• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.69-75
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• 2014

Accurate analysis of fly ash particles is not trivial because of complex nature in physical and chemical properties. SPLITT fractionation (SF) was employed to fractionate the fly ash particles into subpopulations in large quantities. Then the SF-fractions were analyzed by the steric mode of sedimentation field-flow fractionation (Sd/StFFF) for size analysis. The SF-fractions were also analyzed by ICP-OES. The results showed that the fly ash is mainly composed of Fe, Ca, Mg and Mn. No particular trends were observed between the particle size and the concentrations of Fe, Ca, Mg, while Mn, Cu and Zn were in higher concentrations in smaller particles. Sample preparation procedures were established, where the fly ash particles were sieved to remove large contaminants, and then washed with acetone to remove organics on the surface of particles. The sample preparation and analysis methods developed in this study could be applied to other environmental particles.

• Journal of Environmental Impact Assessment
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• v.22 no.2
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• pp.135-145
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• 2013

The recycling of coal bottom ash generated from coal power plants in Korea has been limited due to heterogenous characteristics of the materials. The most common management option for the ash is disposal in landfills (i.e. ash pond) near ocean. The presence of large coarse and fine materials in the ash has prompted the desire to beneficially use it in an application such as fill materials. Prior to reuse application as fill materials, the potential risks to the environment must be assessed with regard to the impacts. In this study, a total of nine test cells with bottom ash samples collected from pretreated bottom ash piles and coal ash pond in a coal-fired power plant were constructed and operated under the field conditions to evaluate the leachability over a period of 210 days. Leachate samples from the test cells were analyzed for a number of chemical parameters (e.g., pH, salinity, electrical conductance, anions, and metals). The concentrations of chemicals detected in the leachate were compared to appropriate standards (drinking water standard) with dilution attenuation factor, if possible, to assess potential leaching risks to the surrounding area. Based on the leachate analysis, most of the samples showed slightly high pH values for the coal ash contained test cells, and contained several ions such as sodium, potassium, calcium, magnesium, chloride, sulfate, and nitrate in relatively large quantities. Three elements (aluminum, boron, and barium) were commonly detected above their respective detection limits in a number of leachate samples, especially in the early leaching period of time. The results of the test cell study indicate that the pollutants in the leachate from the coal ash test cells were not of a major concern in terms of leaching risk to surface water and groundwater under field conditions as fill materials. However, care must be taken in extending these results to actual applications because the results presented in this study are based on the limited field test settings and time frame. Structural characteristics and analysis for coal bottom ash may be warranted to apply the materials to actual field conditions.

• Journal of Mechanical Science and Technology
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• v.15 no.6
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• pp.804-812
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• 2001

A triboelectrostatic separation system for removing unburned carbon from coal fly ash is designed and evaluated. Fly ash from a coal-fired power plant is used as an accepted additive in concrete where it adds strength, sulfate resistance and reduced cost, provided acceptable levels of unburned carbon are maintained. Unfortunately, unburned carbon in coal fly ash absorbs some of other additives and reduces the concrete strength. This paper describes to investigate dry triboelectrostatic process to separate unburned carbon from coal fly ash and utilize it into economically valuable products. The laboratory-scale triboelectrostatic separation system consists of a particle feeding system, a tribocharger, a separation chamber, and collection systems. Particles of unburned carbon and fly ash can be imparted positive and negative surface charges, respectively, with a copper tribocharger due to differences in the work function values of the particles and the tribocharger, and can be separated by passing them through an external electric field. Results showed that fly ash recovery was strongly dependent on the electric field strength and the particle size. 70wt% of fly ash containing 6.5wt% of carbon contents could be recovered at carbon contents below 3%. The triboelectrostatic separation system showed a potential to be an effective method for removing unburned carbon from coal fly ash.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.03a
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• pp.1032-1039
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• 2010

Based on the proven feasibility of bottom ash and tire shred-soil mixtures as lightweight fill materials, tire shred-bottom ash mixtures were suggested as a new lightweight fill material to replace the conventional construction material with bottom ash. Therefore, we carried out the laboratory test, field compaction test and performance test of large scale embankment in order to evaluate their suitability for the use of lightweight fill materials in the before studies. We could verified that the ash, tire-shred and the mixture are able to be the useful materials as light fill materials. In this study, we built real scale embankment with RBA(Reclamated Bottom Ash), TRBA(Tire shred-Reclamated Bottom Ash mixture), WS(Weathered Soil), BA(Bottom Ash screened by 5mm sieve) for monitoring the behavior such as settlement, lateral displacement and water content change. Furthermore, we are examining the ground water quality in the surrounding area of the test embankment.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.4
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• pp.85-92
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• 2014

