• Bulletin of the Korean Chemical Society
• /
• v.25 no.4
• /
• pp.511-516
• /
• 2004

A Li$[Co_{0.17}Li_{0.28}Mn_{0.55}]O_2$ cathode compound was prepared by a simple combustion method. The X-ray diffraction pattern showed that this compound could be classified as ${\alpha} -NaFeO_2$ structure type with the lattice constants of a = 2.8405(9) ${\AA}$ and c = 14.228(4) ${\AA}$. According to XANES analysis, the oxidation state of Mn and Co ions in the compound were 4+ and 3+, respectively. During the first charge process, the irreversible voltage plateau at around 4.65 V was observed. The similar voltage-plateau was observed in the initial charge profile of other solid solution series between $Li_2MnO_3\;and\;LiMnO_2$ (M=Ni, Cr...). The first discharge capacity was 187 mAh/g and the second discharge capacity increased to 204 mAh/g. As the increase of cycling number, one smooth discharge profile was converted to two distinct sub-plateaus and the discharge capacity was slowly decreased. From the Co and Mn K-edge XANES spectra measured at different cyclic process, it can be concluded that irreversible transformation of phase is occurred during continuous cycling process.

• Journal of the Korean Ceramic Society
• /
• v.36 no.2
• /
• pp.172-177
• /
• 1999

Graphite and carbonaceous materials showed an excellent capability as a negative electrode in Li-ion batteries because Li-ion can be intercalated and de-intercalated reversibly within most carbonaceous materials of layered structure. Also, the electrochemical potential of Li-intercalated carbon anode is almost identical with that of Li metal. In the present study, mesocarbon microbeads(MCMB) were used as anode electrode and its properties of charge/discharge and interfacial reaction with electrolyte were studied by Potentiostat/Galvanostat test, FT-IR analysis, XRD and SEM. The passivation film of solid-state was formed as the interface between electrode and electrolyte as the cell reaction began and, once formed, became thicker with repeated charge/discharge process. Also, the relationship between the passivation film formed at the electrode interface and storage capacity was discussed.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.8
• /
• pp.2304-2308
• /
• 2010

A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.11 no.5
• /
• pp.170-175
• /
• 2003

A control algorithm is developed for highly efficient operation of auxiliary power unit (APU) that consists of a diesel engine and a directly coupled induction generator in series hybrid electric Bus (SHEB). In a series hybrid configuration the APU supplies the electric power needed for maintaining the state of charge (SOC) of the battery unit in various conditions of vehicle operation. As the rotational speed of generator does not depend on the vehicle speed, an optimized operation of engine-generator unit based on the efficiency map of each component can be achieved. The output torque of diesel engine can be controlled by the amount of fuel injection, and the power converted from mechanical to electrical energy can be adjusted by generate control unit (GCU) using the decoupling vector control of torque and flux. As for the given reference of the generating power, the multiply of speed and torque, many combinations of operating speed and torque are possible. The algorithm decides the new operating point based on the engine efficiency map and generator characteristic curve. During the transition of operating points, the speed controller saturation is avoided using variable limit and filtering of generator torque reference. A test rig and SHEB consist of a 1.5L diesel engine and a 30kw induction generator are constructed by Hyundai Motor Company.

• Journal of Electrical Engineering and Technology
• /
• v.10 no.4
• /
• pp.1492-1501
• /
• 2015

This paper analyzes the effect of voltage sag on distribution systems due to the connection of Electric Vehicles (EVs). In order to study the impact of the voltage sag on the power system, two scenarios have been selected in this paper. The distribution system and EVs are modeled using the Electro Magnetic Transients Program (EMTP). The numbers of EVs are predicted based on the number of vehicles in distribution system of Seoul. In addition, the number of EVs is set up using real-time traffic in Seoul to simulate Scenario I and II. The simulation results show that voltage sag can occur if the distribution system has more than 30% of the total number of vehicles.

