• Title/Summary/Keyword: Battery Life

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Nanoscale Characterization of a Heterostructure Interface Properties for High-Energy All-Solid-State Electrolytes (고에너지 전고체 전해질을 위한 나노스케일 이종구조 계면 특성)

  • Sung Won Hwang
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.28-32
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    • 2023
  • Recently, the use of stable lithium nanostructures as substrates and electrodes for secondary batteries can be a fundamental alternative to the development of next-generation system semiconductor devices. However, lithium structures pose safety concerns by severely limiting battery life due to the growth of Li dendrites during rapid charge/discharge cycles. Also, enabling long cyclability of high-voltage oxide cathodes is a persistent challenge for all-solid-state batteries, largely because of their poor interfacial stabilities against oxide solid electrolytes. For the development of next-generation system semiconductor devices, solid electrolyte nanostructures, which are used in high-density micro-energy storage devices and avoid the instability of liquid electrolytes, can be promising alternatives for next-generation batteries. Nevertheless, poor lithium ion conductivity and structural defects at room temperature have been pointed out as limitations. In this study, a low-dimensional Graphene Oxide (GO) structure was applied to demonstrate stable operation characteristics based on Li+ ion conductivity and excellent electrochemical performance. The low-dimensional structure of GO-based solid electrolytes can provide an important strategy for stable scalable solid-state power system semiconductor applications at room temperature. The device using uncoated bare NCA delivers a low capacity of 89 mA h g-1, while the cell using GO-coated NCA delivers a high capacity of 158 mA h g−1 and a low polarization. A full Li GO-based device was fabricated to demonstrate the practicality of the modified Li structure using the Li-GO heterointerface. This study promises that the lowdimensional structure of Li-GO can be an effective approach for the stabilization of solid-state power system semiconductor architectures.

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Electrochemical Properties of Sub-micron Size Si Anode Materials Distributed by Wet Sedimentation Method (습식 분급으로 입도 조절된 서브 마이크론 크기의 Si 음극활물질의 전기화학적 특성 분석)

  • Jin-Seong Seo;Hyun-Su Kim;Byung-Ki Na
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.39-44
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    • 2023
  • In this study, the particle size of Si polycrystals was controlled through wet-sedimentation method, and changes in the capacity and cyclic characteristics of the Si anode material according to the particle size were observed. After wet-sedimentation of Si particles pulverized by a vibration mill, the non-uniform particle distribution of Si was uniformly controlled. The d50 of a sample in which Si was sedimented for 24 hours decreased to 0.50 ㎛. As a result of the electrochemical characteristic analysis, the Rct value representing the resistance in the electrode was significantly reduced due to the decrease in particle size. The unclassified Si sample exhibited a discharge capacity of 2,869 mAh/g in the first cycle, and decreased to 85.7 mAh/g after 100 cycles. The sample in which Si was classified for 24 hours showed a capacity of 3,394 mAh/g initially, and maintained a capacity of 1,726 mAh/g after 100 cycles. As the size of the Si particles decreased, the discharge capacity increased and the cycle life was also increased.

Mobile Proxy Architecture and Its Practice: Mobile Multimedia Collaboration System (모바일 기기를 위한 프록시 구조와 모바일 멀티미디어 협업 시스템 적용예)

  • Oh, Sang-Yoon
    • Journal of the Korea Society of Computer and Information
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    • v.14 no.7
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    • pp.123-132
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    • 2009
  • The perforrnance and portability of mobile applications can be greatly increased by adopting proxy modiles which exists between the conventional system and the device. When mobile devices collaborate with the conventional computers, there are problems to address: a battery life problem, limited input and output methods, and intermittent wireless connection. Those issues are magnified in the multimedia collaboration environment since it works in a real-time condition and the size of the message in the system is big in many cases. Additionally, because multimedia collaboration system softwares are too heavy and complex for mobile devices, it is veη hard to integrate them with conventional systems. In this paper, we describe our design and its implementation of a novel approach to map events (i.e. messages) using a proxy for mobile applications. We adopt a proxy to provide a content adaptation (i.e. transcoding) where the message contents are customized. Also, we design a mobile version publish/subscribe system to provide communication service for mobile device in loosely coupled and flexible manner. We present our empirical results which show that our design can be efficiently implemented and integrated with a conventional multimedia collaboration system.

