• Title/Summary/Keyword: Anti-corrosive property

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Electrochemical Characteristics of Marine Anti-Corrosive Coating under Shear Flows (전단유동 하에서의 선박용 방식도막의 전기화학 특성)

  • Park, Hyun;Park, Jin-Hwan;Ha, Hyo-Min;Chun, Ho-Hwan;Lee, In-Won
    • Journal of the Society of Naval Architects of Korea
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    • v.43 no.2 s.146
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    • pp.268-274
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    • 2006
  • Analysis has been made of the anti-corrosive property of organic coating under the shear stress of the flow by means of AC impedance method. Marine anti-corrosive painted panels were placed in the water channel with varying flow rate, thereby experiencing varying flow shear stress on the surfaces. The velocities of the salt water were ranged from 1.48 to 5.2 m/s and the coating thickness of from $70{\mu}m\;to\;140{\mu}m$. For all coating thicknesses investigated, the poorer anti-corrosive property and the lower adhesion strength have been found for the higher shear stress. It has been found that the shear stress accelerates the aging of organic marine coatings.

Evaluation of Life Time for Anti-Corrosive Methods for Marine Steel Sheet by Cyclic Corrosion Test (실내 가속부식시험을 통한 해양 강관합성 말뚝의 방식 기법 수명 평가)

  • Park, J.W.;Lee, J.G.;Lee, K.W.;Kim, J.H.;Jung, M.K.;Lee, J.H.
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.243-250
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    • 2009
  • When a steel sheet pipe applied to marine environment, an anti-corrosive coating should be treated to obtain long-term life-time for steels, especially, splash zone. Although anti-corrosive property of coatings is required to be tested in real marine environment, it is difficult because of long test time such as 20 years or more time. Therefore, we used cyclic corrosion tester in a laboratory, which has similar conditions with salt-dry-wet process such as real marine environment. Anti-corrosive properties of the coatings and two steels were tested their anti-corrosive properties under cyclic corrosion test conditions(KS D ISO 14993) and the results were compared with estimate life-time in real marine environment. According to cyclic corrosion test, accelerated corrosive factor of each anti-corrosive coating was investigated accelerated corrosive factor from impedance with EIS method. Accelerated corrosive factor of type SS400 carbon steel and A690 was also investigated their accelerated corrosive factor from the regression curves of weigh loss results. One of the anti-corrosive coatings showed about 50 years life-time compared with standard sample life-time. Carbon steel SS400 showed from 0.1 mm/yr to 0.06 mm/yr as its corrosion rate.

A Study on the Aging Behavior of Ship Organic Coating by the Flow Induced Shear Stress (유동 전단응력에 의한 선박 유기도막의 열화거동 연구)

  • Park Hyun;Park Jin-Hwan;Ha Hyo-Min;Chun H.H.;Lee In-Won
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.1 s.24
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    • pp.9-14
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    • 2006
  • Analysis has been made of the anti-corrosive property of organic coating under the shear stress of the flow by means of AC impedance method. Marine anti-corrosive painted panels were placed in the water channel with varying flow rate, thereby experiencing varying flow shear stress on the surfaces. The velocities of the salt water were ranged from 1.48 to 5.2 m/s and the coating thickness of from $70{\mu}m\;to\;140{\mu}m$. For all coating thicknesses investigated, the poorer anti-corrosive property and the lower adhesion strength have been found for the higher shear stress. It has been found that the shear stress accelerates the aging of organic marine coatings.

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Development of anti-corrosive coating technique for alloy plated steel sheet using silane based organic-inorganic hybrid materials (Silane계 유무기 하이브리드 적용 합금도금강판 내식성 향상 코팅 기술 개발)

  • Park, Jongwon;Lee, Kyunghwang;Park, Byungkyu;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.6
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    • pp.295-303
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    • 2013
  • Silane surface treatments have been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. The silane performance is comparable to, or in some cases better than, that of chromate layers. Based on the tetra-ethylorthosilicate(TEOS) and methlyl trieethoxysilane(MTES), inorganic sol was synthesized and formed hybrid networks with $SiO_2$ nano particle and polypropylene glycol(PPG) on Zn alloyed steel surface. According to SST results, addition of 10nm and 50nm $SiO_2$ nanoparticle in synthesized solution improved anti-corrosion property by its shear stress relaxation effect during curing process. Also, SST results were shown that anti-corrosive property was affected by the amounts of organic compounds.

Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings (합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅)

  • Park, Jongwon;Lee, Kyunghwang;Na, Hyunju;Park, Byungkyu;Nam, Yeungsub;Hong, Shinhyub
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.27-33
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    • 2013
  • According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

Synthesis of Ceramic Protective Coatings for Chemical Plant Parts Operated in Hi-temperature and Corrosive/Erosive Environment

  • Son, M.C.;Park, J.R.;Hong, K.T.;Seok, H.K.
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.33-38
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    • 2005
  • Some feasibility studies are conducted to produce an advanced ceramic coating, which reveals superior chemical and mechanical strength, on metal base structure used in chemical plant. This advanced coating on metallic frame can replace ceramic delivery pipe and reaction chamber used in chemical plant, which are operated in hi-temperature and corrosive/erosive environment. An dual spraying is adopted to reduce the residual stress in order to increase the coating thickness and the residual stress is estimated by in-situ manner. Then new methodology is tried to form special coating of yttrium aluminum garnet(YAG), which reveals hi-strength and low-creep rates at hi-temperature, superior anti-corrosion property, hi-stability against Alkali-Vapor corrosion, and so on, on iron base structure. To verify the formation of YAG during thermal spraying, XRD(X ray diffraction) technique was used.

