• Membrane Journal
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• v.29 no.3
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• pp.155-163
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• 2019

The anion exchange membrane using the blending polymer of poly(ether sulfone) and poly(phenylene sulfide sulfone) was prepared. It was confirmed by EDXS and FT-IR analysis that the prepared anion exchange membrane had the -N- as an anion exchange group. The ionic conductivity in 1 mol/L $H_2SO_4$ aqueous solution was measured. The ionic conductivity of the prepared anion exchange membrane was 0.015~0.083 S/cm, and had a high value compared with AFN and APS as a commercial anion exchange membrane. Permeabilities of the vanadium ions through the prepared anion exchange membrane were tested to evaluate the possibility as a separator in vanadium redox flow battery. Vanadium ion permeation rate in the prepared anion exchange membrane had a low value compared with Nafion 117 as a commercial cation exchange and AFN as a commercial anion exchange membrane.

• Membrane Journal
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• v.5 no.3
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• pp.109-118
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• 1995

In this study, cell resistivity and membrane resistivity were measured in Fe-Cr redox-fiow battery system using commercial ion-exchange membranes. Cell resistivity and membrane resistivity at charging periods are higher than at discharging periods. And at the same membrane the resistivity were increased with increasing SOC. The resistivity of hydrocarbon type Seiemion CMV membrane was smaller than perfluoro type Nafion 117 and Nafion 551. The cell resistivity and membrne resistivity of CMV membrane at 0 % SOC was $12.864\Omega \textrm{cm}^2$ and $8.751\Omega \textrm{cm}^2$, respectively.

• Membrane Journal
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• v.30 no.1
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• pp.21-29
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• 2020

In this study, we have established the optimum design condition of pore-filled anion-exchange membrane for all-vanadium redox flow battery (VRFB). From the experimental results, it was proven that the membrane design factors that have the greatest influence on the charge-discharge performance of VRFB are the ion exchange capacity, the porosity of substrate film, and the crosslinking degree. That is, the ohmic loss and the crossover of active materials in VRFB were shown to be determined by the above factors. In addition, two methods, i.e. reducing the ion exchange capacity at low crosslinking degree and increasing the crosslinking degree at high ion exchange capacity, were investigated in the preparation of pore-filled anion-exchange membranes. As a result, it was found that optimizing the crosslinking degree at sufficiently high ion exchange capacity is more desirable to achieving high VRFB charge-discharge performances.

• New & Renewable Energy
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• v.9 no.4
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• pp.3-12
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• 2013

This paper proposes the hybrid fuel cell system that can solve disadvantages of existing fuel cell system and ensure high reliability and high stability. The system consists of PEM fuel cell, Ni-MH battery and power management system. In this system, when the power provided from the fuel cell is higher than the load power, the extra energy may be used to charge the Ni-MH battery. When the fuel cell can not provide enough energy to the load, the shortage of energy will be supplied by the Ni-MH battery. Experimental results show that the output voltage is regulated well during load variations. Also, high system efficiency is achieved.

• Membrane Journal
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• v.27 no.5
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• pp.406-414
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• 2017

In this study, we have developed pore-filled ion-exchange membranes (PFIEMs) filled with ionomer in a thin polyethylene porous film (thickness = $25{\mu}m$) and investigated the charge-discharge characteristics of the all vanadium redox flow battery (VRFB) employing them. Especially, the degree of crosslinking and free volume of the PFIEMs were appropriately controlled to produce ion-exchange membranes exhibiting both the low membrane resistance and low vanadium permeability by mixing crosslinking agents having different molecular size. As a result, the prepared PFIEMs exhibited excellent electrochemical properties which are comparable to those of the commercial membranes. Also, it was confirmed through the experiments of vanadium ion permeability and VRFB performance evaluation that the PFIEMs showed low vanadium ion permeability and high charge-discharge efficiency in comparison with the commercial membrane despite their thin film thickness.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.6
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• pp.44-49
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• 2022

