• 비파괴검사학회지
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• 제22권3호
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• pp.267-274
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• 2002

본 연구는 Cr-Mo-V강의 다양한 분극특성들을 이용하여 비파괴적으로 재질열화를 평가하는 전기화학적 기법에 대해서 서술한 것이다. 사용된 전기화학적 기법은 스테인레스강의 열 이력에 의해 주로 야기되는 강화원소 결핍 영역에서의 예민화 그리고 부식속도를 평가하기 위해 널리 사용되는 양극분극 시험법이다. 재질열화 평가는 $10{\times}10{\times}0.5mm$ 크기의 시험편을 사용하는 미소역학 시험법으로 잘 알려진 SP시험에 의해 수행되었다. $630^{\circ}C$에서 1,000hrs 시효된 재료가 가장 높은 재질 열화도 ${\Delta}[DBTT]_{SP}$을 보였으나, 2,000hrs 그리고, 3,000hrs 시효된 재료는 시효 시간이 증가함에 따라 ${\Delta}[DBTT]_{SP}$의 감소를 보였다. 전류밀도의 차 $({\Delta}I_{FP},\;{\Delta}I_{SP})$가 1,000hrs 시효시간까지는 증가하였고, 그 이후의 시효시간에서는 시효시간의 증가와 더불어 감소됨이 관찰되었다. 이 같은 결과는 시효재료에 대한 경도의 거동과 일치하였다. 덧붙여, ${\Delta}[DBTT]_{sp}$는 ${\Delta}I_{FP}$ 및 ${\Delta}I_{SP}$와 같은 전기화학적 분극특성들과 좋은 상관관계를 가지고 있음을 알 수 있었다.

• 센서학회지
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• 제7권6호
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• pp.426-431
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• 1998

본 논문에서는 THAH/IPA/pyrazine 용액에서의 전기화학적 식각정지특성을 기술한다. THAH/IPA/pyrazine 용액에서의 n-형과 p-형의 Si에 대한 I-V 곡선이 얻어졌다. p-형 Si에 대한 OCP(개방회로전압)과 PP(보호막생성 전압)은 각각 -1.2 V와 0.1 V이고, n-형에 대해서는 -1.3 V와 -0.2 V로 각각 나타났다. p-형과 n-형 Si 모두 PP점보다 양의 전압에서 식각율이 급속히 감소하였다. 또한 THAH/IPA/pyrazine 용액에서의 식각정지특성을 관찰하였다. pn 접합부에서의 정확한 식각정지에 의해서 epi. 층의 두께에 상응하는 Si 다이어프램을 제작할 수 있었다. 최적 이방성 식각조건인 TMAH 25 wt.%/IPA 17 vol.%/pyrazine 0.1g/100ml에서 식각률이 가장 높기 때문에 식각소요시간이 크게 감소하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.152-152
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• 2016

Anodizing is a technology to generate thicker and high-quality films than natural oxide films by treating metals via electrochemical methods. It is a technique to develop metals for various uses, and extensive research on the commercial use has been performed for a long time. Aluminum anodic oxide (AAO) is generate oxide films, whose sizes and characteristics depending on the types of electrolytes, voltages, temperatures and time. Electrochemical manufacturing method of nano structure is an efficient technology in terms of cost reduction, high productivity and complicated shapes, which receives the spotlight in diverse areas. The sulfuric acid was used as an anodizing electrolyte, controlling its temperature to $10^{\circ}C$. The anode was 5083 Al alloy with dimension of $5(t){\times}20{\times}20mm$ while the cathode was the platinum. The distance between the anode and the cathode was maintained at 3 cm. Agitation was introduced by magnetic stirrer at 300 rpm to prevent localized temperature rise that hinders stable growth of oxide layer. In order to observe surface characteristics with applied current density, the electrolyte temperature, concentration was maintained at constant condition for $10^{\circ}C$, 10 vol.%, respectively. To prevent hindrance of stable growth of oxide layer due to local temperature increase during the experiment, stirring was maintained at constant rate. In addition, using galvanostatic method, it was maintained at current density of $10{\sim}30mA/cm^2$ for 40 minutes. The cavitation experiment was carried out with an ultrasonic vibratory apparatus using piezo-electric effect with modified ASTM-G32. The peak-to-peak amplitude was $30{\mu}m$ and the distance between the horn tip and specimen was 1 mm. The specimen after the experiment was cleaned in an ultrasonic, dried in a vacuum oven for more than 24 hours, and weighed with an electric balance. The surface damage morphology was observed with 3D analysis microscope. As a result of the investigation, differences were observed surface hardness and anti-cavitation characteristics depending on the development of oxide film with applied current density.

• 한국가스학회지
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• 제6권1호
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• pp.92-97
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• 2002

가스흡수식 냉온수기의 작동매체로 사용되고 있는 LiBr 수용액 중에서 열교환기 세관용 재료인 동 세관 및 동합금재인 큐프로니켈 세관의 부식특성에 관한 연두를 하기 위하여 $62\%$ LiBr 수용액 중에서 각 재료에 대한 전기화학적 분극실험을 실시하여 부식특성을 고찰한 결과 다음과 같은 결론을 얻었다 1) 열교환기 세관재의 분극저항은 $30\%$ 큐프로니켈 세관 > $10\%$ 큐프로니켈 세관 > 동 세관의 순으로 높게 나타난다 2) 큐프로니켈 세관의 개로전위는 동 세관보다 귀전위화되면서 부식전류밑도는 더 억제된다 3) $30\%$ 큐프로니켈 세관의 부동태 영역은 $10\%$ 큐프로니켈 세관보다 전위구간이 더 크게. 나타나면서 부동태유지 전류밀도는 더 낮아진다.