Mechanical Properties of PMMA / Alumina Composites Fused by Heat Treatment (용융 열처리한 PMMA/Alumina 복합체의 기계 특성)

  • Kim, D.J.;Ryu, S.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.3
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    • pp.120-125
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    • 2018
  • The PMMA composited material mixed with alumina studied to find the optimal condition, the adequate ratio of mixing, for the associated mechanical properties such as anti-corrosive, weatherproof performance. The 80% of hardness and 52% of scratch coefficient improved according to increasing ratio of alumina, which is mostly 3 times higher than that of pure PMMA, on other hand 16% of tensile strength and 35% of flexural strength has lost while alumina was adding in. The most proper ratio, having the best availability in substantial production, of composite between pure PMMA and alumina is determined as 93 wt. % vs 7 wt. %. Results of related five properties had estimated by using of a pentagram.

Minimization of Friction and Wear Damage of Marine Structures by Using the Advanced Anti-corrosive Composite Materials (첨단복합방식재를 이용한 각종 선박구조물의 마찰마모손상의 최소화)

  • 김윤해;김진우
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.5 no.2
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    • pp.15-26
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    • 1999
  • The marine structures with sea water cooling system always expose to the oceanic atmosphere. Therefore, the protection of the equipments is very important. To investigate the effectiveness of advanced composite materials for the application in offshore environments, the tensile test, hardness test, undercutting property test, permeance test and the friction and wear test were carried out by using various applicable coating materials. The main results obtained can be summarized as follows; 1. The micro-hardness of the Archcoat 502B showed the highest value. 2. The coefficient of friction of the Rigspray coating at the speed of 2.21m/sec showed the lowest value, and that of the Archcoat 502B coating at 1.08m/sec and 0.18m/sec indicated the lowest values. 3. The wear mass at the speed of 0.18m/sec and 1.08m/sec in dry condition showed the smallest values. 4. The Archcoat 502B coating is fitted to the dynamic instruments in the range of low speed and middle speed. Rigspray coating is fitted to the dynamic instruments in the range of high speed. 5. The wear mass of five kinds of coating materials at the range of low speed was very small, and those of the Archcoat S02B, Archcoat 402B and Rigspray coating at high speed range were quitely smaller than those of the Modified Epoxy and Tar Epoxy.

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A Study on High Temperature Tensile Property of Inconel 625 for Petroleum Application by Flux cored Arc Welding Process (석유시추용 인코넬 625강의 FCAW용접에 의한 고온인장 특성에 관한 연구)

  • PARK KEYUNG-DONG;AN DO-KEYUNG;JIN YOUNG-BEOM
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.352-355
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    • 2004
  • Inconel 625 is useful in variety of industrial applications because of the resistance to attack in various corrosive media at temperatures from $200^{\circ}C$ to over $1090^{\circ}C$, in combination with good law- and high temperature mechanical strength. Rencently, this material is also used widely in offshore processing piping in order to extend the maintenance tenn and improve the quality of anti-corrosion. In general, high quality weldments for this material are readily produced by commonly used processes. Not all processes are applicable to this material group, Ni-alloys. Metallurgiad characterictics or the unavailability of matching, position or suitable welding processes. Nowadays, the flux cored wire is developed and applied for the better productivity in several welding position including the vertical position. in this study, the weldability and weldment characteristics of inconel 625 are considered in FCAW weld associated with the several shielding gases($80\%Ar\;+\;20\%\;CO_2,\;50\%Ar\;+\;50\%\;CO_2,\;100\%\;CO_2$) in viewpoint of welding productivity.

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The Research and Application of Protective Coating for PCCP

  • Lin, Zhu;Xu, Cuizhu;Zhang, Li;Fan, Yunpeng;Zhang, Qibin
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.265-268
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    • 2008
  • Prestressed Concrete Cylinder Pipe(PCCP) had became one of the dominating kinds of pipes substituting for steel pipes because of its unique feature (high intensity, high pressure and high leakproofness). PCCP was produced firstly by Bonna company in France. By the end of 20th century, there were over 19000 km of this product installed in America. PCCP was introduced from Ameron company by Shandong Eletric Power Pipeline Engineering Company in 1988. As the statistical data in 2002, 700 km of PCCP had been applied in China, and the application trended towards rapid increase.Since prestressing wire would be corroded in environment, Several accidents due to the breakdown of pipe had happened. Consequently the external wall of pipe should be covered with protective coatings. There was a lack of technical study in corrosion and control of PCCP, because PCCP had been applied for a short time in China. in order to ensure the service life of PCCP, we have developed a kind of protective coating for concrete pipe, which had high intensity and anti-corrosive property with convenient applicability. The physical and chemical properties, painting technology and field application of this coating was introduced in the paper, at the same time, the future of external protective coating for PCCP was looked into.