• Title/Summary/Keyword: Anisotropic Solid

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Preparation and Swelling Behavior of Cross-Linked Films of Hydroxypropyl Chitosan Possessing Cholesteric Liquid-Crystalline Order (Cholesteric 액정질서를 지닌 Hydroxypropyl Chitosan 가교필름의 제조와 팽윤거동)

  • 마영대;김경희
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.418-430
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    • 2000
  • A new hydroxylpropyl chitosan (HPCTO) capable of forming both thermotropic and lyotropic liquid crystalline phases was synthesized by reaction of alkali chitosan with propylene oxide and its solid films cross-linked with glyoxal were prepared by casting the liquid crystalline solution in methanol. The thermal and swelling properties of the cross-linked films were investigated. The films displayed fingerprint patterns characteristic of cholesteric liquid-crystalline phase, and their pitches increased with increasing temperature and cross-linker concentration. The cross-linked samples exhibited an anisotropic swelling in both water and methanol, suggesting that the two-dimensional cross-linking preferentially performs between HPCTO molecules. The degree of anisotropy highly depended on the solvent, but hardly on the cross-linker concentration investigated.

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Effect of packing structure on anisotropic effective thermal conductivity of thin ceramic pebble bed

  • Wang, Shuang;Wang, Shuai;Wu, Bowen;Lu, Yuelin;Zhang, Kefan;Chen, Hongli
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2174-2183
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    • 2021
  • Helium cooled solid breeder blanket as an important blanket candidate of the Tokamak fusion reactor uses ceramic pebble bed for tritium breeding. Considering the poor effective thermal conductivity of the ceramic breeder pebble bed, thin structure of tritium breeder pebble bed is usually adopted in the blanket design. The container wall has a great influence on the thin pebble bed packing structure, especially for the assembly of mono-sized particles, and thin pebble bed will appear anisotropic effective thermal conductivity phenomenon. In this paper, thin ceramic pebble beds composed of 1 mm diameter Li4SiO4 particles are generated by the EDEM 2.7. The effective thermal conductivity of different thickness pebble beds in the three-dimensional directions are analyzed by three-dimensional thermal network method. It is observed that thin Li4SiO4 pebble bed showing anisotropic effective thermal conductivity under the practical design size. Normally, the effective thermal conductivity along the bed vertical direction is higher than the horizontal direction due to the gravity effect. As the thickness increases from 10 mm to 40 mm, the effective thermal conductivity of the pebble bed gradually increases.

The Evaluation of the dose calculation algorithm(AAA)'s Accuracy in Case of a Radiation Therapy on Inhomogeneous tissues using FFF beam (FFF빔을 사용한 불균질부 방사선치료 시 선량계산 알고리즘(AAA)의 정확성 평가)

  • Kim, In Woo;Chae, Seung Hoon;Kim, Min Jung;Kim, Bo Gyoum;Kim, Chan Yong;Park, So Yeon;Yoo, Suk Hyun
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.2
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    • pp.321-327
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    • 2014
  • Purpose : To verify the accuracy of the Ecilpse's dose calculation algorithm(AAA:Analytic anisotropic algorithm) in case of a radiation treatment on Inhomogeneous tissues using FFF beam comparing dose distribution at TPS with actual distribution. Materials and Methods : After acquiring CT images for radiation treatment by the location of tumors and sizes using the solid water phantoms, cork and chest tumor phantom made of paraffin, we established the treatment plan for 6MV photon therapy using our radiation treatment planning system for chest SABR, Ecilpse's AAA(Analytic anisotropic algorithm). According to the completed plan, using our TrueBeam STx(Varian medical system, Palo Alto, CA), we irradiated radiation on the chest tumor phantom on which EBT2 films are inserted and evaluated the dose value of the treatment plan and that of the actual phantom on Inhomogeneous tissue. Results : The difference of the dose value between TPS and measurement at the medial target is 1.28~2.7%, and, at the side of target including inhomogeneous tissues, the difference is 2.02%~7.40% at Ant, 4.46%~14.84% at Post, 0.98%~7.12% at Rt, 1.36%~4.08% at Lt, 2.38%~4.98% at Sup, and 0.94%~3.54% at Inf. Conclusion : In this study, we discovered the possibility of dose calculation's errors caused by FFF beam's characteristics and the inhomogeneous tissues when we do SBRT for inhomogeneous tissues. SBRT which is most popular therapy method needs high accuracy because it irradiates high dose radiation in small fraction. So, it is supposed that ideal treatment is possible if we minimize the errors when planning for treatment through more study about organ's characteristics like Inhomogeneous tissues and FFF beam's characteristics.

