• Title/Summary/Keyword: Ba/F3

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PMMA Coated BaF2:Er3+ Nanoparticles via a Novel One-Step Reverse-Emulsion Polymerization Process

  • Lian, Hongzhou;Fu, Lianshe;Andre, Paulo S.;Lin, Jun
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2451-2454
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    • 2013
  • Poly(methyl methacrylate) coated $BaF_2:Er^{3+}$ nanoparticles were prepared via a novel reverse-emulsion polymerization process using methyl methacrylate as continuous phase and water as dispersed phase. Preparation and coating of $BaF_2:Er^{3+}$ particles were processed in a single step. The resulting polymeric composites show the characteristic $Er^{3+}$ luminescence at excitation of 980 nm and may have potential applications in amplified optical networks.

Physicochyemical Properties of $ZrF_4-Based$ Fluoride Glasses Containing Rare-Earth Ions

  • Ishioka, Noriyuki;Ogawa, Kouji;Arakawa, Tsuyoshi
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.375-378
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    • 1999
  • In tho XRD study of $56ZrF_4 \cdot34BaF_2 \cdot4AIF_3 \cdot(6-x)LaF_3 \cdotxLnF_3$ glassdLn=Ce, Nd, Gd, Th), halo pattern charactarktic fo an amorphous sample appeared. When the halo peak angle ($\theta_p$) was converted into a wavenumber with $Qp=4\pi sinG\pi/\lambda(\lambda$ is the wavolongth of the radialion used), it was found that the Qp values varied almost liuearly with the concentration 01 $LnF_3$. The emissiou spect1.a of $Ce^{3-}$-containing fluoride glasses nnder 273 nm excitation had a peak maximum at ea. 300 nm $(Ce^{3+}$ 5d-4f- transition). The maximal intensity of the fluorescence was observed when the $CeF_3$, content was extremely low (ca. 1 mol%j. DTA measurement revealed tbat these fluoride glasses had two crystallization temperatures. In $56ZrF_4. 34BaF_2. 4NF_3. (6-x)LaF_3 .xNdF_3$ glasses, the actmation energies of crystallization obtained from a Kssinger plot were 1.7 and 5.0 eV for the glass with x=2, and 1.9 and 5.6 eV for the glass with x=4.

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Screen printed $BaSrTiO_3$ composite for embedded capacitor apprication (Embedded capacitor 적용을 위한 screen printed $BaSrTiO_3$ 복합체)

  • Park, Yong-Jun;Koh, JUng-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.311-312
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    • 2007
  • In this study, composite $BaSrTiO_3$ has been studied for high frequency device applications. Composite $Ba_{0.5}Sr_{0.5}TiO_3$ has high dielectric permittivity and low loss tangent at the relative frequency range from MHz to GHz. 10,30 and 50 wt% of epoxy doped $Ba_{0.5}Sr_{0.5}TiO_3$ powders were prepared with bisphenol A and F polymer employing ball milling process. Epoxy/($BaSrTiO_3$) composites thick films were screen printed on the Cu plated PCB substrates through screen printing methods. The specimens were designed for the embedded capacitor applications. Temperature dependent dielectric permittivity of Epoxy doped $BaSrTiO_3$ ceramics was measured.

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The structural and Microwave Dielectric Properties of (1-x)Ba($Mg_{1/3}Ta_{2/3})O_3$-xBa($Co_{1/3}Nb_{2/3})O_3$(x=0.25~0.5) Ceramics ((1-x)Ba($Mg_{1/3}Ta_{2/3})O_3$-xBa($Co_{1/3}Nb_{2/3})O_3$(x=0.25~0.5) 세라믹스의 구조 및 마이크로파 유전특성)

  • 황태광;최의선;임인호;이영희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.3
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    • pp.197-201
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    • 2001
  • The microwave dielectric properties of (1-x)Ba(Mg$_{1}$3/Ta$_{2}$3/)O$_3$-xBa(Co$_{1}$3/Nb$_{2}$3)O$_3$(x=0.25~0.5) ceramics depending on the Ba(Co$_{1}$3/Nb$_{2}$3/)O$_3$[BCN] contents and the possibility of application as a microwave dielectric resonator were investigated. The specimens were prepared by he conventional mixed oxide method using there sintering temperature of 1575$^{\circ}C$. It was found that Ba(Mg$_{1}$3/Ta$_{2}$3/)O$_3$[BMT] and BCN formed a solid solution with complex perovskite structure. As the mole fraction of BCN increased, dielectric constant increased while temperature coefficient of resonant frequency decreased. The highest value of quality factor, Qxf$_{0}$=138,205GHz, obtained in the sample of 0.9BMT-0.1BCN ceramics. In the range of x$\geq$0.4, the dielectric constant was about 30. The 0.55BMT-0.45BCN ceramics showed excellent microwave dielectric properties with $\varepsilon$$_{r}$=30.84, Qxf$_{0}$=75,325GHz and $\tau$$_{f}$=2.9015ppm/$^{\circ}C$.EX>.EX>.

