• Title/Summary/Keyword: Available $SiO_2$

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Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice;I. Effects of Paper Sludge Application on the Nitrogen Forms and Inorganic Nutrients of Paddy Soil (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);Ⅰ. 슬러지시용(施用)이 토양중(土壤中) 질소형태(窒素形態) 및 무기성분변화(無機成分變化)에 미치는 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik
    • Korean Journal of Environmental Agriculture
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    • v.4 no.2
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    • pp.78-87
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    • 1985
  • To investigate the effects of paper sludge, by-products of paper manufactory, on the chemical properties of paddy soil and growth of paddy rice, paper sludges were applied to the pots at the rates of 300, 600, 900 and 1,200㎏/l0a which were either pread-justed C/N ratio to 30 : 1 or not adjusted. The effects were compared with those of control. Seasonal variations of various forms of soil organic nitrogen, the mineralization of organic nitrogen and the contents of soil minerals were analyzed. The results were summarized as follows: 1) The contents of soil organic nitrogen, especially amino sugar-N and amino acid-N, organic matter, CEC and available $SiO_2$ were increased by application of paper sludge compared with that of control. 2) The mineralizations of organic nitrogen after 6 weeks of incubation at $30^{\circ}C$ were 12. 2, 12.6, 15.1, 9.7 and $15.2^{\circ}C$ in the control, 300㎏/l0a sludge treatment, 300㎏/l0a sludge treatment(C/N ratio adjusted), 600㎏/l0a sludge treatment and 600㎏/l0a sludge treatment(C/N ratio adjusted), respectively. 3) Cu and Pb contents in the soil were in the range of $0{\sim}0.2100$ and $0{\sim}0.0013$ ppm, respectively. Cr and Cu in the soil were not detected at all. There were no differences in the contents of all the heavy metals among all the treatments in the soil.

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Synthesis of Ultrasound Contrast Agent: Characteristics and Size Distribution Analysis (초음파 조영제의 합성 및 합성된 초음파 조영제의 특성 분석)

  • Lee, Hak Jong;Yoon, Tae Jong;Yoon, Young Il
    • Ultrasonography
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    • v.32 no.1
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    • pp.59-65
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    • 2013
  • Purpose: The purpose of this study is to establish the methodology regarding synthesis of ultrasound contrast agent imaging, and to evaluate the characteristics of the synthesized ultrasound contrast agents, including size or degradation interval and image quality. Materials and Methods: The ultrasound contrast agent, composed of liposome and SF6, was synthesized from the mixture solution of $21{\mu}mol$ DPPC (1, 2-Dihexadecanoyl-sn-glycero-3-phosphocholine, $C_{40}H_{80}NO_8P$), $9{\mu}mol$ cholesterol, $1.9{\mu}mol$ of DCP (Dihexadecylphosphate, $[CH_3(CH_2)_{15}O]_2P(O)OH$), and chloroform. After evaporation in a warm water bath and drying during a period of 12-24 hours, the contrast agent was synthesized by the sonication process by addition of buffer and SF6 gas. The size of the contrast agent was controlled by use of either extruder or sonication methods. After synthesis of contrast agents, analysis of the size distribution of the bubbles was performed using dynamic light scattering measurement methods. The degradation curve was also evaluated by changes in the number of contrast agents via light microscopy immediate, 12 hours, 24 hours, 36 hours, 48 hours, 60 hours, 72 hours, and 84 hours after synthesis. For evaluation of the role as an US contrast agent, the echogenicity of the synthesized microbubble was compared with commercially available microbubbles (SonoVue, Bracco, Milan, Italy) using a clinical ultrasound machine and phantom. Results: The contrast agents were synthesized successfully using an evaporation-drying-sonication method. The majority of bubbles showed a mean size of 154.2 nanometers, and they showed marked degradation 24 hours after synthesis. ANOVA test revealed a significant difference among SonoVue, synthesized contrast agent, and saline (p < 0.001). Although no significant difference was observed between SonoVue and the synthesized contrast agent, difference in echogenicity was observed between synthesized contrast agent and saline (p < 0.01). Conclusion: We could synthesize ultrasound contrast agents using an evaporation-drying-sonication method. On the basis of these results, many prospective types of research, such as anticancer drug delivery, gene delivery, including siRNA or microRNA, targeted molecular imaging, and targeted therapy can be performed.

