• Journal of the Korean Electrochemical Society
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• v.8 no.4
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• pp.168-171
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• 2005

The electrochemical properties of $LiFePO_4$ as a cathode for Li-ion batteries were improved by incorporating conductive carbon into the $LiFePO_4$. X-ray diffraction analysis and SEM observations revealed that the carbon-coated $LiFePO_4$ consisted of fine single crystalline particles, which were smaller than the bare $LiFePO_4$. The electrochemical performance of the carbon-coated $LiFePO_4$ was tested under various conditions. The carbon-coated $LiFePO_4$ showed much better performance in terms of the discharge capacity and cycling stability than the bare $LiFePO_4$. The improved electrochemical performances were found to be attributed to the reduced particle size and enhanced electrical conductivity of the $LiFePO_4$ by the carbon.

• Korean Journal of Materials Research
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• v.28 no.6
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• pp.337-342
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• 2018

Using a high pressure homonizer, we report on the electrochemical performance of $Li_4Ti_5O_{12}(LTO)$ particles manufactured as anode active material for lithium ion battery. High-pressure synthesis processing is performed under conditions in which the mole fraction of Li/Ti is 0.9, the synthesis pressure is 2,000 bar and the numbers of passings-through are 5, 7 and 10. The observed X-ray diffraction patterns show that pure LTO is manufactured when the number of passings-through is 10. It is found from scanning electron microscopy analysis that the average size of synthesized particles decreases as the number of passings-through increases. $LiCoO_2-based$ active cathode materials are used to fabricate several coin half/full cells and their battery characteristics such as lifetime, rate capability and charge transfer resistance are then estimated, revealing quite good electrochemical performance of the LTO particles as an effective anode active material for lithium secondary batteries.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.652-654
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• 2015

Integrated switched reluctance motor drive as an electric vehicle battery charger is presented in this paper. The SRM, which is used as the traction power in the driving mode, is used in the charge circuit to improve the power factor of charging system. The charging circuit can share the power switches of the asymmetric converter and phase windings of SRM to charge the battery, and can reduce the size and cost of the system in the plug-in system. To keep the rotor at standstill, zero torque control method is proposed. Since the inductances of the SRM windings are not same at any stop position, the charger controller controls the reference current to satisfy the total charging current with PFC and zero torque condition. A novel cubic equation method is proposed as a current reference distributor of the charging controller. Simulations are performed by MATLAB software and results satisfy the Effectiveness of proposed battery charging system.

• Journal of Electrochemical Science and Technology
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• v.5 no.3
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• pp.87-93
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• 2014

The fluorine-substituted $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode materials were synthesized by using the transition metal precursor, $LiOH{\cdot}H_2O$ and LiF. This was to facilitate the movement of lithium ions by forming more compact SEI layer and to reduce the dissolution of transition metals. The $0.3Li_2MnO_3{\cdot}0.7Li[Mn_{0.60}Ni_{0.25}Co_{0.15}]O_{2-x}F_x$ cathode material was sphere-shaped and each secondary particle had $10{\sim}15{\mu}m$ in size. The fluorine-substituted cathodes initially delivered low discharge capacity, but it gradually increased until 50th charge-discharge cycles. These results indicated that fluorine substitution gave positive effects on the structural stabilization and resistance reduction in materials.

• The Transactions of the Korean Institute of Power Electronics
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• v.17 no.1
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• pp.77-84
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• 2012

This paper describes the process of optimal resonant frequency design with full-bridge series-loaded resonant dc-dc converter in a high efficiency 3.3 kW on-board battery charger application for Electric Vehicles and Plug-in Hybrid Electric Vehicles. The optimal range of resonant frequency and switching frequency used for ZVS are determined by considering trade-off between loss of switching devices and resonant network with size of passive/magnetic devices. In addition, it is defined charging region of battery, the load of on-board charger, as the area of load by deliberating the characteristic of resonant. It is verified the designed frequency band by reflecting the defined area on resonant frequency.

