• The Korean Journal of Nuclear Medicine
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• v.24 no.1
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• pp.101-107
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• 1990

To develop $^{131}I-labelled$ m-iodobeneylguanidine $(^{131}I-MIBG)$, various experiments such as synthesis of MIBG, establishment of labelling conditions, determination of radiochemical purity, and examination of stability were carried out. 1) m-Iodobenzylguanidine (MIBG) sulfate was synthesized with a total yield of 62.4% by the condensation of m-iodobenzylamine hydrochloride with cyanamide via MIBG bicarbonate. Its physical properties, IR, $^1H-NMR$, and elemental analysis data were nearly identical to those of literature. 2) Freeze-dried or vacuum-dried kit vials were prepared from the mixture so as to contain MIBG (2 mg), ascorbic acid (10 mg), copper (II) sulfate (0.14 mg), and tin (II) sulfate (0.5 mg) per vial. Copper ( I ) catalyzed radioiodination of MIBG was carried out using kit vials and 0.01 M $H_2SO_4$ as solvent at $100^{\circ}C$ for 30 min under nitrogen atmosphere (optimal conditions). Labelling yield was 98% and radiochemical purity was 99.5%, respectively. 3) Solid-phase radioiodination of MIBG was carried out at $155^{\circ}C$ for 30 min using the prepared vials to contain MIBG (2 mg) and ammonium sulfate (10 mg). Duplicate reactions under the same conditions showed labelling yield of 95% and radiochemical purity of 99.5%. 4) $^{131}I-MIBG$ prepared either by catalytic or by solid-phase exchange method showed radio-chemical purity of 99% even after 3 days storing at room temperature.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.21 no.3
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• pp.91-102
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• 2016

The spatio-temporal variations of the dissolved methane concentration were investigated and the methane budget was estimated in the Nakdong Estuary in January, September, and November of 2014. Dissolved methane showed seasonal variation (21~874 nM) with high concentration in summer due to enhanced temperature and fresh water discharge. Decreasing trends of dissolved methane from the river to the estuary were consistent in all seasons showing the main source of the estuarine methane is river discharge. However, the decreasing trends were modified seasonally due to the local sources such as organic-rich sediments in intertidal zone or near the estuarine barrage. Dissolved methane concentration in the Nakdong Estuary was high, compared to other estuaries probably due to the well developed wetland in Nakdong-river system and stagnation effect from barrages and dams. Dominant sink for the Nakdong estuarine methane was outflux into the atmosphere. Relatively long residence time (produced by barrier island and estuarine dam) in the estuary might provide the enough time for the outgassing.

• Journal of the Korean Society of Food Culture
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• v.31 no.6
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• pp.634-642
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• 2016

Chinese cabbage is produced and consumed as a main material for kimchi and as a staple vegetable in Korea throughout the year. However, due to environmental changes unbalance between supply and demand is repeated annually, requiring development of long-term storage technologies. Chinese cabbages, were harvested, put in plastic boxes, and precooled at $2^{\circ}C$ for 24 hours using forced air precooler. After precooling, Chinese cabbages were MAP-treated with 0.02 mm HDPE film and functional film and stored at low temperature ($1{\pm}0.5^{\circ}C$). The weight-loss rates after 9-weeks of storage were 8.47% in the control group, 4.07% in the HDPE film-treated group, and 3.07% in the functional film-treated group, respectively, suppressing weight loss. Trimming loss rate after 6-weeks of storage was 6.86% in the functional film MAP-treated group and lower than 7.50% in the control group. In the sensory test with 7 points as the limit of commodity, the control group lost it after 6-weeks of storage while the MAP-treated groups retained over 7 points. The functional film MAP-treated group showed over 6 points for processing as kimchi until 9-weeks of storage, proving that Pallet-type MAP storage is effective for extending storage life of spring Chinese cabbage.