Physico-Chemical Properties of Aggregate By-Products as Artificial Soil Materials (골재 부산물의 용토재 활용을 위한 특성 분석)

  • Yang, Su-Chan;Jung, Yeong-Sang;Kim, Dong-Wook;Shim, Gyu-Seop
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.5
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    • pp.418-428
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    • 2007
  • Physical and chemical properties of the aggregate by-products including sludge and crushed dust samples collected from the 21 private companies throughout the country were analyzed to evaluate possible usage of the by-products as artificial soil materials for plantation. The pH of the materials ranged from 8.0 to 11.0. The organic matter content was $2.85g\;kg^{-1}$, and the total nitrogen content and available phosphate content were low as 0.7 percents and $12.98mg\;kg^{-1}$, respectively. Exchangeable $Ca^{2+}$, $Mg^{2+}$, $K^+$, and $Na^+$ were 2.29, 0.47, 0.02 and $0.05cmol\;kg^{-1}$, respectively. Heavy metal contents were lower than the limits regulated by environmental law of Korea. Textural analysis showed that most of the materials were silt loam with low water holding capacity ranged from 0.67 to 7.41 percents, and with low hydraulic conductivity ranged from 0.4 to $2.8m\;s^{-1}$. Mineralogical analysis showed that the aggregate by product materials were mostly composed of silicate, alumina and ferric oxides except calcium oxide dominant materials derived from limestones. The primary minerals were quartz, feldspars and dolomites derived from granite and granitic gneiss materials. Some samples derived from limestone material showed calcite and graphite together with the above minerals. According to the result, it can be concluded that the materials could be used as the artificial soil material for plantation after proper improvement of the physico-chemical properties and fertility.

Changes in Barley Yield and Some Physico-chemical Properties of Upland Soil by Longterm Application of Silicate Fertilizer and Compost (밭에서 규산(珪酸) 및 퇴비(堆肥)의 장기연용(長期連用)에 의한 보리수량(收量) 및 토양(土壤)의 이화학성(理化學性) 변화(變化))

  • Kim, Chang-Bae;Park, No-Kwuan;Lee, Suk-Hee;Park, Seon-Do;Choi, Boo-Sull
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.3
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    • pp.195-200
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    • 1994
  • This study was conducted to evaluate the changes in barley yield some physico-chemical properties of soils affected by annual application of N.P.K and N.P.K+silicate fertilizer 250kg/10a and N.P.K+compost 1,000kg/10a to the silty clay loam upland soil during the 18 years from 1975 to 1992. The results obtained are as follows. 1. Barley yield of the 18th year increased by 17~18% in the treatments of N.P.K+compost annually applied in comparison with N.P.K treated plot. So, simillar effect was recognized between the silicate fertilizer and the compost treatment plot. 2. The amount of nutrient's uptake by barley plant at the harvesting stage in the treats of N.P.K+silicate fertilizer and N.P.K+compost annually applied increased by 6~8% in comparison with N.P.K treated plot. Fertilizer's efficiency remarkably increased with $P_2O_5$, and $K_2O$ in the treats of N.P.K+silicate fertilizer and N.P.K+compost annualy applied comparing to N.P.K treated Plot. 3. According to soil analysis after experiment, the N.P.K+silicate fertilizer and N.P.K+compost annually applied plot were increased in soil pH, OM, available $P_2O_5$ exchangable cations and soluble $SiO_2$ content, but the content of $NO_3$-N was low. 4. Average yield of barley for 18 years increased by 22% in the treat of N.P.K+silicate fertilizer 250kg/10a annually applied plot and by 31% in the treat of N.P.K+compost 1,000kg/10a annually applied plot in comparison with N.P.K treated plot.

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Effects of Long Term Fertilizations on Growth, Yield and Grain Development of Rice (비료의 장기연용이 벼의 생육ㆍ수량 및 미립발달에 미치는 영향)

