• 한국물환경학회지
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• 제32권6호
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• pp.649-669
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• 2016

This study explored the analytical conditions for 21 veterinary antibiotics which have been popularly sold in South Korea in 2014 but have not yet been targeted in EPA method 1694. Most of the selected antibiotics were separated by a reverse-phase C18 column with a combination of (buffered) water and organic polar solvent, which was commonly methanol and acetonitrile in the gradient elution mode. Volatile additives such as formic acid, ammonium acetate and ammonium formate were usually added to the mobile phases to minimize asymmetrical and tailing of antibiotics' peaks and to increase their ionization in mass spectrometry. The analytical methods of aminoglycoside antibiotics were distinct from those of the other antibiotics in terms of adoption of ion-pair chromatography (IPC) and hydrophilic interaction liquid chromatography (HILIC) capable of retaining and separating extremely polar compounds due to their hydrophilicity. Trifluoroacetic acid or heptafluorobutyric acid was frequently added to the mobile phase as an ion-pair reagent for the IPC. Tandem mass spectrometry was numerously applied to the detection of antibiotics using positive electrospray ionization (ESI) and the selected reaction monitoring (SRM) mode. All reviewed analytical methods had been/were validated by evaluating recovery, limits of detection and quantification, decision limit or detection capability of the methods.

• 분석과학
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• 제16권5호
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• pp.358-367
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• 2003

이 연구는 먼저 침전물 속에 major 원소 (Al, Ca, K, Fe, Mg)를 측정하기위해 ICP-MS를 이용하여 분석방법을 개발하였다. Cool ICP-MS로 major원소를 분석한 결과 Normal ICP-MS보다 더 좋은 분석 결과를 얻었다. 또한 그 결과를 NAA의한 분석 결과와 비교해 보았다. NAA는 고체시료의 비파괴 미량분석법이며 침전물 속에 major원소들에 대한 측정 결과는 ICP-MS보다 더 좋은 결과를 얻었다. 또한 침전물 속에 minor 원소 (Cr, Ce, U, Co, Pb, As, Se)를 측정하기 위해 ICP-MS를 이용하여 분석방법을 개발하였다. 표준 검정곡선으로 분석한 결과 모체방해효과 때문에 정확도가 좋지 않았다. 그래서 ICP-MS를 이용하여 내부표준물법으로 minor 원소들을 분석했을 때 결과값이 향상됨을 알 수 있었다. 그 결과를 NAA분석법과 비교해도 ICP-MS를 이용한 방법이 더 좋은 결과였음을 알 수 있었다. 두 가지의 분석방법은 침전물 속에 존재하는 minor 원소를 충분히 측정할 수 있다. 그러므로 NAA 분석법이 모체가 복잡한 환경시료를 분석하는데 중요한 역할을 하며, ICP-MS 또한 NAA 분석법으로는 분석 할 수 없는 납을 검출할 수 있기 때문에 환경시료를 분석하는데 두 분석법은 상호 보완할 수 있는 중요한 분석법이다.

• Journal of Pharmaceutical Investigation
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• 제40권1호
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• pp.59-61
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• 2010

This study was carried out to establish standard analytical method of Hippocastani Semen extract. Each standard analytical methods were covered for exact and efficient analytical method. Consequently, analytical method of Deutsches Arzneibuch has been adopted for Hippocastani Semen extract. Analytical methods established in this study could be applied to a reasonable and unified quality control of Hippocastani Semen extract.

• Structural Engineering and Mechanics
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• 제44권1호
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• pp.1-13
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• 2012

In this paper the dynamic behavior of a viscoelastic Timoshenko beam subjected to a concentrated moving load are studied analytically and numerically. The viscoelastic properties of the beam obey the linear standard model in shear and incompressible in bulk. The governing equation for Timoshenko beam theory is obtained in viscoelastic form using the correspondence principle. The analytical solution is based on the Fourier series and the numerical solution is performed with finite element method. The effects of the material properties and the load velocity are investigated on the responses by numerical and analytical methods. In addition, the results are compared with the Euler beam results.

