 너무 작으면 외부로부터 유입되는 산소량이 부족하여 전지의 방전전압이 낮아지는 결과를 초래하게 되며 cathode에 포함되어 있는 도전재의 함량에 따라 저항 및 기공율에 많은 변화를 보이고 있다. 이에 본 연구에서는 전지의 용량, 출력특성, 방전전압, DC저항, ASTM에 의한 기공율 측정을 통해 도전재의 종류 및 함량이 아연공기전지에 미치는 영향을 연구하였으며, Super P의 도전재를 $5wt\%$ 첨가하였을 때 가장 우수한 전지특성을 얻을 수 있었다.