An NMR Study on the Phase Change of Lipid Membranes by an Antimicrobial Peptide, Protegrin-1

  • Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.372-378
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    • 2010
  • Membrane disruption by an antimicrobial peptide, protegrin-1 (PG-1), was investigated by measuring the $^2H$ solid-state nuclear magnetic resonance (SSNMR) spectra of 1-palmitoyl-$d_{31}$-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC_$d_{31}$) in the mixture of PG-1 and POPC_$d_{31}$ lipids deposited on thin cover-glass plates. The experimental line shapes of anisotropic $^2H$ SSNMR spectra measured at various peptide-to-lipid (P/L) ratios were simulated reasonably by assuming the mosaic spread of bilayers containing pore structures or the coexistence of the mosaic spread of bilayers and a fast-tumbling isotropic phase. Within a few days of incubation in the hydration chamber, the pores were formed by the peptide in the POPC_$d_{31}$ and POPC_$d_{31}$/cholesterol membranes. However, the formation of the pores was not clear in the POPC_$d_{31}$/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylglycerol (POPG) membrane. Over a hundred days after hydration, a rapidly rotating isotropic phase increased in the POPC_$d_{31}$ and the POPC_$d_{31}$/cholesterol membranes with the higher P/L ratios, but no isotropic phase appeared in the POPC_$d_{31}$/POPG membrane. Cholesterol added in the POPC bilayer acted as a stabilizer of the pore structure and suppressed the formation of a fast-tumbling isotropic phase.

Fabrication Method and Performance Evaluation of Micro Igniter for MEMS Thruster (MEMS 추력기를 위한 마이크로 점화기의 제작 방법 및 성능 평가)

  • Lee, Jongkwang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.1-8
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    • 2015
  • Micro igniter on the glass membrane for MEMS thruster was developed. The stability of the micro igniter by using a glass membrane with a thickness of tens of microns was improved. The micro igniter was fabricated by anisotropic wet etching of photosensitive glass and deposition of Pt/Ti for electric heat coil. The solid propellant was loaded into the propellant chamber without an especial technique due to the high structural stability of the glass membrane. Ignition tests were performed successfully. The minimum ignition delay was 27.5 ms with an ignition energy of 19.3 mJ.

Effect of Magnetic properties and Microstructure of Hydrogenation stage in HDDR process (HDDR 반응시 수소화 반응이 Nd-Fe-B계 분말의 미세조직과 자기적 특성에 미치는 영향)

  • Lee, S.H.;Yu, J.H.;Kim, Y.D.
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.443-448
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    • 2011
  • The HDDR(hydrogenation-disproportionation-desorption-recombination) process can be used as an effective way of converting no coercivity Nd-Fe-B material, with a coarse $Nd_2Fe_{14}B$ grain structure to a highly coercive one with a fine grain. Careful control of the HDDR process can lead to an anisotropic $Nd_2Fe_{14}B$ without any post aligning process. In this study, the effect of hydrogen gas input at various temperature in range of $200{\sim}500^{\circ}C$ of hydrogenation stage (named Modified-solid HDDR, MS-HDDR) on the magnetic properties has been investigated. The powder from the modified-solid HDDR process exhibits Br of 11.7 kG and iHc of 10.7 kOe, which are superior to those of the powder prepared using the normal HDDR process.