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The Microwave Dielectric Properties of (1-x)Ba$Mg_{1/3}Ta_{2/3}O_{3}-xBa_Co_{1/3}Nb_{2/3})O_{3}(x=0.25~0.5)$ Ceramics ((1-X)Ba$Mg_{1/3}Ta_{2/3}O_{3}-xBa_Co_{1/3}Nb_{2/3})O_{3}(x=0.25~0.5)$세라믹스의 마이크로파 유전특성)

  • Hwang, Tae-Kwang;Kim, Kang;Lim, Sung-Soo;Lee, Sung-Gap;Lee, Young-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.221-224
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    • 2000
  • The microwave dielectric properties of Ba(Mg$_{1}$3/Ta$_{2}$3/)O$_3$-xBa(Co$_{1}$3/Nb$_{2}$3/)O$_3$[BMT-BCN] ceramics were investigated. The specimens were prepared by the conventional mixed oxide method. It was found that Ba(Mg$_{1}$3/Ta$_{2}$3/)O$_3$ and Ba(Co$_{1}$3/Nb$_{2}$3/)O$_3$ formed a solid solution with complex perovskite structure. Increasing the BCN content, dielectric constant was increased, but temperature coefficient of resonant frequency was decreased. In the range of x$\geq$0.4, dielectric constant was about 30. 0.55BMT-0.45BCN ceramics showed excellent microwave dielectric properties with $\varepsilon$$_{r}$=30.84, Q$\times$f$_{0}$=75,325[GHz] and $\tau$$_{f}$=-2.9015[ppm/$^{\circ}C$].X>].

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The Dielectric Properties of $Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) Ceramics ($Ba_{1-x}A-x(Mg_{1/3}Nb_{2/3})O_3$ (A = Sr, Ca) 세라믹스의 유전특성)

  • 김부근;김재윤;김강언;정수태;조상희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.248-251
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    • 1999
  • The microwave dielectric properties of The Dielectric Properties of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$ (A = Sr, Ca, x = 0, 0.2 ,0.4 ,0.6, 0.8, 1.0) were investigated. In composition of $Ba_{1-x}$A$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O, densities are decreased with increasing x values. Grain sizes are decreased with Sr content and Increased with Ca content. The hexagonally ordered superstructure was observed in $Ba_{1-x}$Sr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the intensity of superlattice increased with x value. In $Ba_{1-x}$Cr$_{x}$(Mg$_{1}$3/Nb$_{2}$3/)O$_3$(BSMN) systems, the additional diffraction patterns were shown. The highest value of $\varepsilon$$_{r}$ was shown in x=0.2 of BCMN systems and the value was 41.9. The highest Q$\times$f was shown in x=0.2 of BSMN systems and the value was 68,000. $\tau$$_{f}$ were shown 0 ppm/$^{\circ}C$ near x=0.8.TEX> near x=0.8.0.8.

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Contamination Investigation and Risk Characterization on the Polycyclic Aromatic Hydrocarbon of Agricultural Products Used for Food and Medicine (식·약공용 농·임산물의 다환방향족탄화수소 오염도 조사 및 위해도 결정)