The Electrochemical Properties of Sponge Type S@ZIF67/rGO as the Cathode Material for Lithium Sulfur Batteries (리튬 황 전지용 Sponge 형태의 S@ZIF 67/rGO 양극재의 전기화학 특성 분석)

  • Chaelin Seo;Sunghoon Kim;Wook Ahn
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.47-54
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    • 2024
  • In this study, ZIF67/rGO was used to minimize the battery life degradation due to the insulating properties of sulfur and the elution of lithium polysulfide. ZIF67 wrapped in rGO creates more space within the carbon sponge and can hold a large amount of sulfur. The sulfur@ZIF67/rGO composite was synthesized and prepared as a sponge to enhance the sulfur retention capacity. The result showed a high initial capacity, with a value of about 1093 mAh g-1 and a capacity retention rate of 84% after 100 cycles. The high interaction with sulfur through the complexation of cobalt and carbon confirmed that ZIF67/rGO exhibits high performance as a carrier for sulfur, the anode active material of lithium-sulfur batteries, and the high initial capacity and improved capacity retention rate were confirmed.

Public Electric Car Charging Locations Based on Car Navigation Data in Seoul (네비게이션 데이터를 바탕으로 한 서울시의 공공 전기차 충전소 위치)

  • Taekyung Kim;Jangyoung Kim;Yoon Gi Yang
    • Information Systems Review
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    • v.18 no.4
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    • pp.1-15
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    • 2016
  • Electric cars are expected to increase quality of life by reducing air pollution and to contribute to economic growth by creating new businesses. However, electric car adoption has lagged and has not satisfied public expectation. One of the primary reasons for this outcome is the slow charging speed or inconvenience of charging a battery. Under the insufficient diffusion of electric cars, pushing business entities to construct charging facilities is undesirable for a policy maker to increase the adoption rate because of cost and management issues. This study adopts the design science methodology to interpret the problem of deploying electric car charging stations in the view of information systems. A trip planning algorithm is suggested on the basis of the theory of range anxiety. We investigate issues related to the current charging locations using data from drivers' car navigation devices. We also review its applicability to trip planning to obtain insights.

Research Trends in Coating Strategies for Residual Lithium Control in High-Nickel Li(NixCoyMn1-x-y)O2 Cathodes (고니켈 삼원계 층상구조 양극 물질의 잔류 리튬 제어를 위한 코팅 기술 연구 동향)

  • Ui Yeoun Song;Eun Ji Lee;Ji Eun Lee
    • Applied Chemistry for Engineering
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    • v.35 no.3
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    • pp.182-191
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    • 2024
  • Li(NixCoyMn1-x-y)O2 (NCM) is the intensively developed cathode material for expanding the electric vehicle market and developing lithium-ion batteries that meet higher capacity, longer life, and lower cost. High-nickel NCM increases the nickel content to 80% or more, securing price competitiveness by improving performance with high energy density and reducing the cost of cobalt. However, the high-nickel NCM materials have a residual lithium problem, leading to issues in battery performance degradation and stability. While various methods exist for removing residual lithium, such as washing, doping, and coating, this paper focuses on recent research trends in coatings aimed at enhancing NCM performance and stability by removing residual lithium.

Recycling of end-of-life LiNixCoyMnzO2 batteries for rare metals recovery

  • Sattar, Rabia;Ilyas, Sadia;Kousar, Sidra;Khalid, Amaila;Sajid, Munazzah;Bukhari, Sania Iqbal
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.88-95
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    • 2020
  • An investigation of rare metals recovery from LiNixCoyMnzO2 cathode material of the end-of-life lithium-ion batteries is presented. To determine the influence of reductant on the leach process, the cathode material (containing Li 7.6%, Co 20.4%, Mn 19.4%, and Ni 19.3%) was leached in H2SO4 solutions either with or without H2O2. The optimal process parameters with respect to acid concentration, addition dosage of H2O2, temperature, and the leaching time were found to be 2.0 M H2SO4, 4 vol.% H2O2, 70℃, and 150 min, respectively. The yield of metal values in the leach liquor was > 99%. The leach liquor was subsequently treated by precipitation techniques to recover nickel as Ni(C4H7N2O2)2 and lithium as Li2CO3 with stoichiometric ratios of 2:1 and 1.2:1 of dimethylglyoxime:Ni and Na2CO3:Li, respectively. Cobalt was recovered by solvent extraction following a 3-stage process using Na-Cyanex 272 at pHeq ~5.0 with an organic-to-aqueous phase ratio (O/A) of 2/3. The loaded organic phase was stripped with 2.0 M H2SO4 at an O/A ratio of 8/1 to yield a solution of 114 g/L CoSO4; finally recovered CoSO4.xH2O by crystallization. The process economics were analyzed and found to be viable with a margin of $476 per ton of the cathode material.