  • Han, Hee-Suk;Lee, Moon-Hee;Shim, Jai-Sung
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.36 no.1
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    • pp.41-51
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    • 1991
  • This study was conducted to determine the effect of 20 years long term fertilizations on the physical and chemical properties of paddy soil and the growth, yield, yield components and grain development of rice. Non-fertilized, PK, NK, NP, NPK, NPK + compost, NPK+straw and NPK+lime have been applied since 1968 after surface paddy soil was removed. NPK+compost and NPK+straw applications increased the content of organic matter, available P and CEC, and lime increased soil acidity and SiO$_2$ content. While chemical contents in non-fertilized treatment were low as compared with other treatments. Soil porosity was higher in NPK+straw (51.4%) and NPK+lime(53.1%) than in NPK application (49.8%). Soil hardness was highest in the NPK application and was lowest in the NPK + lime. Continuous application of straw with NPK markedly increased the content of aggregate with over 1mm(19.6%) as compared with NPK application (7.1%). Plant height, tiller number, root number, leaf area index and total dry weight were higher in the applications of compost, straw and lime with NPK than in any other treatments. Brown rice yield in non-fertilized, PK and NP applications was decreased 45, 55, 15 and 5% of that in NPK application, respectively, while application of compost, straw and lime with NPK increased the yield by 11, 14 and 4%, respectively, during 20 years. The number of differentiated rachis branchs in the application of compost, straw and lime was 17 to 21 and that in the other application was 13 to 15, whereas the degenerated rachis branchs was low in the application of compost, straw and lime with NPK. The applications having higher level of perfect rice grain such as non-fertilized, NPK+compost, NPK+straw and NPK+lime had high grain weight and had low level of white core rice, white belly rice. The white core and belly rice was highest in the NP application and notched belly rice kernel was markedly increased in NK and NP applications. The period of grain filling was 30 DAH at NP and NPK applications, 35 DAH at NK and NPK+lime, 40DAH at NPK+compost and NPK+ straw, and 45DAH at non-fertilized, respectively.

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Studies on the Acid Sulphate Soils - Effect of the Rice Plant Growth by Amounts of Lime Application on No-Percolation and Percolation - (산성(酸性) 유산염(硫酸鹽) 토양(土壤)에 관(關)한 연구(硏究) - 투수(透水)에 의(依)한 석회(石灰) 시용량(施用量)이 수도생육(水稻生育)에 미치는 영향(影響) -)

  • Ha, H.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.29-34
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    • 1970
  • This experiment was conducted to investigate the influence of amounts of lime dressed on the growth of rice by the treatment of percolation and nonpercolation in the acid sulphate soil. And also analysis of soil chemical components after treatment was carried out. The results obtained were summarized as follows: 1. In the initial stage of growth, number of tillers and plant length showed no distinct differences between the treatments of percolation and nonpercolation, but after August the effect of lime appeared and the percolation treatment was more effective than the nonpercolation. 2. Lime dressing affected good influence on the panicles, grain per panicles and the rate of grain formation, and the treatment of percolation showed better results than nonpercolation. 3. If the yield of rough rice in the control (nonpercolation and lime dressing) was 100, it was 194 in the treatment of nonpercolation 12me/100gr of lime dressed, 268 in the treatment of percolation-4me/100gr of lime and 315 in the 8me/100gr-percolation. 4. Lime dressing affected good influence on the control of Helminthosporium leaf spots. 5. In the case of lime dressing, amounts of available phosphate and soluble silicon dioxide were increased, but ferrous ion ($Fe^{{+}{+}}$) were decreased.

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Influence of Diagnostic Fertilization and Subsoil Breaking on Soil physico-chemical Properties in Direct Seeding of Rice on Flooded Paddy Surface (벼 담수표면 직파재배시 진단시비와 심토파쇄가 토양이화학성 및 벼 생육에 미치는 영향)

  • Yoo, Chul-Hyun;Ryu, Jin-Hee;Yang, Chang-Hyu;Kim, Taek-Kyum;Kang, Seung-Weon;Kim, Jae-Duk;Jung, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.334-338
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    • 2006
  • This study was conducted to evaluate the effect of improvement of soil physical properties such as deep plowing, subsoil breaking and diagnostic fertilization on the yield of rice and nitrogen-use efficiency in direct seeding on flooded paddy surface of rice. The effects of deep plowing, subsoil breaking and diagnostic application of N, P, K fertilizers, Latex coated urea(LCU), compost, silicate were investigated. The soil physical properties, such as bulk density, hardness and porosity were improved and the content of organic matter and available $SiO_2$ were also increased by deep plowing and subsoil breaking. The amount of $NH_4-N$ in soil was highly increased by diagnostic fertilization and deep plowing at 5th leaf stage. The nitrogen-use efficiency was the highest at the diagnostic application of LCU 70% applied as basal dressing with subsoil breaking. The yield of rice increased by 8% under the diagnostic application of LCU 70% applied as basal dressing with subsoil breaking compared with the conventional application.

