• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2004년도 International Symposium on Powder Materials and Processing
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• pp.53-53
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• 2004

• 한국재료학회:학술대회논문집
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• 한국재료학회 2004년도 춘계학술발표대회 및 제6회 신소재 심포지엄
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• pp.54-54
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• 2004

• 한국분말재료학회지
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• 제8권2호
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• pp.131-135
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• 2001

The ferroelectric properties of barium titanate strongly depend on its microstructure, in particular, grain size and distribution. During sintering, $BaTiO_3$ usually exhibits abnormal grain growth, which deteriorates considerably the ferroelectric properties. A typical technique to suppress the abnormal grain growth is the addition of dopants. Dopant addition, however, affects the ferroelectric properties and thus limits the application of $BaTiO_3$. Here, we report a simple but novel technique to prevent the abnormal grain growth of $BaTiO_3$ and to overcome the limitation of dopant use. The technique consists of stepwise sintering in a reducing atmosphere and in an oxidizing atmosphere. The materials prepared by the present technique exhibit uniform grain size and high dielectric properties. The technique should provide opportunities of having $BaTiO_3$-based materials with superior ferroelectric properties.

• 한국재료학회지
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• 제17권4호
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• pp.185-191
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• 2007

The purpose of this study is to evaluate the thin fihn dielectric made of hybrid sol, which consist of barium titanate powder, polymeric sol and other polymers. This sol will be used dielectric applied to small, thin electric passive components such as MLCC(Multi Layer Ceramic Condenser), resister, inductor. This sol is composed of mixed fine barium titanate powder and polymeric sol including Ba, Ti-precursor, solvent, chelating agent, chemical reaction catalyst, the additive sols to improve fired densification and temperature reliability. First at all, we mixed hybrid sol to be dispersed and be stabilized by ball milling for 24hrs. By spin coating method, we makes thin film dielectric on the convectional green sheet for MLCC. After heat treatments, we analyzes the structure morphology, physical, electrical properties and X5R Temperature properties.

• 한국세라믹학회지
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• 제43권9호
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• pp.519-526
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• 2006

A full-factorial design of experiments with three input factors and two levels for each factor including center points was utilized for the preparation and characterization of twelve types of $BaTiO_3$ slips for tape casting. Ceramic powders with different particle sizes, different milling methods such as high energy milling and conventional ball milling, and two types of dispersant with different polymeric species were chosen as input factors in order to investigate their effects on slip and on green tape properties. Tape casting, a small rectangular-shaped K-square preparation, characterization and quantitative data analysis using statistical software were followed. Ceramic powder was the most significant among three input factors for the output responses of slip viscosity and green tape density, showing more favorable results with large particles than with very fine ones. In addition, high energy milling for only 30 min was more efficient than 24h of conventional ball milling in terms of powder dispersion and milling. The optimum condition based on the experimental results was a slip exposed to high energy milling with large ceramic particles along with a methylethyl acetate dispersant.

• 한국세라믹학회지
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• 제42권2호
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• pp.123-126
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• 2005

용매열법으로 출발물질의 농도를 변수로 차여 $BaTiO_3$ 분말을 합성하였다. 평균입자크기는 출발물질의 농도에 따라 비례하였는데 TiO_2를 기준으로 1/16M 농도에tj 59nm이었고 1/2M 농도에서는 89nm까지 증가하였다. 평균입자 크기가 89nm인 BT 분말에 대하여 리트벨트법에 의하여 분석한 결과 상분율은 정방정상 $75.5\%$이었고, 격자상수는 정방정상은 a=0.3999(nm), c=0.40319(nm)이고, 입방정상은 a=0.4015(nm)이었다. 이 분말을 $500^{\circ}C$ 1시간 열처리 후 TEM분석을 한 결과, 분말 내부에 수산 이온들이 거의 존재하지 않음을 확인하였다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.124-125
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• 2006

Multilayer ceramic capacitor (MLCC) miniaturization has increased the demand for superfine $BaTiO_3$ powder due to its thin dielectric layer. Hydrothermally synthesized $BaTiO_3$ powder a pseudo-cubic phase resulting in poor dielectric properties due to size effect and hydroxyl ion inclusion in the $BaTiO_3$ lattice. We attempted a superfine (lower than 100 nm) highly tetragonal $BaTiO_3$ powder via a solvothermal method without precipitating agent. The lattice parameters and the relative amounts of tetragonal and cubic phases were determined using Rietveld refinement.

• 한국결정성장학회지
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• 제15권6호
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• pp.244-251
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• 2005

수열합성법에 의해 제조된 티탄산바륨 (BT01, BT02, BT03, BT04, BT05)의 입자크기와 분체특성과의 상관관계를 비표면적, 제타전위, XPS, XRD 및 SEM에 의해 조사하였다. 레이져광산법에 의해 측정된 입자의 크기는 비표면적과 XRD를 통해 결정된 격자이방성과 밀접한 관계가 있음을 보였다. 분말의 비표면적은 입자의 크기가 증가함에 따라 감소하였으며, BT03 시료는 동일한 입자크기의 BT04에 비하여 큰 비표면적을 보였으며, 이는 입자들의 응집에 기인하는 것으로 SEM사진 및 XRD 분석을 통하여 밝혀졌다. 입자의 크기가 증가함에 따라 제타전위는 증가하는 경향을 보였으며, BT02와 BT03 분말은 다른 분말에 비하여 제타전위가 큰 음의 값을 나타내었다. XPS 분석결과 분쇄시 티탄산바륨과 물 사이의 반응에 의한 $Ba^{2+}$ 이온의 용출과 관련이 있는 것으로 분석되었다.

• 한국세라믹학회지
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• 제21권3호
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• pp.278-282
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• 1984

Barium titanate powder was made by firing the complex hydroxide which had been synthesized with chemical wet process by the medium of $H_2O_2$. This experiment was done as following A mixed solution of $BaCl_2$, $TiCl_4$ and $H_2O_2$ with 1:1:10 mol ratio was prepared. Ammonium hydroxide was added into the mixed solution. In the range of pH 8-10 $BaTiO_3$ complex hydroxide was obtained and treated at room temperature 11$0^{\circ}C$, 20$0^{\circ}C$, 40$0^{\circ}C$ and $600^{\circ}C$. The results obtaiined from this experiment were as follows. At room temperature $BaTiO_3$ complex hydroxide was amorphous. Above 10$0^{\circ}C$ crystalline $BaTiO_3$ was obtained and particle size of $BaTiO_3$ was increased with elevated temperature. So the particle size of BaTiO3 could be controlled by the firing temperature. After treating $BaTiO_3$ complex hydroxide at 10$0^{\circ}C$ the average particle size of $BaTiO_3$ was 0.22$\mu\textrm{m}$.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2003년도 춘계종합학술대회
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• pp.374-377
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• 2003

Sol-gel processing of BaTiO$_3$ ceramics doped with La(0.01-1.00 at.%) were prepared from metal barium, titanium n-butoxide and lanthanum isopropoxide. Characterization of the sol-gel-derived powder using XRD, SEM is also reported. The obtained results suggested that insulator to semiconductor transition for highly donor-doped barium titanate was closely related to the incorporation of donor into the grains and to the resultant grain size, which were significantly affected by the sinterability of BaTiO$_3$ powders and sintering conditions used.