• Journal of Power Electronics
• /
• v.9 no.1
• /
• pp.51-60
• /
• 2009

Hybrid Electric Vehicles (HEVs) utilize electric power as well as a mechanical engine for propulsion; therefore the performance of HEV s can be directly influenced by the characteristics of the Energy Storage System (ESS). The ESS for HEVs generally requires high power performance, long cycle life and reliability, as well as cost effectiveness. So the Hybrid Energy Storage System (HESS), which combines different kinds of storage devices, has been considered to fulfill both performance and cost requirements. To improve operating efficiency, cycle life, and cold cranking of the HESS, an advanced dynamic control regime with which pertinent storage devices in the HESS can be selectively operated based on their status was presented. Verification tests were performed to confirm the degree of improvement in energy efficiency. In this paper, an advanced HESS with improved an Battery Management System (BMS), which has optimal switching control function based on the estimated State of Charge (SOC), has been developed and verified.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.13 no.3
• /
• pp.35-40
• /
• 2005

In the present study, the influence of operating conditions on fuel economy for hybrid electric vehicle was analyzed. In order to accomplish this, vehicle speed, engine speed, battery current and voltage, SOC (state of charge),motor speed and torque, generator speed and torque, engine coolant temperature etc. were measured in real time. The tests were carried out under different driving cycles which are urban and highway cycles, KOREA CITY cycle and on-road driving, and also under various operating conditions such as different initial SOC, with or without regenerative braking etc.. Generally, conventional gasoline engines show a poor fuel economy at stop and go driving, because braking energy is wasted and the engine is operated in low thermal efficiency regions. However, in case of hybrid vehicles, higher fuel economy can be obtained because of utilizing the maximum thermal efficiency regions of engine, idling stop of engine, and regenerative braking etc..

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.713-716
• /
• 2001

In many papers, the electrochemical analysis of LiMn$_2$O$_4$shows the transition results of Mn$^{3+}$ ion. Charge ordering is accompanied by simultaneous orbital ordering due to the Jahn-Teller effect in Mnl$^{3+}$ ions. To analyze the cycle performance of LiMn$_{2-x}$Cu$_{x}$ O$_4$as the cathode of 4 V class lithium secondary batteries, XRD, TGA analysis were conducted. Although the cycle performance of the LiMn$_{2-x}$Cu$_{x}$ O$_4$was improved from pure LiMn$_2$O$_4$, the discharge capacity was significantly lower than LiCoO$_2$. In this paper, We study the Electrochemical characterization and enhanced stability of Cu-doped spinels in the LiMn$_{2-x}$Cu$_{x}$ O$_4$upon initial cycling.l cycling.

• Proceedings of the KIPE Conference
• /
• 2009.11a
• /
• pp.262-264
• /
• 2009

일반적으로, 단위 배터리간의 직/병렬 연결을 통해 구성되는 팩은 이를 구성하는 각 배터리간의 상이한 전기화학적 특성으로 인해 전압 불균형이 존재한다. 이러한 전압 불균형은 팩의 노화 및 성능을 저하시키는 원인이 된다. 이러한 전압불균형을 없애기 위해 전압과 State of Charge(SOC)를 이용한 밸런싱 회로가 폭넓게 연구되고 있다. 하지만, 이러한 연구는 대체적으로, 다른 특성을 가지는 단위 배터리로 구성되는 팩의 밸런싱 방법이다. 따라서, 동일하고 균일한 특성을 갖는 배터리들을 미리 선별하여 팩을 구성한다면, 밸런싱의 전반적인 효율증대가 기대된다. 본 논문에서는 최적의 전압 밸런싱을 위한 스크리닝(Screening)의 새로운 방법을 연구하였다. 용량과 모델 파라미터(Lumped resistance;$R_{Diff}$)를 스크리닝의 척도로 고려하였고, 전압 불균형을 최대한 줄이기 위해 용량, 모델 파라미터의 순으로 스크리닝을 진행하였다. 또한, 전압패턴인식을 이용한 판별법을 통해 제안된 스크리닝 방법을 검증하였다.

• Journal of the Korean Ceramic Society
• /
• v.40 no.1
• /
• pp.69-76
• /
• 2003

For lithium secondary microbattery anode, the tin oxide thin films with Si addition (0, 2, 6, 10, 20 ㏖%) were prepared with R.F. magnetron sputtering at substrate temperature of 30$0^{\circ}C$ and Ar:O$_2$=7:3 atmosphere. As Si addition amount increased, Si-O bonding density increased and Sn-O bonding density decreased. The addition of optimum Si amount led the decrease of Sn oxidation state so that the irreversible capacity reduced and cycle characteristic enhanced during charge-discharge test. SnO$_2$films with 6 ㏖% Si had the highest reversible capacity of 700 mAh/g after 100 cycles.