Suppression of Powdery Mildew Development in Oriental Melon by Silicate Fertilizer (규산질 비료의 참외 흰가루병 발생 억제 효과)

  • Ryu, Na-Hyun;Choi, Mi-Young;Ryu, Youn-Ju;Cho, Hyun-Jong;Lee, Yong-Se;Lee, Young-Deuk;Chung, Jong-Bae
    • Korean Journal of Environmental Agriculture
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    • v.22 no.4
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    • pp.255-260
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    • 2003
  • Silicon is known to accumulate in plants and results in greater resistance to diseases and insect pests. In this study, we investigated the effect of silicate fertilizer applied in soil on the development of powdery mildew of oriental melon. Oriental melon seedlings of four-leaf stage were transplanted and grown in a plastic film house. Silicate fertilizer was applied to maintain soil available $SiO_2$ level of 200 mg/kg one week before transplanting. Fungicide triflumizol was sprayed three times; one, two, and three weeks after transplanting. Sphaerotheca fuliginea was inoculated 2 weeks after transplanting. The number of infected leaf and the number of fungal colony in leaves were measured one, two, and three weeks after the inoculation. Three weeks after the fungal inoculation, in the treatment of fungicide triflumizol. infected leaf numbers and number of colony per leaf were reduced by 10 and 58%, respectively. In the silicate fertilizer treatment, infected leaf numbers and numbers of colony per infected leaf were suppressed only by 6 and 16%, respectively, and the efficacy was lower than that of the fungicide triflumizol. The combined treatment of silicate fertilizer and the fungicide suppressed powdery mildew more effectively, and infected leaf numbers and numbers of colony per leaf were reduced by 31 and 80%, respectively. These results indicate that although silicate fertilizer itself is not much effective in the suppression of powdery mildew, it can significantly enhance the efficacy of the fungicide.

Diagnosis of Real Condition and Distribution of Protected Trees in Changwon-si, Korea (창원시 보호수의 분포현황과 실태진단)

  • You, Ju-Han;Park, Kyung-Hun;Lee, Young-Han
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.29 no.1
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    • pp.59-70
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    • 2011
  • The purpose of this study is to present raw data to systematically and rationally manage the protected trees located in Changwon-si, Korea. This study investigated about the present condition and the information of location, individual, management, health and soil. The results are as follows. The protected trees were located in 26 spots, and species of trees were 9 taxa; Zelkova serrata, Celtis sinensis, Aphananthe aspera, Ginkgo biloba, Carpinus tschonoskii, Pinus densiflora for. multicaulis, Quercus variabilis, Pinus densiflora and Salix glandulosa. In protected tree types, shade trees were the most, and the majority of theirs were 200 years or more in age. The range of altitude was 14~173m, and the number of trees located in flat fields was the most. For location types, village and field and mountain were presented in the order and, in land use, land for building was the most. The range of height was 8.0~30.0m, 0.6~5.1m in crown height, 240~700cm in diameter of breast and 210~800cm in diameter of root. In case of crown area, Zelkova serrata of No.5 was most large. The status boards were mostly installed except No.23 and No.26. The sites with fence were 9 spots, and the site with stonework were 14 spots. The sites with the support beam were 5 spots, and most sites were not covered up with soil. The materials of bottom were soil, gravel and vegetation in the order. The range of withering branch rate was 0~40%, and peeled bark rate was 0~60%. The sites made holes were 23 spots, and the hole size of Aphananthe aspera of No.12 was the largest. The sites disturbed by human trampling were 7 spots, the sites by disease and insects of 2 spots, the sites by injury of 23 spots and the sites by exposed roots of 13 spots. In the results of soil analysis, there showed that acidity was pH 4.5~8.0, organic matter content of 3.5~69.8g/kg, electrical conductivity(EC) of 0.11~2.87dS/m, available $P_2O_5$ of 3.0~490.6mg/kg, exchangeable K of 0.10~1.05cmol+/kg, exchangeable Ca of 1.41~16.45cmol+/kg, exchangeable Mg of 0.37~1.96cmol+/kg, exchangeable Na of 0.25~2.41cmol+/kg and cation exchange capacity(C.E.C) of 8.35~26.55cmol+/kg.

Strength Characteristics on Sulfuric Acid Corrosion of Recycled PET Polymer Concrete with Different Fillers (충전재 종류에 따른 PET재활용 폴리머콘크리트의 황산부식에 대한 강도 특성)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.499-504
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    • 2005
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete Is drawing a strong interest as high-performance materials in the construction industry Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems Posed by plastics and save energy. An objective of this paper is to estimate the damage of sulfuric acid, through investigating recycled PET polymer concrete, immersed at sulfuric acid solution for 84 days. As a result of testing, recycled PET PC, used $CaCO_3$ as filler, makes a problem of appearance and strength if they are exposed for long term at corrosion environment. On the other hand, recycled PET PC, used fly-ash as filler, had less effect on decrease in weight and strength. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.