• 한국통신학회논문지
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• 제22권3호
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• pp.539-546
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• 1997

In this paper, we proposed a new mehtod to analyze the performance degradation by timing jitters in the APD (avalanche photodiode) receivers of intensity modulation/direct detection digital optical communication systems where raised cosine pulse-shaping filters are used to reduce the effect of noise while minimizing intersymbol interferences. The proposed analytical method is an extension of an analytical method we have already developed for pin diode receivers, and incorporates the effects of APD's multiplication factor and resulting shot noise. Using the proposed analytical method, we derive an approximated power penalty due to timing jitters based on an assumption of Gaussian distribution for timing jitters, and compare with that of the conventional analytical method. The results obtained from the proposed analytical method show that conventional analytical methods underestimate the influence of timing jitters on the reciver performance. The results also show that APD's multiplication factor which optimizes receiver sensitivity is smaller than that obtained by the conventional analytical method.

• 지질공학
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• 제7권3호
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• pp.207-216
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• 1997

터널 라이닝에 작용하는 하중을 예측하는 것은 터널설계에서 가장 중요한 문제 중의 하나이다. 하지만 수치해석적 방법외의 기존의 해석적 방법들은 터널건설 방법이나 지질학적인 다양성을 충분히 고려하지 않고 있다. 에드몬톤의 터널에서 실제로 측정된 하중을 기존의 해석적 방법을 이용해 얻어진 하중과 비교하였다. 하지만 기존의 방법들은 터널 하중을 예측하는데 만족하지 못한 결과를 보여주고 있다. 터널 라이닝을 설치하기 이전에 터널 전면에서 일어나는 응력 감소를 고려해 주기 위하여 아이젠스타인-네그로의 방법과 기존의 방법을 결합하여 터널 하중을 예측할 것을 제안 하였다.

• 산업기술연구
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• 제21권A호
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• pp.41-50
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• 2001

A comparison is made of the temperature distribution and heat loss from a trapezoidal profile fin using two different 3-dimensional methods. These two methods are analytical and finite difference methods. In the finite difference method 78 nodes are used for a fourth of the fin. A trapezoidal profile fin being the height of the fin tip is half of that of the fin base is chosen arbitrarily as the model. One of the results shows that the relative error in the total convection heat loss obtained by using 78 nodes in the finite difference method as compared to the heat conduction through the fin root obtained by analytic method seems to be good (i.e., -3.5%

• 전력전자학회:학술대회논문집
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• 전력전자학회 2008년도 추계학술대회 논문집
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• pp.64-67
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• 2008

To detect islanding mode when the grid is being tripped is a major safety issue in the Utility Interactive Distributed Generation (UIDG) system. In this paper, analytical design method is suggested for AFD & RPV method under IEEE929-2000 recommended islanding test condition. We have discussed that there is a same point. we injected reactive component of the current by AFD & RPV methods, but the current reference generated is other waveform. Possible if amount of reactive components in this methods are same each method, there is happened same rates frequency variation. To verify the validity of the analytical comparison, this paper presents simulation and experimental results from single phase, 3[kW] inverter for the transformerless UIDG system.

• 한국약용작물학회지
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• 제3권3호
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• pp.226-232
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• 1995

자호(紫胡) saikosaponin정량(定量)에 대한 추출방법(抽出方法) 및 기기분석조건별(器機分析條件別) 비교분석시험(比較分析試驗)결과는 다음과 같다. 1. HPLC를 이용한 시호 사포닌 정량은 산처리하는 방법에서 무처리 방법보다 분석시간이 더 단축되었다. 2. 추출방법상 상온추출이 수율이 높으나 가온 환류추출에 의해 분석시간이 짧고 양호한 크로마토그람을 얻을 수 있었다. 3. 시호 사포닌 분석시 HPTLC법이 HPLC법보다 대량신속측면에서 양호하나 신뢰도가 떨어졌다. 4. 따라서 시호 사포닌의 추출 및 분석은 가온환류추출과 산처리하는 분석방법이 신속한 분석방법으로 적당하였으며, 성분육종을 위한 간이검정기술로서는TLC 이용 분석이 유리할 것으로 생각되었다.

• 생약학회지
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• 제39권3호
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• pp.218-222
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• 2008

This study was carried out to establish standard analytical methods for Ginkgo biloba leaf extract. Ginkgo flavonoids, terpene lactones, ginkgolic acids were employed as reference compounds for analytical method. Analytical method of US Pharmacopoeia was adopted for flavonoids and terpene lactones, and a new method was developed for ginkgolic acids. Analytical methods established in this study could be applied to a reasonable and unified quality control of G. biloba leaf extract.