  • Park, Young-Ae;Ko, Suk-Kyung;Jo, Sung-Ae;Jung, Sam-Ju;Choi, Eun-Jung;Hong, Sung-Cho;Cho, Seok-Ju;Jung, Ji-Hun;Park, Ju-Sung
    • Korean Journal of Pharmacognosy
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    • v.53 no.3
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    • pp.170-180
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    • 2022
  • Polycyclic aromatic hydrocarbons(PAHs) contents were analyzed by measuring benz(a)anthracene(BaA), chrysene(Chr), benzo(b)fluoranthene(BbF) and benzo(a)pyrene(BaP), and the related risk characterization was conducted for 113 samples out of 14 different agricultural products used for food and medicine. Detection rate of PAHs was 90.3% as a whole, and the highest one was 80.5% for BaP. The detection rate of BaP exceeding the maximum permitted concentration of Rehmanniae Radix Preparata and Rehmanniae Radix, 5.0 ㎍/kg was 1.8%, and the detection rates of BaA, Chr and BbF were within the range of 2.7~10.6%. The highest average concentration of BaA was 3.41 ㎍/kg detected from Lycii Fructus, while those of Chr, BbF, BaP and PAH4(sum of detected BaA, Chr, BbF and BaP) were 5.00, 1.79, 2.36, 12.36 ㎍/kg, respectively, detected from Rehmanniae Radix Preparata. As for the risk characterization on PAHs, the overall MOE(Margin of Exposure) values were measured within the range of 105~107, which is unlikely to cause direct health concerns, but the worring values of MOE were measured 6.57×104 for BaP and 6.10×104 for PAH4 from Rehmanniae Radix Preparata, which may require an improvement plan to reduce BaP contents.

Measurement of the Nonlinear Optical Properties by use of the Far-Field Phase Modulation Method (Far-field 위상 변조량 측정법을 이용한 광학매질의 비선형 특성 측정)

  • 김성훈;양준목;김용평;이영우;신동주;정영붕
    • Korean Journal of Optics and Photonics
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    • v.9 no.3
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    • pp.168-174
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    • 1998
  • We have measured nonlinear refractive index and nonlinear absorption coefficient of optical materials by using a far-field phase modulation technique. The phase variation of the probe beam in the nonlinear material is transformed into the spatial phase modulation in the far-field so that the spatial distribution of the optical intensity in conjunction with the computer simulation analysis can give the nonlinear optical constants. We have obtained the nonlinear refractive indices and nonlinear absorption coefficient of $CS_2$ and $BaF_2$ by fitting the experimental values and numerical simulation analysis of far-field measurements. The nonlinear refractive indices of $CS_2$ and $BaF_2$were obtained as $1.2{\times}10^{-11}$ esu and $1.0{\times}10^{-13}$ esu, respectively at 616 nm, and the nonlinear absorption coefficient of BaF$_2$as $5.0{\times}10^{-11}$cm/W at 308nm. These measured values were in good agreement with previous reports.

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The Kinetics of Hyperpolarization Activated Current$(i_f)$ in Sinoatrial Node of the Rabbit (토끼 동방결결에서 Pacemaker전류(과분극에 의해 활성화되는 내향전류, $i_f$)의 동력학적 특성에 관한 연구)

  • Earm, Yung-E
    • The Korean Journal of Physiology
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    • v.17 no.1
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    • pp.1-11
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    • 1983
  • 1) The two microelectrode method was used to voltage clamp small preparations of rabbit sinoatrial node. The kinetics of hyperpolarization activated inward current, $i_f$ were analysed. 2) The hrperpolarization pulses activated $i_f$ current in the presence of $10^{-7}g/ml$ TTX and 2 mM $Mn^{2+}$. The activation range was in between -45 mV to -75 mV. The current magnitude was increased and time course was faster by strong hyperpolarization pulses. 3) Standard envelope tests indicated that this current is exponentially controlled by single gate. 4) Semilogarithmic plot of $i_f$ activation versus time was found to be linear in the activation range. The decrease in current magnitude and the shifts in activation curve and rate constants curve to the hyperpolarizing direction were obtained with $Ba^{2+}$, indicating that $Ba^{2+}$ shifts the voltage dependence of the gating kinetics, were partially reversed by 24 mM $K^+$.

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The effect of g1ass frit arid BaWO$_4$ Addition Microwave Dielectric Prperties of BaTiO$_3$-3TiO$_2$ Ceramics (Glass 첨가 및 BaWO$_4$ 첨가에 따른 BaTiO$_3$-3TiO$_2$ 세라믹스의 고주파 유전 특성)

  • 윤중락;김지균;이헌용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.335-338
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    • 1998
  • The effect of glass flit addition on microwave dielectric properties of BaTiO$_3$-3TiO$_2$ ceramic was studied. Addition of glass frit to this system obtained sintered sample below sintering temperature 105$0^{\circ}C$. At BaTiO$_3$-3TiO$_2$+ g1ass frit 3wt% + BaWO$_4$6 wt%m, this ceramic showed excellent microwave properties of dielectric constant 34, Q$\times$f 8,100, temperature coefficient of resonant frequency 4 ppm/$^{\circ}C$ .

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