Resonant Scattering of Underwater Acoustic Wave by Transversely Isotropic Cylindrical Shells (횡등방성 원통 셸에 의한 수중 음파의 공명 산란)

  • 김진연
    • Journal of KSNVE
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    • v.7 no.3
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    • pp.449-455
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    • 1997
  • A theoretical study is presented for the prediction of the scattering of obliquely incident plane acoustic wave by transversely isotropic cylindrical shells immersed in water. In dorder to illustrate the vailidity of the theory backscattering form functions are compared with the existing results for degenerated problems: the catterings by isotropic shell and transversely isotropic solid cylinder. The unidirectional fiber reinforced boron-aluminum composites are selected as a model of transversely isotropic materials having potential applications in practice. From the resonant scattering analysis of the partial backscattering form functions, the dispersion curves for fluid-borne Stoneley wave, guided wave along the shell, and the lowest three Lamb type waves can be found. The Lamb type dispersions are compared with those of the flat plate. The variation of anisotropy significantly affects the properties of circumferential waves. From these results, it can be possible to identify parametrically the material properties of anisotropic cylindrical targets.

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A Study on the Radiation Heat Transfer Characteristics of Liquid Droplet Radiator (액적방열기의 복사열전달 특성에 관한 연구)

  • 김금무;김용모;김경근
    • Journal of Advanced Marine Engineering and Technology
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    • v.18 no.1
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    • pp.32-40
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    • 1994
  • The radiative heat transfer analysis in particle layer has an inherent difficulty in treating the governing integro-differential equations, which are derived from the remote effects. Most of the existing analyses are limited to the one dimensional system, taking into account only absorption or isotropic scatting of solid particles. Fortunately, a new Monte Carlo Simulation method is recently developed to analyse multidimensional radiative heat transfer in particles with anisotropically scatting. By this method, the present study analyses the radiative heat transfer in dispersed particles through the numerous droplets in the liquid droplet radiator to develop a technique of liquid droplet radiator. Consequently, knows that the radiative heat flux in particle layer is influenced by exitinction coefficient, optical thickness and surface area of particles in the system.

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Dynamic Modeling of the Stator Core of the Electrical Machine Using Anisotropic Characteristics (이방성을 고려한 회전기기 고정자 코어의 동적 모델링)

  • Kim, Heui-Won;Lee, Soo-Mok;Kim, Kwan-Young
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.11a
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    • pp.401.1-401
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    • 2002
  • The state core of a motor/generator was modeled using dynamic model updating technique based on the modal testing work. In order to take into account the orthotropic effect of laminated structure the axial, radial and circumferential properties of the solid element were separately varied to match the primary modes of the stator core which were extracted from the modal testing. Comparison of the results after model tuning showed fairly good coincidence with measured data.

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Sintering Behavior and Mechanical Properties of Mullite-Zirconia Composites (Mullite-Zirconia 복합체의 소결거동 및 기계적 성질)

  • 박상엽
    • Journal of Powder Materials
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    • v.4 no.1
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    • pp.9-17
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    • 1997
  • The mullite-zirconia composites were prepared by the pressureless sintering with addition of 10~20 vol% ZrO$_2$(TZ3Y) in the fused mullite and sol-gel mullite matrix. The densification rate of sol-gel mullite was higher than that of fused mullite, and the addition of ZrO$_2$(TZ3Y) was effective on the densification of fused mullite. The enhancement of densification and anisotropic growth of mullite in ZrO$_2$added specimen can be explained by the solid solution effect of $Zr^{+4}$ ion in mullite. Both mechanical strength and fracture toughness of mullite-zirconia composite were enhanced compared to those of mullite. The enhancement of mechanical properties is attributed to the hinderance of grain growth and the combined toughening effects of tetra-mono phase transformation and crack deflection due to the residual stress between mullite/ZrO$_2$.

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