• Atmosphere
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• v.31 no.4
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• pp.421-431
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• 2021

The Yeongdong region is frequently vulnerable to heavy snowfall in winter in terms of societal and economical damages. By virtue of a lot of previous efforts, snowfall forecast has been significantly improved, but the performance of light snowfall forecast is still poor since it is very conducive to synoptic and mesoscale interactions, largely attributable to Taeback mountains and East Sea effects. An intensive observation has been made in cooperation with Gangwon Regional Meteorological Office and National Institute of Meteorological Studies in winter seasons since 2019. Two distinctive Cold Air Damming (CAD) events (14 February 2019 and 6 February 2020) were observed for two years when the snowfall forecast was wrong specifically in its location and timing. For two CAD events, lower-level temperature below 2 km ranged to lowest limit in comparisons to those of the previous 6-years (2014~2019) rawinsonde soundings, along with the stronger inversion strength (> 2.0℃) and thicker inversion depth (> 700 m). Further, the northwesterly was predominant within the CAD layer, whereas the weak easterly wind was exhibited above the CAD layer. For the CAD events, strong cold air accumulation along the east side of Taeback Mountains appeared to prevent snow cloud and convergence zone from penetrating into the Yeongdong region. We need to investigate the influence of CAD on snowfall in the Yeongdong region using continuous intensive observation and modeling studies altogether. In addition, the effect of synoptic and mesoscale interactions on snowfall, such as nighttime drainage wind and land breeze, should be also examined.

• Atmosphere
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• v.31 no.4
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• pp.461-472
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• 2021

Yeongdong has frequently suffered from severe snowstorms, which generally give rise to societal and economic damages to the region in winter. In order to understand its mechanism, there has been a long-term measurement campaign, based on the rawinsonde measurements for every snowfall event at Gangneung since 2014. The previous observations showed that a typical heavy snowfall is generally accompanied with northerly or northeasterly flow below the snow clouds, generated by cold air outbreak over the relatively warmer East Sea. An intensive and multi-institutional measurement campaign has been launched in 2019 mainly in collaboration with Gangwon Regional Office of Meteorology and National Institute of Meteorological Studies of Korean Meteorological Administration, with a special emphasis on winter snowfall and spring windstorm altogether. The experiment spanned largely from February to April with comprehensive measurements of frequent rawinsonde measurements at a super site (Gangneung) with continuous remote sensings of wind profiler, microwave radiometers and weather radar etc. Additional measurements were added to the campaign, such as aircraft dropsonde measurements and shipboard rawinsonde soundings. One of the fruitful outcomes is, so far, to identify a couple of cold air damming occurrences, featuring lowest temperature below 1 km, which hamper the convergence zone and snow clouds from penetrating inland, and eventually make it harder to forecast snowfall in terms of its location and timing. This kind of comprehensive observation campaign with continuous remote sensings and intensive additional measurement platforms should be conducted to understand various orographic precipitation in the complex terrain like Yeongdong.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.5
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• pp.388-400
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• 2021

Power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technology produces hydrogen by decomposing water from renewable energy (electricity) and the other produces CH4 by reacting hydrogen with CO2. This study is an experimental study to produce CH4 by reacting CO2 of biogas with hydrogen using a 40 wt% Ni-Mg-Al catalyst and a commercial catalyst. Catalyst characteristics were analyzed through H2-TPR, XRD, and XPS instruments of 40% Ni catalyst and commercial catalyst. The effect on the CO2 conversion rate and CH4 selectivity was analyzed, and the activities of a 40% Ni catalyst and a commercial catalyst were compared. As a result of experiment, In the case of a 40 wt% catalyst, the maximum CO2 conversion rate showed 77% at the reaction temperature of 400℃. Meanwhile, the commercial catalyst showed a maximum CO2 conversion rate of 60% at 450℃. When 50% of CO was added to the CO2 methanation reaction, the CO2 conversion rate was increased by about 5%. This is considered to be due to the atmosphere in which the CO reaction can occur without the process of converting to CH4 after forming carbon and CO as intermediates in terms of the CO2 mechanism on the catalyst surface.

