• Title/Summary/Keyword: Arachidic acid

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$\pi$-A Isotherm for LB Film Deposition (LB 막 제작을 위한 $\pi$-A Isotherm)

  • Song, Il-Seok;Kim, Tae-Wan;Shon, Byoung-Chung;Park, Hyuk;Kang, Dou-Yol
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.864-867
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    • 1992
  • This paper describes optimum conditions for depositing Langumuir Blodgett(LB) films. $\pi$-A isotherm characteristics were studied with the following species, $C_{18}$-Quinolium(TCNQ), $C_{22}$-Quinolium(TCNQ), Azobenzene, Arachidic Acid, by varing length of alkyl chains, temperacture, pH, spreading amount, barrier moving speed and etc. We have observed the change of $\pi$-A isotherm depending on the above variations. From there we investigate the depositing conditions of LB films for each material.

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The investigation into Merocyanine Dye J-aggregation of characteristic by STM (STM을 이용한 Merocyanine Dye J-aggregation 특성관찰)

  • Yang, Chang-Heon;Lee, Ji-Yoon;Choi, Won-Suk;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2008.05a
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    • pp.165-166
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    • 2008
  • We investigate characteristics of J-aggregation as take advantage of LB technic. In order to confirm the applications possible for the molecular electronic device, the morphological properties of merocyanine dye were investigated by AFM. $\pi$-A curves investigated the surface pressure of the LB film from a liquid to a solid state ranged between 90 and 100 mN/m. We observed aggregation and it's characteristics by using visible reflection spectroscopy. We have observed morphology of merocyanine dye on gold surface by STM. focuses on results obtained in mercocyanide dye of J-aggregation. When LB films of merocyanine dye are mixed with arachidic acid, J-aggregate formation is exhibited. J-aggregate formation has been serving as typical systems in revealing the physical and structural aspects of nano-sized molecular aggregates constructed as muiltilayers.

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Emission Properties of EL Device Fabricated by LB Method (LB법으로 제작한 백색 EL소자의 발광특성)

  • 김주승;이경섭;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.351-354
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    • 2001
  • We fabricated organic electroluminescent(EL) devices with mixed emitting layer of poly (N- vinylcarbazole) ( PVK) , 2,5-bis (5-tert-butyl -2- benzoxaBoly) thiophene ( BBOT) , N,N-diphenyl-N,N- (3-methyphenyl) -1,1-biphenyl-4, 4-thiamine(TPD) and poly(3-hexylthiophene) (P3HT) deposited by LB(Langumuir-Boldgett) method. From the AFM(atomic force microscope) images, the monolayer containing 30% of AA(arachidic acid) showed a roughness value of 28$\AA$. In the voltage-current characteristics of ITO/Emitting layer/BBOT/LiF/A1 devices, current density much smaller than that of the spin-coated devices having a same thickness.

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A Study for the LB Film Deposition of Azobenaene Derivative (Azobenzene 유도체의 LB막 누적을 위한 기초 연구)

  • Lee, Chang-Keun;Choi, Kang-Hoon;Shin, Dong-Myung;Kang, Don-Yol
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1376-1378
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    • 1994
  • Azobenzene derivative is so stiff that monolayer cannot be formed on the subphase. To form a monolayer on the subphase, azobenzene derivative was mixed arachidic acid. It didn't form a monolayer, either. The mixture of azobenzene derivative and L-${\alpha}$-phosphatidylcholine generated a monolayer on the wafer subphase. Thickness of LB film layered at 30 mN/m was about $70{\AA}$. The polarized UV-visible absorption spectra of the mixture exhibited a dichroic ratio of azobenzene derivative and L-${\alpha}$-phosphatidylcholine.

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Inelastic Electron Tunneling Spectroscopy of 1-layer Arachidicacid films using a Polyimide barrier (Polyimide 터널 장벽을 이용한 Arachidicacid 단분자막의 비탄성 터널 스펙트라)

  • Lee, Won-Jae;Kang, Dou-Yol;Iwamoto, Mitsumasa
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.234-236
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    • 1994
  • We fabricated Au/PI/Pb and Au/PI/1-layer Arachidic acid/Pb structures in order to electron transport properties through the junctions. It was found that 9-layer PI LB films function as a good tunneling barrier from the I-V properties. And several peaks originating in the vibrational modes of the constituent molecules of 1-layer arachidicacid LB films were clearly observed in $d^2V/dI^2-V$ curves.

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Different Adsorption Behavior of Rare Earth and Metallic Ion Complexes on Langmuir Monolayers Probed by Sum-Frequency Generation Spectroscopy

  • Sung, Woongmo;Vaknin, David;Kim, Doseok
    • Journal of the Optical Society of Korea
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    • v.17 no.1
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    • pp.10-15
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    • 2013
  • Adsorption behavior of counterions under a Langmuir monolayer was investigated by sum-frequency generation (SFG) spectroscopy. By comparing SFG spectra of arachidic acid (AA) Langmuir monolayer/water interface with and without added salt, it was found that the simple trivalent cation $La^{3+}$ adsorbed on AA monolayer only when the carboxylic headgroups are charged (deprotonated), implying that counterion adsorption is induced by Coulomb interaction. On the other hand, metal hydroxide complex $Fe(OH)_3$ adsorbed even on a charge-neutral AA monolayer, indicating that the adsorption of iron hydroxide is due to chemical interaction such as covalent or hydrogen bonding to the headgroup of the molecules at the monolayer.

