• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.229-232
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• 1998

Recently it has become general to use the inhibitor with a view to protecting corrosion of rebars in concrete. As the inhibitors used in construction works are almost made in America or Japan, we immediately need to begin home production of inhibitors. In this paper, to estimate the domestic anodic inhibitor of nitrite in comparison with foreign made inhibitor we made some fundamental experiments of setting time, slump and compressive strength. Besides, we analysed the effect of corrosion protection of inhibitor on the ground of corrosion current, resistance to chloride penetration and diffusion of chloride ingress in concrete.

• 한국화재소방학회논문지
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• 제11권3호
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• pp.15-23
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• 1997

In this study, the alumina for gas sensor was prepared by anodic oxidation. It was stable thermally and chemically, and pore diameter and pore distribution was uniform. And the shape of pore was cylinderical. The aluminum plate was carried out by the thermal oxidation, chemical polishing and electropolishing pretreatment. The pore diameter, pore size distribution, pore density and thickness of alumina was observed with the change of reaction temperature, electrolyte concentration and current density. As a results, It was able to use for carrier because alumina which was prepared by anodic oxidationhas uniform pore size distribution.

• 한국환경과학회지
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• 제23권10호
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• pp.1745-1753
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• 2014

Sediment microbial fuel cell (SMFC), equipped with Zn, Al, Cu, Fe or graphite felt (GF) anode and marine sediment, was performed. Graphite felt was used as a common cathode. SMFC was single chambered and did not use any redox mediator. The aim of this work was to find efficient anodic material. Oxidation reduction potential (ORP), cell voltage, current density, power density, pH and chemical oxygen demand (COD) were measured for SMFC's performance.. The order of maximum power density was $913mWm^{-2}$ for Zn, $646mWm^{-2}$ for Fe, $387.8mWm^{-2}$ for Cu, $266mWm^{-2}$ for Al, and $127mWm^{-2}$ for graphite felt (GF). The current density over voltage was found to be strongly correlated with metal electrodes, but the graphite felt electrode, in which relatively weaker electricity was observed because of its bio-oriented mechanism. Metal corrosion reactions and/or a complicated microbial electron transfer mechanism acting around the anodic compartment may facilitate to generate electricity. We presume that more sophisticated selection of anodic material can lead to better performance in SMFC.

• 산업식품공학
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• 제21권2호
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• pp.180-186
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• 2017

Salt, as food, is the most essential element for human survival due to its significant physiological functions. Here, we report the simultaneous detection of Pb and Cd in sea salt by square wave anodic stripping voltammetry (SWASV). Stripping voltammetric measurements were conducted using a manufactured rotating disk electrode system (MRDES). The detection limit was $3.6{\pm}0.18{\mu}gL^{-1}$ for Pb and $3.9{\pm}0.37{\mu}gL^{-1}$ Cd in NaCl solution. When the pH increased from 5.5 to 8.5, the peak currents of Pb and Cd decreased. At a pH of 8.3, the ratio of the current drop compared with that at a pH of 5.5 was 0.6 for Pb and 0.73 for Cd. The concentrations corrected by the current drop are in agreement with the concentrations obtained with ICP (inductively coupled plasma). This system demonstrates the reliable detection of heavy metals in aqueous media and, at a high $Na^+$ concentration, the successful application for the determination of Pb and Cd in sea salts.

• Journal of Advanced Marine Engineering and Technology
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• 제29권5호
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• pp.519-525
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• 2005

An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint(DFT:25um) was carried out for 5 kinds of heavy anticorrosive paints such as high solid epoxy(HE), solvent free epoxy(SE). tar epoxy(TE), phenol epoxy(PE). and ceramic epoxy(CE). Corrosion current densities obtained by Tafel extrapolation method from anodic and cathodic polarization curves didn't correspond with the values obtained by AC impedance measurement, however, the values of polarization resistance obtained from the cyclic voltammogram showed a good tendency corresponding well with the values of AC impedance measurement. Futhermore there was a good correlation against the corrosion resistance evaluation between passivity current density of the anodic polarization curve and diffusion limiting current density of the cathodic polarization curve. And corrosion resistance increased with corrosion potential shifting to noble direction. From the results discussed above. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paints.