• Journal of Electrochemical Science and Technology
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• 제13권4호
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• pp.462-471
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• 2022

In this study, the electrochemical impedance characteristics of CO₂/H₂O co-reduction to produce CO/H₂ syngas were investigated in a low-temperature single cell. The effect of the operating conditions on the single-cell performance was evaluated at different feed concentrations and cell voltages, and the corresponding electrochemical impedance spectroscopy (EIS) data were collected and analyzed. The Nyquist plots exhibited two semicircles with separated characteristic frequencies of approximately 1 kHz and tens of Hz. The high-frequency semicircles, which depend only on the catholyte concentration, could be correlated to the charge transfer processes in competitive CO₂ reduction and hydrogen evolution reactions at the cathodes. The EIS characteristics of the CO₂/H₂O co-reduction single cell could be explained by the equivalent circuit suggested in this study. In this circuit, the cathodic mass transfer and anodic charge transfer processes are collectively represented by a parallel combination of resistance and a constant phase element to show low-frequency semicircles. Through nonlinear fitting using the equivalent circuit, the parameters for each electrochemical element, such as polarization resistances for high- and low-frequency processes, could be quantified as functions of feed concentration and cell voltage.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.3407-3412
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• 2007

The performance characteristics of the polymer electrolyte fuel cells (PEFCs) were investigated under various humidification conditions at steady-state and transient conditions. The PEFC studied in this study was characterized by I-V curves in potentiostatic mode. The I-V curves representing steady-state performance were obtained from OCV to 0.25V, and the dynamic performance responses were obtained at some points of voltages. The anodic external humidification was applied and the humidity was controlled from 20% to 100%. The effects of relative humidity of hydrogen were measured with the dry air at the cathode. At high voltage region, the performance at high temperature was higher, but at low voltage region, low temperature condition showed the higher performance. The dynamic responses were observed at the instant when the voltage of the PEFC was changed. It was observed that the performance reached steady-state earlier with the increase of temperature.

• 한국표면공학회지
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• 제46권6호
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• pp.271-276
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• 2013

The demand for stainless steel is continuously increasing with the development in offshore industry due to its excellent corrosion resistance characteristics. However, it suffers cavitation-erosion in application of high rotating fluid and the damage accelerates in combination with electrochemical corrosion because of Cl-ion in sea water. This paper investigated the complex damage behavior for 431 stainless steel, that is one of martensite stainless steels, through the hybrid test in sea water. Various experiments were carried out, including potential measurement, anodic/cathodic polarization experiment and Tafel analysis. Surface morphology was observed and damage depth was analyzed by SEM and 3D microscope after each experiment, respectively. The results revealed that more active potential was observed under cavitation condition than static condition due to breakdown of passive film and activation of charge transfer, and that higher corrosion current density was obtained under cavitation condition due to synergistic effect of corrosion and erosion.

• Corrosion Science and Technology
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• 제14권3호
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• pp.140-146
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• 2015

The commercialization of aluminum had been delayed than other metals because of its high oxygen affinity. Anodizing is a process in which oxide film is formed on the surface of a valve metal in an electrolyte solution by anodic oxidation reaction. Aluminum has thin oxide film on surface but the oxide film is inhomogeneous having a thickness only in the range of several nanometers. Anodizing process increases the thickness of the oxide film significantly. In this study, porous type oxide film was produced on the surface of aluminum in sulfuric acid as a function of electrolyte temperature, and the optimum condition were determined for anodizing film to exhibit excellent cavitation resistance in seawater environment. The result revealed that the oxide film formed at $10^{\circ}C$ represented the highest cavitation resistance, while the oxide film formed at $15^{\circ}C$ showed the lowest resistance to cavitation in spite of its high hardness.

• 전자공학회논문지D
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• 제35D권9호
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• pp.42-47
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• 1998

현재의 전자빔 묘화의 한계를 극복할 수 있는 마이크로 전자빔 시스템의 전자 광학 렌즈를 제작하였고 전자빔 묘화실험을 통하여 이를 검증하였다. 마이크로머시닝기술을 이용하여 실리콘 전극을 제작하고 이를 양극 접합을 통해 조립하여 다층 전극의 전자 광학 렌즈를 제작하였다. 완성된 전자 광학 소자를 초고진공 챔버에 장착하여, STM(Scanning Tunneling Microscope) 팁에서 방출된 전자빔의 focusing 특성을 관찰하였으며 전자를 집속하여 리소그라피를 수행하였다. E-beam 감광막은 PMMA(Poly-methylmethacrylate)를 사용하였고 0.13㎛의 패턴을 형성시킬 수 있었다.

• 한국수소및신에너지학회논문집
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• 제2권1호
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• pp.15-21
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• 1990

Nickel-hydrogen battery systems with metal hydride alloys are expected to have both higher energy density and lower pollution than nickel-cadmium cells. Nickel-hydrogen storage cells are expected to be well-suited for use in space crafts for a large capacity power storage system. Their major advantages are not only a capability of deep DOD(depth of discharge) using but also with excellent durability under excessive overcharging and overdischarging. In this study, the charge/discharge capacities, anodic polarization characteristics and durability for the continious charge/diacharge cycling of the $Ti_{1-X}Zr_XVNi$ and $Ti_{1-X}Zr_XV_{0.5}Ni_{1.5}$ alloys were measured by electrochemical method. The electrode properties of the copper or nickel plated $Ti_{1-X}Zr_XV_{0.5}Ni_{1.5}$ alloys were examined with a battery charge/discharge testing system in the temperature range of -5 to $25^{\circ}C$.