Effects of an Unexpected Change in Housing Environment on Stress in Poultry (급격한 사육환경의 변화가 가금의 생산성과 스트레스에 미치는 영향)

  • Kim, Jimin;Yoon, Hyung-sook;Hwangbo, Jong;Kim, Sang-Ho;Choi, Yang-Ho
    • Journal of Animal Environmental Science
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    • v.18 no.3
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    • pp.183-190
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    • 2012
  • The objective of this study was to evaluate the effects of an unexpected change in housing environment on stress in poultry. Laying hens (Hy-line Brown), adapted to a free-range housing system for more than a month, were randomly divided into two groups to be subjected to an unexpected change of their housing environment: one half of them were individually housed into conventional battery cages and the other continually left in the same housing system throughout the entire period of the study. The sudden change resulted in an increase in egg production and albumen height (P<0.05), but decrease in eggshell thickness (P<0.05). The change had tendency to increase Haugh unit ($P{\leq}0.061$) and to decrease eggshell color ($P{\leq}0.074$), but did not affect body weight for 5 days thereafter. No significant changes were detected in liver color. Plasma concentrations of corticosterone was acutely increased one day after the change (P<0.05), then returned to similar control levels. The results of the present study indicate that unexpected changes in housing environment cause acute increase in stress hormone concentrations, but interpretation of the results should be cautious due to the experimental conditions.

Effect of MgF2 Surface Modification for LiNi0.8Co0.15Al0.05O2 Cathode Material on Improving Electrochemical Characteristics (LiNi0.8Co0.15Al0.05O2 양극활물질의 전기화학적 특성 향상을 위한 MgF2 표면처리 효과)

  • Jin, Su-Jin;Seo, Jin-Seong;Na, Byung-Ki
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.52-58
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    • 2020
  • Electrochemical characterization and thermal stability were investigated for MgF2 coated LiNi0.8Co0.15Al0.05O2 cathode. The ratio of MgF2 was controlled by 0.5, 1, 3 wt%. Cyclic voltammetry, charge-discharge profiles, rate capability, cycle life were measured for electrochemical properties. DSC analysis was measured for thermal stability. The first discharge capacities of MgF2 coated LiNi0.8Co0.15Al0.05O2 were decreased at 0.1C-rate compared to pristine LiNi0.8Co0.15Al0.05O2. But the rate capability and cycle life of MgF2 coated LiNi0.8Co0.15Al0.05O2 were improved at 2C-rate. In DSC analysis result, the exothermic temperature of MgF2 coated LiNi0.8Co0.15Al0.05O2 was increased and peak height was decreased.

Development of Monitoring System for Real Time Maintenance of Road Beacon Light (도로 표시등 실시간 유지관리를 위한 모니터링시스템 개발)

  • Lee, Jong Ho;Kim, Kyou Jeon;Choi, Ju Weon;Ahn, Won Tea;Lee, Seung Ki;Choi, Seok Keun
    • Journal of Korean Society for Geospatial Information Science
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    • v.23 no.3
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    • pp.69-75
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    • 2015
  • Road facilities for safe driving were designed for drivers to distinguish them during day and night, but they cannot play their role when the weather becomes worse. Recently, the road facilities have been designed by using electric and electronic technology so that they can be displayed well at a long distance, but they should be replaced very often due to their frequent breakdown. So, there are many problems in traffic calming and maintenance. In this study, to solve the above problems, semi-permanent LED beacon light was installed in the area where traffic accident are frequent, and monitoring system was developed so that the LED beacon light can be maintenanced by connecting with system. For the above installation and development, system was based on window operating system and it was developed for worker to operate it by using P.C. through connecting with wireless local area network. The result of this study led to analyzing state information on the battery of field-installed LED beacon light in real time, and manegement to effectively by predicting their life cycle.