Physicochemical Properties and Antioxidant Capacities of Different Parts of Ginger (Zingiber officinale Roscoe) (생강(Zingiber officinale Roscoe) 부위별 이화학적 특성 및 항산화 활성)

  • Lee, Hye-Ryun;Lee, Jong-Hun;Park, Cheol-Seong;Ra, Kyung-Ran;Ha, Jin-Sook;Cha, Mi-Hyun;Kim, Se-Na;Choi, Youngmin;Hwang, Jinbong;Nam, Jin-Sik
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.9
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    • pp.1369-1379
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    • 2014
  • The physicochemical characteristics and antioxidant activities of leaf, stem, and root of ginger (Zingiber officinale R.) were determined. Nutrient composition, reducing sugar, saponin, mineral, heavy metal, total phenolic and total flavonoid contents, and antioxidant activities based on DPPH radical scavenging and FRAP assay were measured. Catechins, gingerols, shogaols, and capsaicin compositions were also determined by HPLC. The contents of water, proteins, fats, carbohydrates, fiber, and ash from ginger root were 6.4, 6.8, 3.2, 65.4, 7.3, and 18.2%, respectively. Crude fiber contents of leaf and stem were 4~5 times higher than those of root (P<0.05), and reducing sugar content of stem was about 3 times higher than those of root. Crude saponin contents were in the order of stem

Electrochemical Study of Functional Organic Monomolecular Film prepared by Langmuir-Blodgett Method (기능성 유기 LB단분자막의 전기화학적 연구)

  • 박수길;임기조;전일철;이주성
    • Journal of Surface Science and Engineering
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    • v.28 no.1
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    • pp.34-45
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    • 1995
  • An amphiphilic nitroxide radical(2,2'6,6'-tetramethyl-4-octadecyioxy-1-piperidinyloxyl, TEMOPO) or mixture of TEMOPO and arachidic acid(Icosanoic acid, AA), was spread on water surface by the Langmuir-Blodgett(LB) method and surface pressure-area curve was measured. Such monolayer films of TEMOPO were transferred onto surfaces of photo transferable tin oxide electrodes(PTTO) by the LB method under various surface pressure with the transfer ratio of larger than 0.95 at the surface pressure higher than 15mN/m. The electrochemical effect of functional nitroxy radical monolayer onto semi-conductive electrode to electrolyte have been investigated by using LB method. Cyclic voltammetry technique was used for the electrochemical behavior measurement of TEMOPO monolayer onto the PTTO in 0.18 mo1/$dm^3$ $H_2SO_4$ solutions. The shape of voltammograms was found to change from one electrode to another. The amount of charge for the oxidation and the re-reduction of the cation to TEMOPO were evaluated from graphical integration. The amounts of charge were always smaller than those predicted from the $\pi$-$\sigma$ curves though the transfer ratio was unity. The poor reproducibility of the cyclic voltammograms was improved by the mixing with AA. Structure and arrangement of monomolecular layer on water surface and electrode were studied. Characteristics of monolayer film applied for the mediation reaction was also discussed by electrochemical method.

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Breakdown Voltage and Electrical Characteristics of Organic Thin Film (유기박막의 파괴전압과 전기특성)

  • Song, Jin-Won;Kang, Yong-Chul;Kim, Hyung-Gon;Lee, Woo-Sun;Chung, Hun-Sang;Chang, Hee-Dong;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1497-1499
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    • 2000
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 30 [mN/m]. LB layers of Arac. acid deposited by LB method were deposited onto y-type silicon wafer as y-type film. In processing of a device manufacture. we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/arachidic acid/Al. the number of accumulated layers are 9$\sim$21. Also. we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Carcass traits, meat quality, and fatty acid profiles of broiler chickens fed diets with increasing inclusion levels of microwave-dried black soldier fly (Hermetia illucens) larvae meal

  • Byeonghyeon Kim;Minji Kim;Hye Ran Kim;Jin Young Jeong;Hyunjung Jung;Seol Hwa Park
    • Korean Journal of Agricultural Science
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    • v.49 no.2
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    • pp.249-257
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    • 2022
  • The present study investigates the effects of different inclusion levels of a microwave-dried black soldier fly (Hermetia illucens) larvae meal (HILM) on the carcass characteristics, breast meat quality, and fatty acid profiles of leg meat in broiler chickens. A total of 150 male broilers were randomly assigned to three dietary treatment groups (10 replicates·treatment-1 and 5 birds·replicate-1). HILM was included at increasing levels (0, 2, and 4%; CON, 2HILM, and 4HILM, respectively) in diets formulated for three feeding phases: starter (1 - 7 d), grower (7 - 21 d), and finisher (21 - 35 d). One bird per replicate was slaughtered at d 35; the carcasses and organs were weighed, and breast and leg meats were excised for a meat analysis. A linear decrease (p < 0.01) was observed for live and carcass weights for the whole period of the experiment, with no difference between the CON and 2HILM groups. Broilers fed HILM showed no significant differences in meat quality parameters, except for an increase in yellowness (b*) in the 2HILM and 4HILM groups compared to the CON group (p < 0.01). With an increase in the HILM inclusion level, the proportion of saturated fatty acids (SFAs) such as lauric, myristic, stearic, arachidic, and heneicosylic acids showed a linear increase (p < 0.01); however, total SFA, monounsaturated fatty acid, and polyunsaturated fatty acid did not differ among the dietary treatments. Thus, microwave-dried HILM can be considered as a possible alternative ingredient to soybean meal in broiler diets up to a 2% inclusion level.