• 제목/요약/키워드: Au addition

검색결과 227건 처리시간 0.03초

피복합금을 사용한 Bi-2223 선재의 열전도도 및 전기전도도 특성평가 (Effects of Ag-alloy sheath on thermal/electrical conductivity of Bi-2223 superconductor tapes)

  • 장석헌;지봉기;임준형;주진호;나완수
    • Progress in Superconductivity
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    • 제4권2호
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    • pp.180-183
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    • 2003
  • We evaluated the effect of alloying-element additions to Ag sheath on thermal conductivity of Bi-2223 superconductor tapes. In order to evaluate the effect of sheath alloys and their configuration on the properties of tape, various combinations of Ag and Ag alloys were selected as inner and outer sheath. Thermal conductivity of the tapes was measured by using thermal integral method at 10∼120 K. It is observed that the presence of alloying-elements such as Mg, Sb, and Au in Ag sheath results in decreased thermal conductivity at low temperature. Specifically, the thermal conductivity of AgMg, AgSb, and AgAu at 40 K were 411.4, 142.3, and 109.7 W/(m·K), respectively, which is about 2∼9 times lower than that of Ag (1004.6 W/(m·K)). In addition, the thermal conductivity of alloy-sheathed tape was significantly dependent on their values of constituent sheath materials.

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Phase Transition of Octaneselenolate Self-assembled Monolayers on Au(111) Studied by Scanning Tunneling Microscopy

  • Choi, Jung-Seok;Kang, Hun-Gu;Ito, Eisuke;Hara, Masahiko;Noh, Jae-Geun
    • Bulletin of the Korean Chemical Society
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    • 제32권8호
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    • pp.2623-2627
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    • 2011
  • We investigated the surface structure and wetting behavior of octaneselenolate self-assembled monolayers (SAMs) on Au(111) formed in a 50 ${\mu}M$ ethanol solution according to immersion time, using scanning tunneling microscopy (STM) and an automatic contact angle (CA) goniometer. Closely-packed, well-ordered alkanethiol SAMs would form as the immersion time increased; unexpectedly, however, we observed the structural transition of octaneselenolate SAMs from a molecular row phase with a long-range order to a disordered phase with a high density of vacancy islands (VIs). Molecularly resolved STM imaging revealed that the missing-row ordered phase of the SAMs could be assigned as a $(6{\times}{\surd}3)R30^{\circ}$ superlattice containing three molecules in the rectangular unit cell. In addition, CA measurements showed that the structural order and defect density of VIs are closely related to the wetting behaviors of octaneselenolate SAMs on gold. In this study, we clearly demonstrate that interactions between the headgroups and gold surfaces play an important role in determining the physical properties and surface structure of SAMs.

Electrodeposition of Some Selective Metals Belonging to Light, Refractory and Noble Metals from Ionic Liquid Electrolytes

  • Dilasari, Bonita;Kwon, Kyung-Jung;Lee, Churl-Kyoung;Kim, Han-Su
    • 전기화학회지
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    • 제15권3호
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    • pp.135-148
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    • 2012
  • Ionic liquids are steadily attracting interests throughout a recent decade and their application is expanding into various fields including electrochemistry due to their unique properties such as non-volatility, inflammability, low toxicity, good ionic conductivity, wide electrochemical potential window and so on. These features make ionic liquids become an alternative solution for electrodeposition of metals that cannot be electroplated in aqueous electrolytes. In this review, we classify investigated metals into three categories, which are light (Li, Mg), refractory (Ti, Ta) and noble (Pd, Pt, Au) metals, rather than covering the exhaustive list of metals and try to update the recent development in this area. In electrodeposition of light metals, granular fine Li particles were successfully obtained while the passivation of electrodeposited Mg layers is an obstacle to reversible deposition-dissolution process of Mg. In the case of refractory metals, the quality of Ta and Ti deposit particles was effectively improved with addition of LiF and pyrrole, respectively. In noble metal category, EMIM TFSA ionic liquid as an electrolyte for Au electrodeposition was proven to be effective and BMP TFSA ionic liquid developed a smooth Pd deposit. Pt nanoparticle production from ionic liquid droplet in aqueous solution can be cost-effective and display an excellent electrocatalytic activity.