The improvement in the battery performance and life using a battery thermal management system directly affects the improvement in the performance, life, and energy efficiency of electric vehicles. Therefore, this study numerically analyzed the heat exchange processes between the coolant inside the cooling plate channel and the heat generated by the battery. The cooling performance was analyzed based on the average temperature, temperature uniformity, and the maximum and minimum temperature differences of the battery. A performance difference existed depending on the coolant inlet temperature but showed the same tendency of cooling performance according to the shape of each plate's channel. Type 1 showed the best results in terms of battery temperature uniformity, which is the most important measure of battery performance; Type 2 showed the best results in terms of the average temperature of the battery; and Type 3 showed the best results in terms of the maximum and minimum temperature differences of the battery compared with that of the other cooling plates.

• Proceedings of the KIPE Conference
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• 2013.07a
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• pp.182-183
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• 2013

In the design of the fuel cell charger, it is important to find out the suitable topology and to design the converter to guarantee the performance of the fuel cell as well as the battery. Most of the chargers developed so far have used step-down converters. However, since the small fuel cell stack can only generate a low voltage, it is required to use the step-up converter to charge the battery. In this paper, a modified non-isolated boost charger topology for the Proton Exchange Membrane Fuel Cell (PEMFC) is proposed to meet the strict ripple requirements for the battery charge and its control method by using PI controller is detailed. The feasibility of the proposed topology and its control method is then verified by the experiments.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2021.10a
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• pp.567-569
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• 2021

The power battery supply chain in China currently lacks stable cooperation and effective information exchange. The competitive pressure brings about irregular recycling channels, reducing the operation and efficiency of the power battery supply chain. Besides, some regular power battery recycling enterprises fabricate data to obtain subsidies by taking advantage of the loopholes in the relevant policies of the state on recycling subsidies. Due to the high price of recycling in the black market, some regular enterprises resell the batteries recycled through regular channels, later purchasing the batteries with no utilization value to obtain the national recycling subsidies by cheating at the same time. Fig. 3 shows the present network structure of the tradi tional Chinese power battery closed-loop supply chain

• Polymer(Korea)
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• v.34 no.2
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• pp.126-132
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• 2010

A cation-exchange nanofiber poly(vinylidene fluoride) (PVdF) membrane was prepared by a radiation-induced graft polymerization (RIGP) of sodium styrene sulfonate (NaSS) in the presence of the polymerizable access agents in methanol solution. The used polymerizable access agents include styrene, acrylic acid, and vinyl pyrrolidone. The anion-exchange nanofiber PVdF membrane was also prepared by RIGP of glycidyl methacrylate (GMA) and its subsequent chemical modification. The successful preparations of cation- and anion-exchange PVdF membranes were confirmed via SEM, XPS and thermal analysis. The content of the grafting yield, ion-exchange group, and water uptake was in the range of 30.0~32.3%, 2.81~3.01 mmol/g and 66.6~147%, respectively. The proton conductivity at 20$^{\circ}C$ was in the range of 0.020~0.053 S/cm. From the result, the prepared ionexchange PVdF membrane can be used as a separator in battery cells.

• Membrane Journal
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• v.24 no.5
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• pp.386-392
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• 2014

Two commercial membranes (porous membrane and cation exchange membrane) were evaluated as a separator in the Zn-Br redox-flow battery (ZBRFB). The performance properties of ZBRFB were test in the current density of $20mA/cm^2$. The electromotive forces (OCV at SOC 100%) of ZBRFB using SF-600 (porous membrane) and Nafion 117 (cation exchange membrane) were 1.87 V and 1.93 V, respectively. The cycle performance of ZBRFB using each membrane was evaluated during 7 cycles. The performance of ZBRFB using SF-600 membrane was 89.76%, 83.46% and 74.88% for average current efficiency, average voltage efficiency and average energy efficiency, respectively. The performance of ZBRFB using Nafion117 membrane was 97.7%, 76.33% and 74.56% for average current efficiency, average voltage efficiency and average energy efficiency, respectively.