The disposal of the paper mill sludge and the paper mill sludge ash become more important issue, because the environment regulation becomes more strict. In this study, the new mulching system was developed by using the paper sludge ash. The soil surface hardening mechanism for mulching with paper sludge ash, red clay and coal ash was evaluated. Since the CaO in the paper sludge ash provided the harden structure with water, the surface hardening mulching structure could cover the field surface and prevent the germination of weeds. More than 50 w.t.% of red clay and 10 w.t.% of paper sludge ash were required to create the solid soil surface structure for mulching. The field test with the new soil surface hardening mulching system for three months showed the generation of weeds could successfully be inhibited by the system.

• Journal of The Korean Society of Agricultural Engineers
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• v.57 no.6
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• pp.99-105
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• 2015

Bottom ash and fly ash are by-product from thermoelectric power plants. Fly ash is recycled to various field. However, though an output of bottom ash have increased each year, most of them is reclaimed in ash landfill. It is necessary to find a solution that bottom ash is recycled economically and know characteristics of bottom ash to recycle. It is goal to investigate engineering properties of bottom ash, especially the particle breakage, to recycle that. Bottom ash was crushed by impact method according to compaction energy and then compared with or original sample and crushed it in terms of particle size distribution and characteristics of strength. In result, after crushed it, particle finer was increased, especially 2~0.85 mm size, than original. It was displayed a tendency that internal friction of crushed sample was decreased but cohesion of it was not. Therefore, it is important to investigate the engineering properties of bottom ash in terms of the particle breakage to use construction materials for various field.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.275-280
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• 2002

To study of high volume fly -ash concrete replace cement and fine aggregate together. Proportion consideration economy cost and performance improve replacement high volume fly-ash. Experimentation study of high-strength which cement about fly-ash replacement maximum 50%Flash concrete tested slump, air contest, setting and Hardening concrete tested day of age 1, 3, 7, 28, 91 compression strength in underwater curing. Purpose of study is consultation materials in field that variety of fly ash replacement concrete mix proportion comparison and valuation.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.858-865
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• 2009

Based on the proven feasibility of bottom ash and tire shred-soil mixtures as lightweight fill materials, tire shred-bottom ash mixtures were suggested as a new lightweight fill material to replace the conventional construction material with bottom ash. Therefore, we carried out the laboratory test, field compaction test and performance test of large scale embankment in order to evaluate their suitability for the use of lightweight fill materials in the before studies. We could verified that the ash, tire-shred and the mixture are able to be the useful materials as light fill materials. In this study, we estimated the long-term compressible settlements for 6 materials such as TA(Tire-Bottom Ash mixture), TBA(Tire-Bottom Ash<5mm) mixture, TWS(Tire-Weathered Soil mixture), Bottom Ash, Bottom Ash(<5mm), Weathered soils.

• Journal of the Korean GEO-environmental Society
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• v.6 no.1
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• pp.15-21
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• 2005

In this study, the utilization of coal-ash and phosphogypsum was considered as the evapotranspiration final landfill cover(ET cover) material. Cover material considered was the mixture of the weathered granite soil, coal-ash and phosphogypsum and so we sequentially performed the leaching test, column test and field model test to investigate the environmental effects of mixtures of coal-ash and phosphogypsum. In the leaching test, all materials had lower heavy metal concentration than the regulated threshold values. The column test and the review of related regulations were carried out to determine the optimum mixing ratio(OMR) and OMR was soil(4):coal-ash(1): phosphogypsum(1) on the volume base, which was applied to field model test. Field model tests were continued from February to June, 2004 in the soil box that was constructed with cement block. It was verified that coal-ash and phospogypsum mixed with soil was safe environmentally and the mixture of both wastes could improve the water retention capacity of cover materials.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.676-681
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• 2000

This paper covers durability and field application of marine concrete which have been enhanced the resistance against deterioration in seawater. Fly ash concrete is applied to make the concrete with good durability. It is well known fly ash in concrete has a good performance preventing fro a sulphate attack and a steel corrosion. Several durability tests were performed to find characteristics of marine concrete which is proposed in this paper comparing with normal concrete. Field application was executed to compare results with laboratory test and to give a reliability to engineers. The project was supported by Ministry of Marine Affairs and Fisheries for two years.