FEM을 이용한 수정진동자의 진동 및 주파수 해석 (An Analysis of Vibration and Frequency Characteristics for Quartz Crystal Using the Finite Element Method)

  • 박재성;고영준
    • 대한전자공학회논문지TE
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    • 제42권1호
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    • pp.7-12
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    • 2005
  • 유한요소해석 프로그램인 ANSYS를 이용하여 수정진동자의 진동 및 주파수특성을 해석하였다. 수정진동자의 직경을 고정하고 두께를 변화시키면서 주파수특성을 조사하였다. 전극박막을 금, 은, 알루미늄으로 적층하였을 경우, 금속의 종류에 따른 공진주파수를 구하였다. 그 결과 유한요소법을 이용하여 수정진동자의 최적조건을 예측할 수 있었다. 또 수정편 두께가 0.2mm 보다 작은 영역에서의 주공진주파수는 8.102 MHz이상의 고주파를 얻을 수 있는 것을 확인하였다. 전극박막으로 사용한 금속의 종류에 따른 수정진동자의 주공진주파수 변화를 조사한 결과, 금이나 은에 비해 알루미늄이 우수한 주파수특성을 나타내었다.

고온초전도 선재용 피복합금의 열전도도 측정 및 특성평가 (Thermal conductivity and properties of sheath alloy for High-$T_c$ superconductor tape)

  • 박형상;지봉기;김중석;임준형;오승진;오승진;주진호;나완수;유재무
    • 한국전기전자재료학회논문지
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    • 제13권8호
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    • pp.711-717
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    • 2000
  • Effect of alloying element additions to Ag on thermal conductivity electrical conductivity and mechanical properties of sheath materials for BSCCO tapes has been characterized. The thermal conductivity at low temperature range(10~300K) of Ag alloys were evaluated by both direct and indirect measurement techniques and compared with each other. It was observed that thermal conductivity decreased with increasing the content of alloying elements such as Au, Pd and Mg. Thermal conductivity of pure Ag at 30 K was measured to be 994.0 W/m.K on the other hand the corresponding values of A $g_{0.9995}$/M $g_{0.0005}$, A $g_{0.974}$/A $u_{0.025}$/M $g_{0.001}$, A $g_{0.973}$/Au.0.025//M $g_{0.002}$, and A $g_{0.92}$/P $d_{0.06}$/M $g_{0.02}$ were 342.6, 62.1, 59.2, 28.9 W/m.K respectively indicating 3 to 30 times lower than that of pure Ag. In addition alloying element additions to Ag improved mechanical strength while reduced elongation probably due to the strengthening mechanisms by the presence of additive atoms.s.

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YBCO 박막형 초전도 한류소자의 퀜치 회복 특성에 관한 연구 (Quench recovery characteristics of YBCO thin film type superconducting fault current limiter)

  • 임성우;심정욱;김혜림;현옥배;김호민;박권배;이방욱;오일성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 B
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    • pp.711-712
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    • 2006
  • For the application of superconducting fault current limiters(SFCLs) to the protection system, quench recovery characteristics of Au/YBCO thin film were investigated. The Au/YBCO thin film was designed as a SFCL element with a bi-spiral pattern. The SFCL element limited the fault current successfully. For the analysis of the recovery to superconducting state, we measured resistance variation of the SFCL element after the quench. In addition, in order to investigate the dependence of quench characteristics of SFCL on the $LN_2$ cooling condition, we measured the recovery time under a pressure of 1, 2 and 3 atm. As the results, the recovery time increased in proportion to the duration of the fault currents. In the sub-cooled condition, while the quench development was exactly the same, the recovery time was shortened as the pressure increased.

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$TiO_{2}$와 귀금속을 첨가한 $WO_{3}$ 후막 센서의 제조 및 NOx 감응 특성 (Fabrication and NOx Sensing Characteristics of $WO_{3}$ Based Thick Film Devices Doped with $TiO_{2}$ and Noble Metals)

  • 이대식;한상도;손영목;이덕동
    • 센서학회지
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    • 제6권4호
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    • pp.274-279
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    • 1997
  • $WO_{3}$ 모물질로 하여 NOx 검지센서를 제조하여 전기적 특성과 가스감지특성을 알아 보았다. $SnO_{2}$$TiO_{2}$를 포함한 $WO_{3}$ 후막은 동작온도 $400^{\circ}C$에서 순수한 $WO_{3}$ 후막보다 NOx가스에 대한 뛰어난 감도와 가스 흡탈착 특성을 보였다. $TiO_{2}-WO_{3}$ 후막에 Ru와 Au와 같은 귀금속 촉매를 특별히 첨가하여 제작된 센서에서는 NOx 가스에 대한 감도, 회복 속도 및 선택도 등을 더욱 개선되었다.