• Atmosphere
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• v.31 no.3
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• pp.311-326
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• 2021

To improve the predictability of high-impact weather phenomena around Seoul, where a larger number of people are densely populated, KMA conducted the intensive observation from 22 June to 20 September in 2020 over the Seoul area. During the intensive observation period (IOP), the dropsonde from NIMS Atmospheric Research Aircraft (NARA) and the radiosonde from KMA research vessel Gisang1 were observed in the Yellow Sea, while, in the land, the radiosonde observation data were collected from Icheon and Incheon. Therefore, in this study, the effects of radiosonde and dropsonde data during the IOP were investigated by Observing System Experiment (OSE) based on Korean Integrated Model (KIM). We conducted two experiments: CTL assimilated the operational fifteen kinds of observations, and EXP assimilated not only operational observation data but also intensive observation data. Verifications over the Korean Peninsula area of two experiments were performed against analysis and observation data. The results showed that the predictability of short-range forecast (1~2 day) was improved for geopotential height at middle level and temperature at lower level. In three precipitation cases, EXP improved the distribution of precipitation against CTL. In typhoon cases, the predictability of EXP for typhoon track was better than CTL, although both experiments simulated weaker intensity as compared with the observed data.

• Journal of Aerospace System Engineering
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• v.15 no.3
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• pp.11-19
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• 2021

Contrails are line-shaped clouds formed by the condensation of water vapor from the interaction of exhaust gas from aircraft engines and the high-altitude atmosphere. Contrails are known to aggravate global warming by creating a greenhouse effect by absorbing or reflecting radiation emitted from the Earth. In this study, development of a model that can quantitatively predict the contrail occurrence was conducted for the reduction of contrail, which is likely to form an aircraft certification category in the future. Based on prior research results, a model that can predict the occurrence of contrail between Tokyo and Qingdao was developed, in addition to proposing improved flight altitude that can minimize the occurrence of contrail.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.5
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• pp.376-381
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• 2019

In this work, we evaluated the structural, electrical and optical properties of $Ge_8Sb_2Te_{11}$ and Cu-doped $Ge_8Sb_2Te_{11}$ thin films prepared by rf-magnetron reactive sputtering. The 200-nm-thick deposited films were annealed in a range of $100{\sim}400^{\circ}C$ using a furnace in an $N_2$ atmosphere. The amorphous-to-crystalline phase changes of the thin films were investigated by X-ray diffraction (XRD), UV-Vis-IR spectrophotometry, a 4-point probe, and a source meter. A one-step phase transformation from amorphous to face-centered-cubic (fcc) and an increase of the crystallization temperature ($T_c$) was observed in the Cu-doped film, which indicates an enhanced thermal stability in the amorphous state. The difference in the optical energy band gap ($E_{op}$) between the amorphous and crystalline phases was relatively large, approximately 0.38~0.41 eV, which is beneficial for reducing the noise in the memory devices. The sheet resistance($R_s$) of the amorphous phase in the Cu-doped film was about 1.5 orders larger than that in undoped film. A large $R_s$ in the amorphous phase will reduce the programming current in the memory device. An increase of threshold voltage ($V_{th}$) was seen in the Cu-doped film, which implied a high thermal efficiency. This suggests that the Cu-doped $Ge_8Sb_2Te_{11}$ thin film is a good candidate for PRAM.

• Atmosphere
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• v.29 no.3
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• pp.269-282
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• 2019

While it is important to obtain the accurate information on snowfall data due to the increase in damage caused by the heavy snowfall in the winter season, it is not easy to observe the snowfall quantitatively. Recently, snow measurements using a weighing precipitation gauge have been carried out, but there is a problem that high snowfall intensity results in low accuracy. Also, the observed snowfall data are sensitive depending on wind speed, temperature, and humidity. In this study, a new process of quality control for snow water equivalent (SWE) data of the weighing precipitation gauge were proposed to cover the low accuracy of snow data and maximize the data utilization. Snowfall data (SWE) observed by Pluvio, Parsivel, snow-depth meter using laser or ultrasonic, and rainfall gauge in Cloud Physics Observation Site (CPOS) were compared and analyzed. Applying the QC algorithm including the use of number of hydrometeor particles as reference, the increased SWE per the unit time was determined and the data noise was removed and marked by flag. The SWE data converted by the number concentration of hydrometeor particles are tested as a method to restore the QC-removed data, and show good agreement with those of the weighing precipitation gauge, though requiring more case studies. The three events data for heavy snowfall disaster in Pyeongchang area was analyzed. The SWE data with improved quality was showed a good correlation with the eye-measured data ($R^2$ > 0.73).