• International Journal of Automotive Technology
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• v.8 no.5
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• pp.651-658
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• 2007

This paper presents a new type of fuzzy logic-based power control strategy for fuel cell hybrid electric vehicles designed to improve their fuel economy while maintaining the battery's state of charge. Since fuel cell systems have inherent limitations, such as a slow response time and low fuel efficiency, especially in the low power region, a battery system is typically used to assist them. To maximize the advantages of this hybrid type of configuration, a power distribution control strategy is required for the two power sources: the fuel cell system and the battery system. The required fuel cell power is procured using fuzzy rules based on the vehicle driving status and the battery status. In order to show the validity and effectiveness of the proposed power control strategy, simulations are performed using a mid-size vehicle for three types of standard drive cycle. First, the fuzzy logic-based power control strategy is shown to improves the fuel economy compared with the static power control strategy. Second, the robustness of the proposed power control strategy is verified against several variations in system parameters.

• Journal of Electrical Engineering and Technology
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• v.6 no.5
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• pp.671-676
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• 2011

A multilayer square-type piezoelectric transformer with a hole at the center was investigated in this paper. Temperature distribution at the center was improved by using this construction, therefore increasing input voltage and output power. This model was simulated and investigated successfully by applying a finite element method (FEM) in ATILA software. An optimized structure was then fabricated, examined, and compared to the simulation results. Electrical characteristics, including output voltage and output power, were measured at different load resistances. The temperature distribution was also monitored using an infrared camera. The piezoelectric transformer operated at first radial vibration mode and a frequency area of 70 kHz. The 16 W output power was achieved in a three-layer transformer with 96% efficiency and $20^{\circ}C$ temperature rise from room temperature under 115 V driving voltage, 100 ${\Omega}$ matching load, $28{\times}28{\times}1.8mm$ size, and 2 mm hole diameter. With these square-type multilayer piezoelectric transformers, the temperature was concentrated around the hole and lower than in piezoelectric transformers without a hole.

• Proceedings of the KIPE Conference
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• 2014.07a
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• pp.335-336
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• 2014

This paper investigates the design of coupled inductor for minimum inductor current ripple in rapid traction battery charger systems. Based on the general circuit model of coupled inductor together with the operating principles of dc-dc converter, the relationship between the ripple size of inductor current and the coupling factor is derived under the different duty ratio. The optimal coupling factor which corresponds to a minimum inductor ripple current becomes -1, i.e. a complete inverse coupling without leakage inductance, as the steady-state duty ratio operating point approaches 0.5. In an opposite manner, the optimal coupling factor value of zero, i.e. zero mutual inductance, is required when the steady-state duty ratio operating point approaches either zero or one. Coupled inductors having optimal coupling factor can minimize the ripple current of inductor and battery current resulting in a reliable and efficient operation of battery chargers.

• Transactions of the Korean hydrogen and new energy society
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• v.8 no.2
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• pp.79-90
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• 1997

Extensive work has been done on investigating the inner cell pressure characteristics of sealed type Ni-MH battery in which Zr-Ti-Mn-V-Ni alloy is used as anode. The inner cell pressure of this type Ni-MH battery much more increases with the charge/discharge cycling than that of the other type Ni-MH battery where commercialized $AB_5$ type alloy is used as anode. The increase of inner cell pressure in the sealed type Ni/MH battery using Zr-Ti-Mn-V-Ni alloy system is mainly due to the accumulation of oxygen gas during charge/discharge cycling. The accumulation of oxygen gas arises mainly due to the low rate of oxygen recombination on the MH electrode surface during charge/discharge cycling. The difference of oxygen recombination rate between $AB_5$ type electrode and Zr-Ti-Mn-V-Ni electrode is caused by the difference of electrode reaction surface area resulting from different particle size after their activation and the difference of surface catalytic activity for oxygen recombination reaction, respectively. After EIS analysis, it is identified that the surface catalytic activity affects much more dominantly on the oxygen recombination reaction than the reaction surface area does. In order to suppress the inner cell pressure of Ni-MH battery where Zr-Ti-Mn-V-Ni is used as anode, it is suggested that the surface catalytic activity for oxygen recombination should be improved.

• Journal of the Korean Electrochemical Society
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• v.5 no.2
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• pp.74-78
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• 2002

Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820 mAh/g. However, if the pore size in cathode is small then the flow rate of air decreased, and as a result of that discharge voltage of batteries becomes low. We focused on resistance and porosity of cathode. So we studied the effects of conducting agents to zinc air batteries performance, capacity, power density, average discharge voltage, resistance. And we also measured porosity of cathode by the ASTM. So we have got optimum contents of conducting agent.