• 대한금속재료학회지
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• 제46권6호
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• pp.370-376
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• 2008

The formation of anodic oxide film of titanium (Ti) was studied at a variety of electrolyte concentrations and current density to clarify their effects on morphology, microstructure and composition of Ti oxide layer. For the analysis of the Ti oxide films, a scanning electron microscopy (SEM), X-ray diffractometer (XRD), and X-ray photoelectron spectroscopy (XPS) were used. The results showed that the concentration of phosphoric acid played a crucial role in the crystalline structure of the Ti oxide layer while the current density gave a critical effect on the thickness and diameter of its pore. In particular, the crystalline anatase phase with a thickness larger than $2{\mu}m$, which is quite desirable for a dental implant application, could be readily prepared at the phosphoric acid concentration of 0.5 M and current density higher than $2.0A/dm^2$.

• Corrosion Science and Technology
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• 제21권2호
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• pp.89-99
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• 2022

A versatile method for performing non-cyanide electroless gold plating using thiomalic acid (TMA) as a complexing agent and 2-aminoethanethiol (AET) as a reducing agent was investigated. It was found that TMA was an excellent complexing agent for gold. It can be used in electroless gold plating baths at a neutral pH with a high solution stability, makes it a potential candidate to replace conventional toxic cyanide complex. It was found that one gold atomic ion could bind to two TMA molecules to form the [2TMA-Au⁺] complex in a solution. AET can be used as a reducing agent in electroless gold plating solutions. The highest current density was obtained at electrode rotation rate of 250 to 500 rpm based on anodic and cathodic polarization curves with the mixed potential theory. Increasing AET concentration, pH, and temperature significantly increased the anodic polarization current density and shifted the plating potential toward a more negative value. The optimal gold ion concentration to obtain the highest current density was 0.01 M. The cathodic current was higher at a lower pH and a higher temperature. The current density was inversely proportional to TMA concentration.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.429-429
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• 2009

Nanoporous anodic alumina membranes (NAAM) with high-density through-hole pores fabricated by hard anodization of aluminum in 0.3 M oxalic acid under the applied voltage of 40 (mild anodization), 80, 100, 120 and 140 V were investigated. The current-time responses monitored using a PC-controlled anodization cell and the corresponding pore structures attainable from field-enhanced scanning electron microscopy (FE-SEM) were analyzed in order to establish the optimum fabrication process. The nanoporous structure can be produced for all the voltage conditions, while the stabilized through-hole pore formation seems to occur at 40, 80 and 140 V. The growth rate under 140 V hard anodization was over 30 times higher than under 40 V mild anodization (1.5 um/hr).

• 한국재료학회지
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• 제14권9호
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• pp.664-669
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• 2004

Anodic aluminum oxide (AAO) with pores of various diameter, density, and thickness values was obtained through control of the anodization parameters including voltage, temperature, pore widening time, anodization time, etc. The pore diameter was controlled by a pore widening in an etchant, and alumina templates having stepped nano-channels were fabricated by repetition of anodization and pore widening processes. Stepped carbon nanotubes (CNTs) were then grown on the stepped AAO templates by pyrolysis of acetylene without using the catalyst. High-resolution transmission electron microscopy images revealed that CNTs have a multi-wall structure made of graphite flakes of several nm sizes. The current-voltage characteristic of the sloped and linear CNTs were also examined.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2002년도 학술대회논문집
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• pp.207-211
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• 2002

Anodizing film was prepared by anodic oxidation of pure aluminum(purity > 99.50) using DC power supply for constant current mode in an electrolytic solution of surface of sulfuric acid. Effects of pre-treatment process such as chemical polishing, acid cleaning, alkali etching before anodic oxidation, were studied to microstructures and surface morphologies. A roughness on surface of anodizing film had to be decreased for amorphous phase by anodic oxidation. A roughness on surface of anodizing film decrease as annealing temperature increased in chemical polishing.