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Viologen 유도체를 전하전달체로 이용한 Glucose 센서의 $H_2O_2$ 검출 특성 ($H_2O_2$ Detection Property of Glucose Sensor using Self Assembled Viologen Modified Electrode as Mediator)

  • 이동윤;최원석;박상현;권영수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 Techno-Fair 및 추계학술대회 논문집 전기물성,응용부문
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    • pp.86-87
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    • 2007
  • An amperometric glucose biosensor has been developed using viologen derivatives as electron mediator of glucose oxidase (GOD) at Au electrode. Highly stable self assembled monolayer (SAM) of thiol-based viologen is immobilized onto the Au electrode followed byGOD is immobilized onto the viologen modified electrode. This biosensor response to glucose was evaluated amperometrically in the potential of -300 mV. Upon immobilization of glucose oxidase onto the viologen modified-electrode, the biosensor showed rapid response towards glucose. Experimental conditions influencing the biosensor performance such as, pH, potential were optimized and assessed. This biosensor offered an excellent electrochemical response for glucose concentration below ${\mu}mol$ level with high sensitivity and selectivity and short response time. The levels of the RSD's (< 5 %) for the entire analyses reflected the highly reproducible sensor performance. Using the optimized a linear relationship between current and glucose concentration was obtained up to $4.5{\times}10^{-4}$ M. In addition, this biosensor showed well reproducibility and stability.

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Highly Productive Process Technologies of Cantilever-type Microprobe Arrays for Wafer Level Chip Testing

  • Lim, Jae-Hwan;Ryu, Jee-Youl;Choi, Woo-Chang
    • Transactions on Electrical and Electronic Materials
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    • 제14권2호
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    • pp.63-66
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    • 2013
  • This paper describes the highly productive process technologies of microprobe arrays, which were used for a probe card to test a Dynamic Random Access Memory (DRAM) chip with fine pitch pads. Cantilever-type microprobe arrays were fabricated using conventional micro-electro-mechanical system (MEMS) process technologies. Bonding material, gold-tin (Au-Sn) paste, was used to bond the Ni-Co alloy microprobes to the ceramic space transformer. The electrical and mechanical characteristics of a probe card with fabricated microprobes were measured by a conventional probe card tester. A probe card assembled with the fabricated microprobes showed good x-y alignment and planarity errors within ${\pm}5{\mu}m$ and ${\pm}10{\mu}m$, respectively. In addition, the average leakage current and contact resistance were approximately 1.04 nA and 0.054 ohm, respectively. The proposed highly productive microprobes can be applied to a MEMS probe card, to test a DRAM chip with fine pitch pads.

An integrated DNA barcode assay microdevice for rapid, highly sensitive and multiplex pathogen detection at the single-cell level

  • Jung, Jae Hwan;Cho, Min Kyung;Chung, So Yi;Seo, Tae Seok
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.276-276
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    • 2013
  • Here we report an integrated microdevice consisting of an efficient passive mixer, a magnetic separation chamber, and a capillary electrophoretic microchannel in which DNA barcode assay, target pathogen separation, and barcode DNA capillary electrophoretic analysis were performed sequentially within 30 min for multiplex pathogen detection at the single-cell level. The intestine-shaped serpentine 3D micromixer provides a high mixing rate to generate magnetic particle-pathogenic bacteria-DNA barcode labelled AuNP complexes quantitatively. After magnetic separation and purification of those complexes, the barcode DNA strands were released and analyzed by the microfluidic capillary electrophoresis within 5 min. The size of the barcode DNA strand was controlled depending on the target bacteria (Staphylococcus aureus, Escherichia coli O157:H7, and Salmonella typhimurium), and the different elution time of the barcode DNA peak in the electropherogram allows us to recognize the target pathogen with ease in the monoplex as well as in the multiplex analysis. In addition, the quantity of the DNA barcode strand (~104) per AuNP is enough to be observed in the laser-induced confocal fluorescence detector, thereby making single-cell analysis possible. This novel integrated microdevice enables us to perform rapid, sensitive, and multiplex pathogen detection with sample-in-answer-out capability to be applied for biosafety testing, environmental screening, and clinical trials.

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